Photoreactive composition
This invention provides a photoreactive composition in which reaction of a hydrolyzable metal compound takes place by irradiation of light. A photoreactive composition, which comprises a hydrolyzable metal compound (A) comprising a metal atom and a hydrolyzable functional group bonded to the metal atom and, a compound (B) promoting reaction, polymerization or crosslinking of the compound (A) in the presence of oxygen by irradiation of light.
1. A conductive material composition which comprises a hydrolyzable metal compound (A) comprising a metal atom and a hydrolyzable functional group bonded to the metal atom and,
a compound (b) promoting reaction, polymerization or crosslinking of the compound (A) in the presence of oxygen by irradiation of light and which does not contain a photo acid generator,
wherein the compound (B) has a molecular skeleton represented by the following general formula (1);
in the formula, n is an integer of 2, 3, 4 or 5; k is an integer equal to or lower than n; Y is an atom belonging to group IVB, VB or VIB in the periodic table; and Z is hydrogen or hydroxyl, mercapto, amino, a halogen, an alkoxyl, an alkylthio, carbonyloxy or oxo group and may be the same as or different from one another; however, when Y is carbon, at least one of Z is a group having an aromatic ring or an unsaturated bond.
2. A conductive material composition
which comprises a hydrolyzable metal compound (A) comprising a metal atom and a hydrolyzable functional group bonded to the metal atom and,
a compound (b) promoting reaction, polymerization or crosslinking of the compound (A) in the presence of oxygen by irradiation of light and which does not contain a photo acid generator,
wherein the hydrolyzable metal compound (A) is a compound (A1) represented by the following general formula (2-1):
(X) m Si(R) 4 m (21)
in the formula, m is an integer of 2, 3, or 4, R is a hydrocarbon group; and X is a hydrolyzable functional group.
3. A transparent conductive material composition
which comprises a hydrolyzable metal compound (a) comprising a metal atom and a hydrolyzable functional group bonded to the metal atom and,
a compound (b) promoting reaction, polymerization or crosslinking of the compound (a) in the presence of oxygen by irradiation of light and which does not contain a photo acid generator,
wherein the compound (B) has a molecular skeleton represented by the following general formula (1);
in the formula, n is an integer of 2, 3, 4 or 5; k is an integer equal to or lower than n; Y is an atom belonging to group IVB, VB or VIB in the periodic table; and Z is hydrogen or hydroxyl, mercapto, amino, a halogen, an alkoxyl, an alkylthio, carbonyloxy or oxo group and may be the same as or different from one another; however, when Y is carbon, at least one of Z is a group having an aromatic ring or an unsaturated bond.
4. A transparent conductive material composition
which comprises a hydrolyzable metal compound (a) comprising a metal atom and a hydrolyzable functional group bonded to the metal atom and,
a compound (b) promoting reaction, polymerization or crosslinking of the compound (a) in the presence of oxygen by irradiation of light and which does not contain a photo acid generator,
wherein the hydrolyzable metal compound (A) is a compound (A1) represented by the following general formula (2-1):
(X) m Si(R) 4-m (2-1)
in the formula, m is an integer of 2, 3, or 4, R is a hydrocarbon group; and X is a hydrolyzable functional group.
5. A color filter composition which comprises a hydrolyzable metal compound (A) comprising a metal atom and a hydrolyzable functional group bonded to the metal atom and,
a compound (B) promoting reaction, polymerization or crosslinking of the compound (A) in the presence of oxygen by irradiation of light and which does not contain a photo acid generator,
wherein the a compound (B) has a molecular skeleton represented by the following general formula (1);
in the formula, n is an integer of 2, 3, 4 or 5; k is an integer equal to or lower than n; Y is an atom belonging to group IVB, VB or VIB in the periodic table; and Z is hydrogen or hydroxyl, mercapto, amino, a halogen, an alkoxyl, an alkylthio, carbonyloxy or oxo group and may be the same as or different from one another; however, when Y is carbon, at least one of Z is a group having an aromatic ring or an unsaturated bond.
6. A color filter composition which comprises a hydrolyzable metal compound (A) comprising a metal atom and a hydrolyzable functional group bonded to the metal atom and,
a compound (B) promoting reaction, polymerization or crosslinking of the compound (A) in the presence of oxygen by irradiation of light and which does not contain a photo acid generator,
wherein the hydrolyzable metal compound (A) is a compound (A1) represented by the following general formula (2-1):
(X) m Si(R) 4-m (2-1)
in the formula, m is an integer of 2, 3, or 4, R is a hydrocarbon group; and X is a hydrolyzable functional group.