Binding agent component for surface coating agents with improved adhesive properties
The invention relates to a binding agent composition, in particular an adhesive, containing at least one epoxy compound or at least one amino compound comprising at least two amino groups, or at least one hydroxy compound comprising at least two OH groups, or at least one mercapto compound comprising at least two mercapto groups, or at least one isocyanate comprising at least two NCO groups and a compound with chelating properties. The invention also relates to a method for producing binding agent compounds of this type and to the use of the same.
1. A binder component comprising (a) at least one substance selected from the group consisting of epoxy compounds, amino compounds having at least two amino groups, hydroxy compounds having at least two OH groups, mercapto compounds having at least two SH groups, isocyanates having at least two NCO groups and (b) at least one compound having chelating properties
wherein the at least one compound having chelating properties comprises from about 1 to about 25% by weight of said binder component and
comprises a compound of the general formula I, II or III
in which A is Y or X-Y, and Y is NH 2 , NHR 8 or SH, and X is a linear or branched alkyl radical having 1 to 22 carbon atoms, and R 1 , R 2 , R 3 , R 4 , R 5 , and in formulae II and III, R 6 and R 7 , independently of one another, are H, SO 3 H, OSO 3 H, OP(O)(OH) 2 ,P(O)(OH) 2 , P(O)HOH, COOH, OH, NH 2 , NHR 8 , C(O)R 8 , CN or NO 2 , in which R 8 is hydrogen or a linear or branched, saturated or unsaturated aliphatic hydrocarbon radical having 1 to 10 carbon atoms, or two adjacent radicals from R 1 to R 7 together form an aromatic or heteroaromatic ring, at least two of the radicals R 1 to R 7 not being H or part of an aromatic or heteroaromatic ring system, and the remaining radicals being arranged such that the compound of the general formula I, II or III binds to a divalent or polyvalent metal ligand in chelate form.
2. The binder component of claim 1 wherein the at least one compound having chelating properties contains an amino group or a mercapto group.
3. The binder component of claim 1 wherein the at least one compound having chelating properties comprises a compound of the general formula I.
4. The binder component of claim 1 wherein at least one of the radicals R 1 to R 7 is COOGH.
5. The binder component of claim 1 wherein the at least one compound having chelating properties comprises at least one member selected from the group consisting of aminosalicylic acids, aminoisophthalic acids, and derivatives thereof.
6. A process for preparing a binder component in accordance with claim 1 , said process comprising mixing said at least one substance with said at least one compound having chelating properties.
7. The binder component of claim 1 wherein (a) comprises at least one epoxy compound and at least one second substance selected from the group consisting of amino compounds having at least two amino groups, hydroxy compounds having at least two OH groups, mercapto compounds having at least two SH groups, and isocyanates having at least two NCO groups.
8. The binder component of claim 1 wherein said at least one compound having chelating properties comprises from about 2 to about 20% by weight of said binder component.
9. The binder component of claim 1 comprising 20 to 90% by weight of at least one epoxy compound, and 3 to 79.9% by weight of at least one hardener selected from the group consisting of polymercaptan hardeners and polyamine hardeners.
10. The binder component of claim 1 comprising 35 to 90%by weight of at least one epoxy compound, 2 to 10% by weight of at least one catalytic hardener, 3 to 40% by weight of at least one filler, and 1 to 12% by weight of said at least one compound having chelating properties.
11. The binder component of claim 1 comprising 40 to 80 % by weight of at least one epoxy compound, 10 to 60% by weight of at least one hardener selected from the group consisting of polymercaptan hardeners and polyamine hardeners, and 2 to 15% by weight of said at least one compound having chelating properties.
12. The binder component of claim 1 comprising 50 to 80 % by weight of at least one diglycidyl ether, 10 to 49% by weight of at least one hardener selected from the group consisting of polyetheramines bearing at least two amino groups per molecule and polyaminoamides, and 2 to 12% by weight of said at least one compound having chelating properties.
13. The binder component of claim 1 comprising 25 to 60 % by weight of at least one epoxy compound, 15 to 40% by weight of at least one hardener selected from the group consisting of polyamines and polymercaptans, 10 to 40% by weight of at least one filler, and 1 to 12% by weight of said at least one compound having chelating properties.
14. The binder component of claim 1 additionally comprising at least one auxiliary selected from the group consisting of stabilizers, defoamers, antioxidants, photostabilizers, pigment dispersants, fillers, plasticizers, tackifiers, dyes, microbiocides, impact modifiers, and catalysts.
15. The binder component of claim 1 wherein said at least one compound having chelating properties contains a combination of functional groups selected from the group consisting of a) COOH and CHO, b) COOH and OH, c) COOH and SO 3 H, d) COOH and COOH, e) SO 3 H and OH, f) SO 3 H and CHO, g) OP(O)(OH) 2 and COOH, h) OP(O)(OH) 2 and OH, i) OP(O)(OH) 2 and OP(O)(OH) 2 , j) OP(O)(OH) 2 and CHO, k) P(O)(OH) 2 and P(O)(OH) 2 , l) P(O)(OH) 2 and COOH, m) P(O)(OH) 2 and SO 3 H, n) P(O)HOH and COOH, o) P(O)HOH and P(O)HOH, p) P(O)HOH and OH, q) P(O)HOH and CHO, and r) P(O)HOH and SO 3 H.
16. The binder component of claim 1 wherein said at least one compound having chelating properties is selected from the group consisting of 4- amino-2-hydroxybenzoic acid, 5 -amino-2-hydroxybenzoic acid, 5 -aminoisophthalic acid, 1 -amino-2-hydroxynaphthalene-4-sulfonic acid, aminosalicylaldehyde, 4- aminophthalic acid, 4-aminophthalonitrile, mercaptosalicylic acid, mercaptoisophthalic acid, or a mixture thereof.
17. A method of coating or sealing a surface comprising applying a binder component in accordance with claim 1 to said surface and curing said binder component.
18. The method of claim 17 wherein said surface is comprised of metal.
19. A method of adhering a first substrate to a second substrate comprising using a binder component in accordance with claim 1 to bond said first substrate and said second substrate.
20. The method of claim 19 wherein at least one of said first substrate or said second substrate is comprised of metal.