Resin composition and method for producing the same
The present invention provides a resin composition which comprises EVOH and a thermoplastic resin other than EVOH and which generates less odor and therefore is suitable for food packaging applications. The invention also provides an environmentally friendly method for producing a resin composition, without releasing any carboxylic acid such as acetic acid to the peripheral environment. A resin composition containing less carboxylate group is obtained by contacting an ethylene-vinyl alcohol copolymer resin with an aqueous solution containing both carbon dioxide gas and at least one additive selected from the group consisting of an alkali metal salt (A) and a boron compound (B) and then melt kneading with a thermoplastic resin (G) other than EVOH.
1. A resin composition comprising:
an unmodified ethylene-vinyl alcohol copolymer resin composition (F):
containing 0.1 to 20 μmol/g, in terms of alkali metal, of an alkali metal salt (A);
yielding 0 to 2 μmol/g of a carboxylate group (C1) upon extraction by immersion treatment in water at 95° C. for 10 hours; and
yielding 0 to 40 μmol/g of a carboxylate group (C2) upon extraction by immersion treatment in a 0.05 N aqueous sodium hydroxide solution at 95° C. for 10 hours; and
a thermoplastic resin (G) comprising at least one resin selected from the group consisting of polyolefin (G1), polyamide (G2) and a modified ethylene-vinyl alcohol copolymer (G3) having an ethylene content of 5 to 55 mol % and containing 0.3 to 40 mol % of the following structural unit (I):
wherein R 1 , R 2 , R 3 and R 4 each denote a hydrogen atom, an aliphatic hydrocarbon group having 1 to 10 carbon atoms, an alicyclic hydrocarbon group having 3 to 10 carbon atoms or an aromatic hydrocarbon group having 6 to 10 carbon atoms; R 1 , R 2 , R 3 and R 4 may be the same or different; R 3 and R 4 may be combined together; and R 1 , R 2 , R 3 and R 4 each may have a hydroxyl group, a carboxyl group or a halogen atom.
2. The resin composition according to claim 1 which comprises 0.1 to 99.9% by weight of the unmodified ethylene-vinyl alcohol copolymer resin composition (F) and 0.1 to 99.9% by weight of the polyolefin (G1).
3. The resin composition according to claim 1 which comprises 1 to 99% by weight of the unmodified ethylene-vinyl alcohol copolymer resin composition (F) and 1 to 99% by weight of the polyamide (G2).
4. The resin composition according to claim 3 , wherein the polyamide (G2) has terminal amino groups in an amount of 15 μmol/g of less.
5. The resin composition according to claim 1 which comprises 1 to 99% by weight of the unmodified ethylene-vinyl alcohol copolymer resin composition (F) and 1 to 99% by weight of the modified ethylene-vinyl alcohol copolymer (G3).
6. The resin composition according to claim 1 , wherein the alkali metal salt (A) is a potassium salt.
7. The resin composition according to claim 1 , wherein the unmodified ethylene-vinyl alcohol copolymer resin composition (F) further contains 1 to 200 μmol/g, in terms of boron element, of a boron compound (B).
8. The resin composition according to claim 1 , wherein a phosphorus element content (t) of the unmodified ethylene-vinyl alcohol copolymer resin composition (F) is 0.05 to 5 μmol/g.
9. A molded article obtained by molding the resin composition according to claim 1 .
10. A resin composition comprising:
an unmodified ethylene-vinyl alcohol copolymer resin composition (F):
containing 0.1 to 20 μmol/g, in terms of alkali metal, of an alkali metal salt (A);
yielding 0 to 2 μmol/g of a carboxylate group (C1) upon extraction by immersion treatment in water at 95° C. for 10 hours; and
having a degree of saponification of 99.7 to 100 mol %; and
a thermoplastic resin (G) comprising at least one resin selected from the group consisting of polyolefin (G1), polyamide (G2) and a modified ethylene-vinyl alcohol copolymer (G3) having an ethylene content of 5 to 55 mol % and containing 0.3 to 40 mol % of the following structural unit (I):
wherein R 1 , R 2 , R 3 and R 4 each denote a hydrogen atom, an aliphatic hydrocarbon group having 1 to 10 carbon atoms, an alicyclic hydrocarbon group haying 3 to 10 carbon atoms or an aromatic hydrocarbon group having 6 to 10 carbon atoms; R 1 , R 2 , R 3 and R 4 may be the same or different; R 3 and R 4 may be combined together; and R 1 , R 2 , R 3 and R 4 each may have a hydroxyl group, a carboxyl group or a halogen atom.
11. The resin composition according to claim 10 which comprises 0.1 to 99.9% by weight of the unmodified ethylene-vinyl alcohol copolymer resin composition (F) and 0.1 to 99.9% by weight of the polyolefin (G1).
12. The resin composition according to claim 10 which comprises 1 to 99% by weight of the unmodified ethylene-vinyl alcohol copolymer resin composition (F) and 1 to 99% by weight of the polyamide (G2).
13. The resin composition according to claim 12 , wherein the polyamide (G2) has terminal amino groups in an amount of 15 μmol/g or less.
14. The resin composition according to claim 10 which comprises 1 to 99% by weight of the unmodified ethylene-vinyl alcohol copolymer resin composition (F) and 1 to 99% by weight of the modified ethylene-vinyl alcohol copolymer (G3).
15. The resin composition according to claim 10 , wherein the alkali metal salt (A) is a potassium salt.
16. The resin composition according to claim 10 , wherein the unmodified ethylene-vinyl alcohol copolymer resin composition (F) further contains 1 to 200 μmol/g, in terms of boron element, of a boron compound (B).
17. The resin composition according to claim 10 , wherein a phosphorus element content (t) of the unmodified ethylene-vinyl alcohol copolymer resin composition (F) is 0.05 to 5 μmol/g.
18. A molded article obtained by molding the resin composition according to claim 10 .
19. A method for producing a resin composition, wherein an unmodified ethylene-vinyl alcohol copolymer is contacted with an aqueous solution containing both carbon dioxide gas and at least one additive selected from the group consisting of an alkali metal salt (A) and a boron compound (B) and then is melt kneaded with a thermoplastic resin (G) comprising at least one resin selected from the group consisting of polyolefin (G1), polyamide (G2) and a modified ethylene-vinyl alcohol copolymer (G3) having an ethylene content of 5 to 55 mol % and containing 0.3 to 40 mol % of the following structural unit (I):
wherein R 1 , R 2 , R 3 and R 4 each denote a hydrogen atom, an aliphatic hydrocarbon group having 1 to 10 carbon atoms, an alicyclic hydrocarbon group having 3 to 10 carbon atoms or an aromatic hydrocarbon group having 6 to 10 carbon atoms; R 1 , R 2 , R 3 and R 4 may be the same or different; R 3 and R 4 may be combined together; and R 1 , R 2 , R 3 and R 4 each may have a hydroxyl group, a carboxyl group or a halogen atom.
20. The method for producing a resin composition according to claim 19 , wherein the thermoplastic resin (G) is polyolefin (G1).
21. The method for producing a resin composition according to claim 19 , wherein the thermoplastic resin (G) is polyamide (G2).
22. The method for producing a resin composition according to claim 19 , wherein the thermoplastic resin (G) comprises the modified ethylene-vinyl alcohol copolymer (G3).