Optical film composite having spatially controlled adhesive strength
The present invention generally relates to optical films useful in the manufacture of polarizer plates, an improved method for producing polarizing plates, and a Liquid Crystal Display employing the same. More particularly, the invention relates to an optical film composite comprising a temporary carrier substrate having a center area and an edge area, said substrate having coated thereon an optical film wherein the adhesive strength between the optical film and the substrate is greater at the edge area than at the center area of the substrate.
1. An optical film composite comprising a temporary carrier substrate having a center area and an edge area, said substrate having coated thereon an optical film wherein the adhesive strength between the optical film and the substrate is greater at the edge area than at the center area of the substrate.
2. The optical film composite of claim 1 wherein the composite is in the form of a roll.
3. The optical film composite of claim 2 wherein the roll has a leading end area and a trailing end area and wherein the adhesive strength is also greater at the leading end area and the trailing end area than at the center area.
4. The optical film composite of claim 1 wherein the adhesive strength at the edge area is greater than the adhesive strength at the center area by a factor of at least 10.
5. The optical film composite of claim 1 wherein the adhesive strength at the edge area is greater than the adhesive strength at the center area by a factor of at least 50.
6. The optical film composite of claim 1 wherein the adhesive strength at the edge area is greater than the adhesive strength at the center area by a factor of at least 200.
7. The optical film composite of claim 1 wherein the varying adhesive strength is created by a surface energy treatment of the edge area of the substrate.
8. The optical film composite of claim 1 wherein the substrate comprises a release layer located adjacent to the optical film, said release layer covering substantially all of the center area of the substrate.
9. The optical film composite of claim 8 wherein the release layer comprises a silicone containing polymer.
10. The optical film composite of claim 1 wherein the optical film comprises a low birefringence polymer film.
11. The optical film composite of claim 10 wherein the low birefringence polymer film is from 5 to 30 microns thick.
12. The optical film composite of claim 1 wherein the optical film comprises a peelable layer located adjacent to the substrate, said peelable layer covering substantially all of the center area of the substrate.
13. The optical film composite of claim 12 wherein the peelable layer is an adhesive layer.
14. The optical film composite of claim 13 wherein the adhesive layer is polyvinyl alcohol.
15. The optical film composite of claim 1 wherein the optical film is a polarizer cover sheet.
16. The optical film composite of claim 1 wherein the optical film is triacetylcellulose, polycarbonate or a cyclic olefin polymer.
17. The optical film composite of claim 1 wherein the optical film further comprises a compensation layer or an abrasion resistant hard coat.
18. The optical film composite of claim 1 wherein the substrate is polyethyleneterephthalate.
19. The optical film composite of claim 1 wherein substrate comprises a subbing layer on the edge areas adjacent to the optical film.
20. The optical film composite of claim 19 wherein the subbing layer comprises vinylidene chloride.
21. The optical film composite of claim 1 wherein the edge area comprises at least two percent of the substrate area.
22. The optical film composite of claim 1 wherein the leading end and the trailing end are individually at least 5 meters in length.
23. The optical film of claim 1 wherein the optical film is coated on both sides of the substrate.
24. The optical film composite of claim 1 wherein the edge area of the substrate is chemically modified.
25. The optical film composite of claim 1 wherein the edge area of the substrate is roughened.
26. An optical film composite comprising a temporary carrier substrate having a center area and an edge area, said substrate having adhered to the center area and to the edge area an optical film, wherein the adhesive strength between the optical film and the substrate is greater at the edge area than at the center area of the substrate.
27. A method of manufacturing an optical film composite comprising a temporary carrier substrate having a center area and an edge area, and an optical film comprising a low birefringence polymer film, wherein the adhesive strength between the optical film and the substrate will be greater at the edge areas than at the center area of the substrate, said method comprising providing a precursor substrate; forming an edge area and a center area on the precursor substrate to provide a temporary carrier substrate wherein the center area has a different adhesive property than the edge area; and coating and drying at least an optical film composition comprising a low birefringence polymer on the substrate to form the optical film.
28. The method of manufacturing of claim 27 wherein the edge area of the precursor substrate is subjected to a surface energy treatment.
29. The method of manufacturing of claim 28 wherein the surface energy treatment is a corona discharge treatment.
30. The method of manufacturing of claim 28 wherein a release layer is coated on the center area of the precursor substrate to form the temporary carrier substrate.
31. The method of manufacturing of claim 27 wherein a peelable layer is applied to the center area of the substrate prior to coating the low birefringence polymer composition.
32. The method of manufacturing of claim 27 wherein a subbing layer is applied to the edge area of the precursor carrier substrate to form the temporary carrier substrate.
33. The method of manufacturing of claim 32 wherein the peelable layer is coated simultaneously with low birefringence polymer composition.
34. The method of manufacturing of claim 27 wherein the optical film composite is manufactured in the form of a roll.
35. The method of manufacturing of claim 34 comprising forming a leading end area and a trailing end area on said roll wherein the adhesive strength is greater on the leading end area and the trailing end area than on the center area.
36. The method of manufacturing of claim 27 wherein adhesive strength in the edge area is greater than the adhesive strength in the center area by a factor of at least 10.
37. The method of manufacturing of claim 27 wherein adhesive strength in the edge area is greater than the adhesive strength in the center area by a factor of at least 50.
38. The method of manufacturing of claim 27 wherein adhesive strength in the edge area is greater than the adhesive strength in the center area by a factor of at least 200.
39. The method of manufacturing of claim 27 further comprising slitting the edge area off of the optical film composite.
40. The method of manufacturing of claim 27 wherein the optical film composition comprises knurls in the center area.
41. The method of manufacturing of claim 27 wherein the optical film is a polarizer cover sheet.
42. The method of manufacturing of claim 27 wherein said method comprising providing a precursor substrate; forming an edge area and a center area on the precursor substrate on both side of the substrate to provide a temporary carrier substrate wherein the center area has a different adhesive property than the edge area; and coating and drying at least a low birefringence polymer composition on both sides of the substrate to form the optical film.
43. A method of providing an optical film comprising taking an optical film composite comprising a temporary carrier substrate and an optical film having a center area and an edge area wherein the adhesive strength between the optical film and the substrate will be greater at the edge areas than at the center area of the substrate; and removing the edge area.