Ink composition and ink cartridge including the ink composition
An ink composition comprising a colorant, a solvent, a surfactant, and a defoaming agent is provided. The defoaming agent has a structure of Formula R 1 —X—(CH 2 CH 2 O) m -(CHCH 3 CH 2 O) n -R 2 (I), in which, X is selected from the group consisting of COO, O, S, R 3 —N and R 4 (R 5 )—C; R 1 , R 2 , R 3 , R 4 , and R 5 are each independently selected from the group consisting of a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted aryl group and a substituted or unsubstituted aralkyl group; m is an integer from 0 to 100; and n is a natural number from 1 to 100. The ink composition according to the exemplary embodiment exhibits low foaming properties in order to flow smoothly and has a good initial discharge capacity and less ink bleeding so that it is possible to achieve a high print quality during printing, and an ink cartridge including the same.
1. An ink composition comprising a colorant, a solvent, a surfactant, and a defoaming agent, wherein the defoaming agent has a structure as in Formula (I),
R 1 —X—(CH 2 CH 2 O) m -(CHCH 3 CH 2 O) n -R 2 (I)
in which, X is selected from the group consisting of COO, S, R 3 —N and R 4 (R 5 )—C; R 1 , R 2 , R 3 , R 4 , and R 5 are each independently selected from the group consisting of a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted aryl group and a substituted or unsubstituted aralkyl group;
m is an integer from 0 to 100; and
n is a natural number from 1 to 100.
2. The ink composition as claimed in claim 1 , wherein m is an integer from 0 to 50 and n is a natural number from 1 to 50.
3. The ink composition as claimed in claim 1 , wherein the colorant is either a dye or a pigment.
4. The ink composition as claimed in claim 3 , wherein the dye is selected from the group consisting of direct dyes, acid dyes, edible dyes, alkaline dyes, reactive dyes, disperse dyes, and oily dyes.
5. The ink composition as claimed in claim 3 , wherein the dye is selected from the group consisting of azo dyes, anthraquinone dyes, indigo dyes, phthalocyanine dyes, carbonyl dyes, quinoneimine dyes, methine dyes, quinoline dyes, and nitro dyes.
6. The ink composition as claimed in claim 3 , wherein the pigment is an inorganic pigment selected from the group consisting of titanium oxide, iron oxide (Bengala), antimony red, cadmium red, cadmium yellow, cobalt blue, carbon black and graphite, or an organic pigment selected from the group consisting of azo pigments.
7. The ink composition as claimed in claim 1 , wherein the colorant is contained in an amount from about 0.5% by weight to about 10% by weight based on the weight of the ink composition.
8. The ink composition as claimed in claim 1 , wherein the solvent is selected from the group consisting of water, a water-soluble or water-miscible organic solvent and mixtures thereof.
9. The ink composition as claimed in claim 8 , wherein the water-soluble or water-miscible organic solvent is selected from the group consisting of an aliphatic monohydric alcohol, an aliphatic polyhydric alcohol and a derivative of the aliphatic polyhydric alcohol.
10. The ink composition as claimed in claim 9 , wherein the aliphatic monohydric alcohol is selected from the group consisting of methyl alcohol, ethyl alcohol, n-propyl alcohol, i-propyl alcohol, n-butyl alcohol, s-butyl alcohol and t-butyl alcohol.
11. The ink composition as claimed in claim 9 , wherein the aliphatic polyhydric alcohol is selected from the group consisting of alkylene glycols, polyalkylene glycols, thiodiglycols; and mixtures thereof.
12. The ink composition as claimed in claim 11 , wherein said alkylene glycol is selected from the group consisting of ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, butylene glycol and glycerol.
13. The ink composition as claimed in claim 11 , wherein said polyalkylene glycol is selected from the group consisting of polyethylene glycol and polypropylene glycol.
14. The ink composition as claimed in claim 9 , wherein the derivative of the aliphatic polyhydric alcohol is selected from the group consisting of lower alkyl ethers of aliphatic polyhydric alcohols and lower carboxylic acid esters of aliphatic polyhydric alcohols.
