Film for optical applications
A hard coat film for optical applications which suppresses formation of defects on the surface derived from roughness of the surface of the substrate film, exhibits excellent scratch resistance and crack resistance and suppresses curling of the substrate film is provided. The film for optical applications comprises (A) a layer of a cured resin 2 which comprises 70% by weight or more of a cured resin derived from a difunctional urethane acrylate-based oligomer having a weight-average molecular weight of 3,000 or greater and has a thickness of 5 to 25 μm and (B) a hard coat layer 3 which comprises a resin cured by irradiation with an ionizing radiation and has a thickness of 1 to 15 μm, layers (A) and (B) being successively laminated on one face of a substrate film 1.
1. A film for optical applications which comprises (A) a layer of a cured resin which comprises 70% by weight or more of a cured resin derived from a difunctional urethane acrylate-based oligomer having a weight-average molecular weight in a range of 5,000 to 50,000 and has a thickness of 5 to 25 μm and (B) a hard coat layer which comprises a resin cured by irradiation with an ionizing radiation and has a thickness of 1 to 15 μm, layers (A) and (B) being successively laminated on one face of a substrate film.
2. The film according to claim 1 , which comprises (C) a layer for preventing reflection of light comprising at least one layer and laminated on layer (B).
3. The film according to claim 1 , wherein the substrate film is an acetylcellulose-based film, a polycarbonate-based film, a cyclic polyolefin-based film, an acrylic resin-based film or a polyester-based film.
4. The film according to claim 2 , wherein the substrate film is an acetylcellulose-based film, a polycarbonate-based film, a cyclic olefin-based film, an acrylic resin-based film or a polyester-based film.
5. The film according to claim 1 , wherein the hard coat layer of layer (B) has a refractive index of 1.49 to 1.65.
6. The film according to claim 2 , wherein the hard coat layer of layer (B) has a refractive index of 1.49 to 1.65.
7. The film according to claim 3 , wherein the hard coat layer of layer (B) has a refractive index of 1.49 to 1.65.
8. The film according to claim 4 , wherein the hard coat layer of layer (B) has a refractive index of 1.49 to 1.65.
9. The film according to claim 1 , which further comprises an adhesive layer having a thickness of 1 to 40 μm and disposed on another face of the substrate film.
10. The film according to claim 2 , which further comprises an adhesive layer having a thickness of 1 to 40 μm and disposed on another face of the substrate film.
11. The film according to claim 3 , which further comprises an adhesive layer having a thickness of 1 to 40 μm and disposed on another face of the substrate film.
12. The film according to claim 4 , which further comprises an adhesive layer having a thickness of 1 to 40 μm and disposed on another face of the substrate film.
13. The film according to claim 5 , which further comprises an adhesive layer having a thickness of 1 to 40 μm and disposed on another face of the substrate film.
14. The film according to claim 6 , which further comprises an adhesive layer having a thickness of 1 to 40 μm and disposed on another face of the substrate film.
15. The film according to claim 7 , which further comprises an adhesive layer having a thickness of 1 to 40 μm and disposed on another face of the substrate film.
16. The film according to claim 8 , which further comprises an adhesive layer having a thickness of 1 to 40 μm and disposed on another face of the substrate film.
17. The film according to claim 1 , wherein the layer (A) comprises 90% by weight or more of the cured resin.
18. The film according to, claim 1 , wherein the difunctional urethane acrylate-based oligomer has a weight-average molecular weight in a range of 5,000 to 35,000.
19. A film for optical applications which comprises (A) a layer of a cured resin which consists essentially of a cured resin derived from a difunctional urethane acrylate-based oligomer having a weight-average molecular weight in a range of 5,000 to 50,000 and has a thickness of 5 to 25 μm and (B) a hard coat layer which comprises a resin cured by irradiation with an ionizing radiation and has a thickness of 1 to 15 μm, layers (A) and (B) being successively laminated on one face of a substrate film.
20. The film according to claim 19 , wherein layer (A) further comprises 30% by weight or less of cured resins derived from at least one oligomer selected from the group consisting of a urethane acrylate oligomer having a functionality of three or greater, a polyester acrylate oligomer, an epoxy acrylate oligomer and a polyol acrylate oligomer.