R-T-B system permanent magnet
An R-T-B system permanent magnet 1 comprises a magnet body 2 comprising a sintered body comprising at least a main phase comprising R 2 T 14 B grains (wherein R represents one or more rare earth elements, and T represents one or more transition metal elements including Fe or Fe and Co essentially) and a grain boundary phase containing R in a larger amount than the main phase, the magnet body 2 having a 300 μm or less thick (not inclusive of zero thick) hydrogen-rich layer 21 having a hydrogen concentration of 300 ppm or more formed in the surface layer portion, and an overcoat 3 covering the surface of the magnet body 2 can improve the corrosion resistance of the R-T-B system permanent magnet 1 with an overcoat 3 formed thereon without degrading the magnetic properties thereof. The present invention can be applied to formation of the overcoat 3 by electrolytic plating, can fully ensure the corrosion resistance as a primary target of the overcoat 3 formation without substantially degrading the production efficiency, and can provide the R-T-B system permanent magnet 1 with a high dimensional precision by suppressing the partial collapse (detachment of grains) of the surface thereof.
1. An R-T-B system permanent magnet characterized by comprising:
a magnet body comprising a sintered body comprising at least a main phase comprising R 2 T 14 B grains (wherein R represents one or more rare earth elements, and T represents one or more transition metal elements including Fe or Fe and Co essentially) and a grain boundary phase containing R in a larger amount than the main phase, the magnet body having a 10-200 μm thick hydrogen-rich layer having a hydrogen concentration of 300 ppm or more formed in the surface layer portion; and
an overcoat covering the surface of the magnet body.
2. The R-T-B system permanent magnet according to claim 1 , characterized in that the hydrogen-rich layer has a hydrogen concentration of 1000 ppm or more.
3. The R-T-B system permanent magnet according to claim 1 , characterized in that:
said sintered body comprises at least a main phase comprising R 2 Fe 14 B grains and a grain boundary phase comprising R in a larger amount than the main phase; and
the sum of the areas of the R 2 Fe 14 B grains of 10 μm or less in grain size is 90% or more, and the sum of areas of the R 2 Fe 14 B grains of 20 μm or more in grain size is 3% or less, in relation to the total area of the main phase.
4. The R-T-B system permanent magnet according to claim 1 , characterized in that the magnet body comprises a sintered body having a composition comprising R: 27.0 to 35.0 wt % (wherein R represents one or more rare earth elements), B: 0.5 to 2.0 wt %, O: 2500 ppm or less, C: 1500 ppm or less, N: 200 to 1500 ppm, and the balance substantially being Fe.
5. The R-T-B system permanent magnet according to claim 4 , characterized in that the sintered body comprises one or more of Nb: 0.1 to 2.0 wt %, Zr: 0.05 to 0.25 wt %, Al: 0.02 to 2.0 wt %, Co: 0.3 to 5.0 wt % and Cu: 0.01 to 1.0 wt %.
6. The R-T-B system permanent magnet according to claim 1 , characterized in that the hydrogen-rich layer has a hydrogen concentration of 300 to 1000 ppm.
7. The R-T-B system permanent magnet according to claim 1 , characterized in that the overcoat is formed by electrolytic metal plating.
8. The R-T-B system permanent magnet according to claim 2 , characterized in that the hydrogen-rich layer has a hydrogen concentration decreased from the surface of the magnet body toward the inside of the magnet body.
9. The R-T-B system permanent magnet according to claim 8 , characterized in that the hydrogen-rich layer has a hydrogen concentration continuously decreased from the surface of the magnet body toward the inside of the magnet body.
10. The R-T-B system permanent magnet according to claim 8 , characterized in that the hydrogen-rich layer has a hydrogen concentration stepwise decreased from the surface of the magnet body toward the inside of the magnet body.
11. The R-T-B system permanent magnet according to claim 8 , characterized in that the overcoat is formed by electrolytic metal plating.