15. The ink composition as claimed in claim 8 , wherein the water-soluble organic solvent is contained in an amount from about 1% by weight to about 40% by weight based on the weight of the ink composition.
16. The ink composition as claimed in claim 8 , wherein the solvent contains water and water-soluble organic solvent, and where the water-soluble organic solvent is contained in an amount from about 2% by weight to about 100% by weight based on the weight of the water.
17. The ink composition as claimed in claim 1 , wherein the surfactant is at least one selected from the group consisting of a cationic surfactant, an anionic surfactant and a nonionic surfactant.
18. The ink composition as claimed in claim 17 , wherein the nonionic surfactant comprises one of ethoxylated acetylenic diol, polyethylene oxide, polypropylene oxide, and polyoxyethylene sorbitan fatty acid ester.
19. The ink composition as claimed in claim 1 , wherein the surfactant is included in an amount of about 0.05% by weight to about 3% by weight based on the weight of the ink composition.
20. The ink composition as claimed in claim 1 , wherein the defoaming agent is selected from the group consisting of polypropylene glycol fatty acid esters, polyoxyalkylene amines, and polypropylene dialkylaminoalkyl ethers.
21. The ink composition as claimed in claim 1 , wherein in Formula (I), R 1 , R 2 , R 3 , R 4 , and R 5 are hydrocarbon groups having 1 to 40 carbon atoms.
22. The ink composition as claimed in claim 1 , wherein the alkyl group is selected from the group consisting of a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, a heptyl group, an octyl group, a nonyl group, a decyl group, a dodecyl group, a tetradecyl group, a hexadecyl group, and an octadecyl group.
23. The ink composition as claimed in claim 1 , wherein the cycloalkyl group is a cyclohexyl group.
24. The ink composition as claimed in claim 1 , wherein the alkenyl group is a vinyl group or an allyl group.
25. The ink composition as claimed in claim 1 , wherein the aryl group is selected from the group consisting of a phenyl group, a tolyl group, a naphthyl group, and a biphenyl group.
26. The ink composition as claimed in claim 1 , wherein the aralkyl group is either a 2-phenylethyl group or a 2-methyl-2-phenylethyl group.
27. The ink composition as claimed in claim 1 , wherein the defoaming agent is contained in an amount from about 0.01% by weight to about 3% by weight based on the weight of the ink composition.
28. The ink composition as claimed in claim 1 , further comprising at least one additive selected from the group consisting of a dispersant, a viscosity modifier, a pH modifier, an antiseptic and a chelating agent.
29. An ink cartridge comprising:
an ink storage part which stores an ink composition; and
an ink ejection part which ejects the ink composition,
wherein the ink composition comprises a colorant, a solvent, a surfactant, and a defoaming agent, in which the defoaming, agent has a structure as in Formula (I),
R 1 —X—(CH 2 CH 2 O) m -(CHCH 3 CH 2 O) n -R 2 (I)
in which, X is selected from the group consisting of COO, S, R 3 —N and R 4 (R 5 )—C;
R 1 , R 2 , R 3 , R 4 , and R 5 are each independently selected from the group consisting of a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted aryl group and a substituted or unsubstituted aralkyl group;
m is an integer from 0 to 100; and
n is a natural number from 1 to 100.
30. An ink composition comprising a colorant, a solvent, a surfactant, and a defoaming agent, wherein the defoaming agent has a structure as in Formula (I),
R 1 —X—(CH 2 CH 2 O) m -(CHCH 3 CH 2 O) n -R 2 (I)
in which, X is selected from the group consisting of COO, O, S, R 3 —N and R 4 (R 5 )—C; R 1 , R 2 , R 3 , R 4 , and R 5 are each independently selected from the group consisting of a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted aryl group and a substituted or unsubstituted aralkyl group;
m is an integer from 0 to 100; and
n is a natural number from 1 to 100.