Photoelectrocatalytic method and photoelectrochemical detector for electrochemical analysis
A photoelectrocatalytic method for detecting current that illuminates a photoelectrochemical electrode to generate a photocurrent and to magnify the current. Thereby, accuracy of the detection is increased. A photoelectrochemical detector used in the method has a base ( 10 ), a cover ( 20 ) pivotally mounted on the base ( 10 ) and a locking device attached between the base ( 10 ) and the cover ( 20 ). The base ( 10 ) has a top and a recess ( 12 ) defined in the top to accommodate a working electrode ( 50 ) with a photoelectrochemical inner lead ( 52 ). A spacer is clamped between the base ( 10 ) and the cover ( 20 ) to form a space over the inner lead ( 52 ). Multiple channels and a light hole ( 22 ) are defined through the cover ( 20 ) to communicate with the space. Therefore, the inner lead is illuminated through the light hole ( 22 ) to perform the photoelectrochemical method.
1. A photoelectrochemical detector comprising:
a base ( 10 ) with a top, a front end, a rear end and sides, and having a recess ( 12 ) defined longitudinally in the top and extending to the front end;
a cover ( 20 ) with a top, a bottom, a front end, a rear end and two sides, which is mounted pivotally on the base ( 10 ) and has a spacer with an inner open area attached to the bottom of the cover ( 20 ), and a light hole ( 22 ) and multiple channels defined through the cover ( 20 ) to communicate with the inner open area of the spacer, wherein a light source ( 55 ) is attached to the cover ( 20 ) to operatively communicate with light hole ( 22 );
a working electrode ( 50 ) mounted in the recess ( 12 ) and having a top face, an inner end, an outer end, and an inner lead ( 52 ) made of material with photoelectrochemical properties, wherein the inner lead ( 52 ) is attached on the top face of the working electrode ( 50 ) near the inner end and aligned with the light hole ( 22 ) when the cover ( 20 ) is closed, and wherein the working electrode is connected to an electricity source; and
wherein the multiple channels are:
an inlet ( 27 ) defined in the cover ( 20 ) on one side;
a first outlet ( 24 ) defined in the cover ( 20 ) on the other side; and
a second outlet ( 26 ) defined in the cover ( 20 ) on the same side as the first outlet ( 24 ); and
wherein the device further has a reference electrode ( 30 ) corresponding to the first outlet ( 24 ); and
wherein the device further has an auxiliary electrode ( 40 ) corresponding to the second outlet ( 26 ); and
a locking device mounted between the base ( 10 ) and the cover ( 20 ) to attach the cover ( 20 ) to the base ( 10 ).
2. The photoelectrochemical detector as claimed in claim 1 , wherein the locking device comprises:
two locking posts ( 14 ) formed on and protruding from the top of the base ( 10 ) at opposite sides of the front end and each of the two locking posts ( 14 ) having
a hole; and
a ball-spring combination mounted in the hole and comprising
a retractable ball ( 186 ) retractably mounted in the hole in the locking post ( 14 ); and
a resilient member ( 1 84 ) mounted in the hole to push the retractable ball outward; and
two ball detents ( 23 ) defined at the front end of the cover ( 20 ) to correspond to the retractable balls ( 186 ) when the cover ( 20 ) is closed.
3. The photoelectrochemical detector as claimed in claim 2 ,
wherein the cover ( 20 ) further has two side cutouts defined respectively at opposite sides of the front end to correspond to the locking posts ( 14 ); and the two ball detents ( 23 ) are defined in the two side cutouts and align respectively with the retractable balls ( 186 ) in the locking posts ( 14 ).
4. The photoelectrochemical detector as claimed in claim 2 , wherein each locking post ( 14 ) further has:
a threaded hole ( 142 ) defined through the locking post ( 14 ); and
a threaded rod ( 1 8 ) screwed into the threaded hole ( 142 ) and having
a bore ( 1 82 ) defined in the threaded rod ( 1 8 ) in which the retractable ball ( 186 ) is mounted; wherein each resilient element is ( 184 ) mounted inside the bore ( 182 ) in one corresponding thread rod ( 18 ) to press the retractable ball ( 186 ) to correspondingly engage and lock with one of the ball detents ( 23 ).
5. The photoelectrochemical detector as claimed in claim 3 , wherein each locking post ( 14 ) further has:
a threaded hole ( 142 ) defined through the locking post ( 14 );
a threaded rod ( 18 ) screwed into the threaded hole ( 142 ) and having a bore ( 182 ) defined in the threaded rod ( 18 ) in which the retractable ball ( 186 ) is mounted; and
wherein a resilient element ( 184 ) is mounted inside the bore ( 182 ) in one corresponding thread rod ( 18 ) to press the retractable ball ( 186 ) to correspondingly engage and lock with one of the ball detents ( 23 ).
6. The photoelectrochemical detector as claimed in claim 5 ,
wherein each resilient element is a spring.
7. The photoelectrochemical detector as claimed in claim 1 , wherein the spacer in the cover ( 20 ) comprises a gasket seat ( 28 ) defined in the bottom of the cover ( 20 ); and a rectangular gasket ( 282 ) with the inner open area mounted in the gasket seat ( 28 ).
8. The photoelectrochemical detector as claimed in claim 1 ,
wherein the device further has a reference electrode ( 30 ) corresponding to the second outlet ( 26 ).
9. The photoelectrochemical detector as claimed in claim 8 ,
wherein the device further has an auxiliary electrode ( 40 ) corresponding to the first outlet ( 26 ).
10. The photoelectrochemical detector as claimed in claim 1 , wherein the recess ( 12 ) is a dovetail recess; and the base ( 10 ) further has multiple grooves ( 102 ) defined in the sides of the base ( 10 ) to make the base easy to hold.