Aromatic polymer, film, electrolyte membrane and separator
An aromatic polymer containing aromatic polyamide structural units and aromatic carbohydrazide structural units at a specific ratio is disclosed. A film having a high Young's modulus, high elongation at break and low moisture absorption can be formed from such an aromatic polymer. Dehydration cyclization of a compound having a carbohydrazide structure can be conducted under mild conditions at low cost by causing the chemical reaction using a chemical which is selected from the acids and bases.
1. An aromatic polymer comprising structural units represented by chemical formulas (I), (II) and (III) and satisfying formulas (1) to (3) when molar fractions (%) of the structural units of the chemical formulas (I), (II) and (III) are represented by l, m and n, respectively:
80 ≦l+m+n ≦100 (1)
5≦m≦90 (2)
20≦n≦90 (3);
R 1 : an aromatic group, and
R 2 : a para-directed phenylene group, provided that each of the hydrogen atoms at 2-, 3-, 5- and 6-positions of an aromatic ring may be substituted with another atom or substituent;
R 3 : a 1,3-bis(4-phenoxy)benzene group represented by chemical formula (IV):
R 4 : a para-directed phenylene group, provided that each of the hydrogen atoms at 2-, 3-, 5- and 6-positions of an aromatic ring may be substituted with another atom or substituent;
R 5 : 2, 6-naphthalene group, and
R 6 : a para-directed phenylene group, provided that each of the hydrogen atoms at 2-, 3-, 5- and 6-positions of an aromatic ring may be substituted with another atom or substituent.
2. The aromatic polymer according to claim 1 , wherein R 1 is an aromatic group containing no substituent selected from the group consisting of an ether group (—O—), a methylene group (—CH 2 —) and a sulfone group (—SO 2 —).
3. The aromatic polymer according to claim 1 , wherein R 1 is a group selected from the group consisting of a phenyl group, a biphenyl group, a terphenyl group, a naphthalene group, an anthracene group, a diaminobenzanilide residue and a 9,9-bis(4-aminophenyl)fluorene residue, provided that part or all of the hydrogen of an aromatic ring may be substituted with another or other atoms or substituents.
4. The aromatic polymer according to claim 1 , wherein R 1 is an aromatic group containing no halogen atom.
5. A film comprising the aromatic polymer according to claim 1 .
6. The film according to claim 5 , wherein the film has a tensile modulus of elasticity of 5 GPa or more in at least one direction, a moisture absorption of 7% or less, and an elongation at break of 20% or more in at least one direction.
7. A magnetic recording material comprising the film according to claim 5 .
8. An aromatic polymer wherein part or all of the carbohydrazide structures contained in the aromatic polymer have been cyclized by dehydration, wherein the aromatic polymer before cyclization is an aromatic polymer comprising structural units represented by chemical formulas (I), (II) and (III) and satisfying formulas (1) to (3) when molar fractions (%) of the structural units of the chemical formulas (I), (II) and (III) are represented by l, m and n, respectively:
80 ≦l+m+n ≦100 (1)
5≦m≦90 (2)
20≦n≦90 (3)
R 1 : an aromatic group, and
R 2 : a para-directed phenylene group, provided that each of the hydrogen atoms at 2-, 3-, 5- and 6-positions of an aromatic ring may be substituted with another atom or substituent;
R 3 : an aromatic group having 12 or more carbon atoms which has at least one substituent selected from the group consisting of an ether group (—O—), a methylene group (—CH 2 —) and a sulfone group (—SO 2 —), and
R 4 : a para-directed phenylene group, provided that each of the hydrogen atoms at 2-, 3-, 5- and 6-positions of an aromatic ring may be substituted with another atom or substituent;
R 5 : 2, 6-naphthalene group, and
R 6 : a para-directed phenylene group, provided that each of the hydrogen atoms at 2-, 3-, 5- and 6-positions of an aromatic ring may be substituted with another atom or substituent.
9. An aromatic polymer wherein the aromatic polymer according to claim 8 has been modified with a polar group.
10. The aromatic polymer according to claim 9 , wherein the polar group is a sulfonic acid and/or a phosphonic acid.
11. An electrolyte membrane comprising the aromatic polymer according to claim 9 .
12. A fuel cell using the electrolyte membrane according to claim 11 .
13. A film comprising the aromatic polymer according to claim 9 .
14. An aromatic polymer/acid composite comprising the aromatic polymer according to claim 8 and an acid.
15. An electrolyte membrane comprising the aromatic polymer/acid composite according to claim 14 .
16. A fuel cell using the electrolyte membrane according to claim 15 .
17. A separator comprising the aromatic polymer according to claim 8 .
18. A fuel cell using the separator according to claim 17 .
19. A film comprising the aromatic polymer according to claim 8 .