Synthesis of carbon nanotubes filled with palladium nanoparticles using arc discharge in solution
View Patent ↗A novel method for simultaneously forming and filling and decorating carbon nanotubes with palladium nanoparticles is disclosed. Synthesis involves preparing a palladium chloride (PdCl 2 ) solution in a container, having two graphite electrodes, then immersing the graphite electrode assembly, into the PdCl 2 solution; connecting the graphite electrodes to a direct current power supply; bringing the electrodes into contact with each other to strike an arc; separating the electrodes to sustain the arc inside the solution; putting the container with electrode assembly in a water-cooled bath; and collecting Pd-nanoparticles encapsulated in carbon nanotubes and carbon nanotubes decorated with Pd-nanoparticles. The temperature at the site of the arc-discharge is greater than 3000° C. At these temperatures, the palladium is ionized into nanoparticles and the graphite electrodes generate layers of graphene (carbon), which roll away from the anode and encapsulate or entrap the Pd-nanoparticles. The unique nanotube structures have significant commercial potential as gas sensors or as a means for hydrogen storage.
1. A process for synthesizing carbon nanotubes filled with palladium nanoparticles comprising the steps of:
preparing a palladium chloride (PdCl 2 ) solution in a container;
immersing a graphite electrode assembly, having two graphite electrodes, into the PdCl 2 solution;
connecting the graphite electrodes to a direct current power supply;
bringing the electrodes into contact with each other to strike an arc;
vaporizing the PdCl 2 solution to leave a residue of Pd-nanoparticles;
separating the electrodes to sustain the arc inside the solution;
forming graphene layers that roll away from the electrodes and simultaneously encapsulate the Pd-nanoparticles;
putting the container with electrode assembly in a water-cooled bath; and
collecting Pd-nanoparticles entrapped in carbon nanotubes.
2. The process of claim 1 , wherein the palladium chloride solution comprises, PdCl 2 powder, dc-ionized water, and hydrochloric acid.
3. The process of claim 1 , wherein the electrode assembly consists of one electrode acting as a cathode and another electrode acting as an anode.
4. The process of claim 1 , wherein the electrodes in contact with each other cream an arc-discharge.
5. The process of claim 1 , wherein the temperature at the site of the arc-discharge is greater than 3000° C.
6. The process of claim 1 , wherein the electrodes are separated to a distance of approximately 1 millimeter (mm) to sustain the arc in the solution.
7. The process of claim 1 , wherein the direct current supply has an open circuit potential of approximately 28 volts (V) with an optimized direct current of approximately 35 ampere (A) units.
8. The process of claim 1 , wherein the water-cooled bath has a temperature of approximately 7° C.
9. The process of claim 1 , wherein the Pd-nanoparticles have a diameter of approximately 3 nanometers (nm).
10. The process of claim 1 where in the carbon nanotubes each have a diameter of approximately 15 nanometers (nm).
11. The process of claim 1 wherein the carbon nanotubes and the Pd-nanoparticles are simultaneously formed and encapsulated.
12. The process of claim 1 wherein the carbon nanotubes and the Pd-nanoparticles are simultaneously formed and entrapped in carbon nanotubes walls.
13. The process of claim 1 wherein the carbon nanotubes are selected from the group consisting of: single-walled CNTs and multi-walled CNTs.