Electroluminescent device
A method of forming an electroluminescent device comprising the steps of: providing a substrate comprising a first electrode for injecting charge carriers of a first type; forming an electroluminescent layer having a surface by depositing onto the substrate a composition comprising a host material and a light-emitting dopant monomer of formula (I): A-C—(X) n (I) wherein X represents a polymerisable group; A represents a light-emitting group; C represents a bond or a spacer group and n is an integer; rendering at least some of the electroluminescent layer insoluble in a solvent by polymerising the monomer of formula (I); exposing the electroluminescent layer to the solvent; and depositing a second electrode capable of injecting charge carriers of a second type over the electroluminescent layer.
1. A method of forming an electroluminescent device comprising:
providing a substrate comprising a first electrode for injecting charge carriers of a first type;
forming an electroluminescent layer having a surface by depositing onto the substrate a composition comprising a host material, a light-emitting dopant monomer of formula (I) and a second polymerisable group Y for copolymerization with X, one of X and Y being an optionally substituted thiol and the other is a group comprising a reactive unsaturated carbon-carbon bond:
A-C—(X) n (I)
wherein X represents a polymerisable group; A represents a light-emitting group; C represents a bond or a spacer group; and n is 1;
rendering at least some of the electroluminescent layer insoluble in a solvent by polymerising the monomer of formula (I);
exposing the electroluminescent layer to the solvent; and
depositing a second electrode capable of injecting charge carriers of a second type over the electroluminescent layer.
2. A method according to claim 1 , wherein the host material is bound to a further first polymerisable group X or the second polymerisable group Y.
3. A method according to claim 1 wherein the light-emitting group is a phosphorescent compound.
4. A method according to claim 1 , wherein the polymerising the monomer of formula (I) comprises exposing only some of the surface of the electroluminescent layer to UV light such that only the portion of the surface of the electroluminescent layer that is exposed to UV light rendered insoluble to the solvent and the exposing the electroluminescent layer to the solvent results in soluble material being washed away to leave a patterned insoluble electroluminescent layer.
5. A method according to claim 1 , wherein the entire surface of the electroluminescent layer is rendered insoluble.
6. A method according to claim 4 , wherein the exposing the electroluminescent layer to the solvent comprises forming an electroactive layer by depositing over the electroluminescent layer a composition comprising the solvent and an electroactive material.