Method of making an electroactive sensing/actuating material for carbon nanotube polymer composite
View Patent ↗An electroactive sensing or actuating material comprises a composite made from a polymer with polarizable moieties and an effective amount of carbon nanotubes incorporated in the polymer for a predetermined electromechanical operation of the composite when such composite is affected by an external stimulus. In another embodiment, the composite comprises a third component of micro-sized to nano-sized particles of an electroactive ceramic that is also incorporated in the polymer matrix. The method for making the three-phase composite comprises either incorporating the carbon nanotubes in the polymer matrix before incorporation of the particles of ceramic or mixing the carbon nanotubes and particles of ceramic together in a solution before incorporation in the polymer matrix.
1. A method of making an electroactive sensing/actuating material, comprising the steps of:
providing a polymer with polarizable moieties;
incorporating an effective amount of carbon nanotubes in said polymer that provides for a predetermined electromechanical operation of said polymer with said carbon nanotubes incorporated therein when an external stimulus is applied thereto; and
incorporating nano-sized particles of an electroactive ceramic in said polymer in addition to said carbon nanotubes, wherein a ratio of dielectric constant of said ceramic to dielectric constant of said polymer is at least 50:1, and wherein said nanotubes are incorporated in said polymer in an effective amount that provides a dielectric constant for said composite that is greater than said dielectric constant of said polymer while simultaneously providing for said predetermined electromechanical operation of said composite.
2. A method according to claim 1 wherein said carbon nanotubes are incorporated in said polymer before said nano-sized particles of ceramic are incorporated therein.
3. A method according to claim 1 further comprising the steps of:
mixing said carbon nanotubes and said nano-sized particles of ceramic together to form a mixture; and
incorporating said mixture in said polymer.
4. A method according to claim 1 wherein said polymer with said carbon nanotubes and said nano-sized particles of electroactive ceramic incorporated therein define a composite, said method further comprising the step of poling said composite.
5. A method according to claim 1 further comprising the step of incorporating micro-sized particles of an electroactive ceramic in said polymer in addition to said carbon nanotubes.
6. A method according to claim 5 wherein said carbon nanotubes are incorporated in said polymer before said micro-sized particles of ceramic are incorporated therein.
7. A method according to claim 5 further comprising the steps of:
mixing said carbon nanotubes and said micro-sized particles of ceramic together to form a mixture; and
incorporating said mixture in said polymer.
8. A method according to claim 5 wherein said polymer with said carbon nanotubes and said micro-sized particles of electroactive ceramic incorporated therein define a composite, said method further comprising the step of poling said composite.