High-strength, high-permeability steel sheet for picture tube band and method of producing the same
A high-strength, high-permeability steel sheet for picture tube band comprises, in mass percent, C: 0.003-0.010%, Si: 0.5-1.0%, Mn: 1.0-2.0%, P: 0.04-0.15%, S: not more than 0.02%, Al: not more than 0.030%, N: not more than 0.004% and the balance of Fe and unavoidable impurities, has a chemical composition satisfying C×Mn×P≧2.5×10 −4 , and has a ferrite crystal grain diameter of 10-100 μm and a yield stress of 300 N/mm 2 or higher, and preferably has a specific permeability μ0.35 in a DC magnetic field of 0.35 Oe of 400 or higher. The steel sheet can be produced by regulating the hot-rolling coiling temperature to 600-700° C. and selecting an appropriate combination of the cold rolling reduction ratio and a final annealing temperature in the range of 750-900° C.
1. A high-strength, high-permeability steel sheet for picture tube band having a chemical composition consisting of, in mass percent, C: 0.005-0.010%, Si: 0.5-1.0%, Mn: 1.0-2.0%, P: 0.04-0.15%, S: not more than 0.02%, Al: 0.011-0.030%, N: not more than 0.004% and the balance of Fe and unavoidable impurities, and having a ferrite crystal grain diameter of 10-100 μm and a yield stress of 300 N/mm 2 or higher.
2. A high-strength, high-permeability steel sheet for picture tube band consisting of, in mass percent, C: 0.005-0.010%, Si: 0.5-1.0%, Mn: 1.0-2.0%, P: 0.04-0.15%, S: not more than 0.02%, Al: 0.011-0.030%, N: not more than 0.004% and the balance of Fe and unavoidable impurities, having a chemical composition satisfying the following Equation 1, and having a ferrite crystal grain diameter of 10-100 μm and a yield stress of 300 N/mm 2 or higher:
C×Mn×P≧2.5×10 −4 (1).
3. A steel sheet according to claim 1 , whose specific permeability μ0.35 in a DC magnetic field of 0.35 Oe is 400 or higher.
4. A steel sheet according to claim 1 , further comprising a Zn-system or Al-system plating layer on the surface thereof.
5. A method of producing a steel sheet set out in claim 1 characterized in that when production is carried out by, after hot rolling, conducting one or a plurality of cold rolling and annealing runs,
(1) a coiling temperature after hot rolling is made 600-700° C., and
(2) a final cold rolling reduction ratio and a final annealing temperature in a range of 750-900° C. are combined in accordance with a recrystallization property of the steel so that the ferrite crystal grain diameter after final annealing becomes 10-100 μm.
6. A method of producing a steel sheet set out in claim 1 , further comprising:
a production process of, after hot rolling, conducting one or a plurality of cold rolling and annealing runs and conducting Zn-system or Al-system hot-dip plating inline in the cooling step of the final annealing run, or
a production process of, after hot rolling, conducting one or a plurality of cold rolling and annealing runs, conducting Zn-system or Al-system hot-dip plating inline in the cooling step of the final annealing run, and thereafter conducting temper rolling of not greater than 1.5%,
in which method,
(1) a coiling temperature after hot rolling is made 600-700° C., and
(2) a final cold rolling reduction ratio and a final annealing temperature in a range of 750-900° C. are combined in accordance with a recrystallization property of the steel so that the ferrite crystal grain diameter after plating becomes 10-100 μm.
7. A method of producing a steel sheet set out in claim 1 , further comprising one production process among:
a production process of, after hot rolling, conducting one or a plurality of cold rolling and annealing runs and then conducting temper rolling at not greater than 1.5%,
a production process of, after hot rolling, conducting one or a plurality of cold rolling and annealing runs and thereafter conducting Zn-system electroplating,
a production process of, after hot rolling, conducting one or a plurality of cold rolling and annealing runs, then conducting temper rolling at not greater than 1.5% and thereafter conducting Zn-system electroplating, and
a production process of, after hot rolling, conducting one or a plurality of cold rolling and annealing runs, thereafter conducting Zn-system electroplating, and further conducting temper rolling at not greater than 1.5%,
in which method,
(1) a coiling temperature after hot rolling is made 600-700 ° C., and
(2) a final cold rolling reduction ratio and a final annealing temperature in a range of 750-900° C. are combined in accordance with a recrystallization property of the steel so that the ferrite crystal grain diameter after plating becomes 10-100 μm.
8. A method of producing a steel sheet set out in claim 2 characterized in that when production is carried out by, after hot rolling, conducting one or a plurality of cold rolling and annealing runs,
(1) a coiling temperature after hot rolling is made 600-700° C., and
(2) a final cold rolling reduction ratio and a final annealing temperature in a range of 750-900° C. are combined in accordance with a recrystallization property of the steel so that the ferrite crystal grain diameter after final annealing becomes 10-100 μm.
9. A method of producing a steel sheet set out in claim 2 , further comprising:
a production process of, after hot rolling, conducting one or a plurality of cold rolling and annealing runs and conducting Zn-system or Al-system hot-dip plating inline in the cooling step of the final annealing run, or
a production process of, after hot rolling, conducting one or a plurality of cold rolling and annealing runs, conducting Zn-system or Al-system hot-dip plating inline in the cooling step of the final annealing run, and thereafter conducting temper rolling of not greater than 1.5%,
in which method,
(1) a coiling temperature after hot rolling is made 600-700° C., and
(2) a final cold rolling reduction ratio and a final annealing temperature in a range of 750-900° C. are combined in accordance with a recrystallization property of the steel so that the ferrite crystal grain diameter after plating becomes 10-100 μm.
10. A method of producing a steel sheet set out in claim 2 , further comprising one production process among:
a production process of, after hot rolling, conducting one or a plurality of cold rolling and annealing runs and then conducting temper rolling at not greater than 1.5%,
a production process of, after hot rolling, conducting one or a plurality of cold rolling and annealing runs and thereafter conducting Zn-system electroplating,
a production process of, after hot rolling, conducting one or a plurality of cold rolling and annealing runs, then conducting temper rolling at not greater than 1.5% and thereafter conducting Zn-system electroplating, and
a production process of, after hot rolling, conducting one or a plurality of cold rolling and annealing runs, thereafter conducting Zn-system electroplating, and further conducting temper rolling at not greater than 1.5%,
in which method,
(1) a coiling temperature after hot rolling is made 600-700° C., and
(2) a final cold rolling reduction ratio and a final annealing temperature in a range of 750-900° C. are combined in accordance with a recrystallization property of the steel so that the ferrite crystal grain diameter after plating becomes 10-100 μm.