Fluorine-containing resin composition inhibiting corrosiveness
The present invention relates to a fluorine-containing resin composition for molding comprising a fluorine-containing resin (A) and a hydrofluoric acid scavenger (B), in which the hydrofluoric acid scavenger (B) is organopolysiloxane. According to the present invention, a fluorine-containing resin composition which can reduce an amount of hydrofluoric acid released from a fluorine-containing resin and inhibits corrosiveness can be provided.
1. A fluorine-containing resin composition for molding, comprising a fluorine-containing resin (A) which comprises a perfluororesin and a hydrofluoric acid scavenger (B), said hydrofluoric acid scavenger (B) being an organopolysiloxane.
2. The composition of claim 1 , wherein said hydrofluoric acid scavenger (B) is contained in an amount of not less than 1 part by mass and less than 30 parts by mass based on 100 parts by mass of the fluorine-containing resin (A).
3. The composition of claim 2 , wherein said fluorine-containing resin (A) comprises a copolymer comprising a tetrafluoroethylene unit and a unit of a perfluoro ethylenically unsaturated compound represented by the formula (1):
CF 2 ═CF—R f 1 (1)
wherein R f 1 represents —CF 3 and/or —OR f 2 ; R f 2 represents a perfluoroalkyl group having 1 to 5 carbon atoms.
4. The composition of claim 1 , wherein said fluorine-containing resin (A) comprises a fluorine-containing ethylenic polymer (a) having a carbonyl group-containing end group.
5. The composition of claim 3 , wherein said fluorine-containing resin (A) comprises a fluorine-containing ethylenic polymer (a) having a carbonyl group-containing end group.
6. The composition of claim 4 , wherein said fluorine-containing ethylenic polymer (a) has a melting point of 120° to 310° C.
7. The composition of claim 5 , wherein said fluorine-containing ethylenic polymer (a) has a melting point of 120° to 310° C.
8. The composition of claim 1 , wherein the organopolysiloxane which is the hydrofluoric acid scavenger (B) is at least one kind selected from the group consisting of diorganopolysiloxane, silicone resin, crosslinkable silicone rubber composition and crosslinked silicone rubber particles.
9. The composition of claim 2 , wherein the organopolysiloxane which is the hydrofluoric acid scavenger (B) is at least one kind selected from the group consisting of diorganopolysiloxane, silicone resin, crosslinkable silicone rubber composition and crosslinked silicone rubber particles.
10. The composition of claim 5 , wherein the organopolysiloxane which is the hydrofluoric acid scavenger (B) is at least one kind selected from the group consisting of diorganopolysiloxane, silicone resin, crosslinkable silicone rubber composition and crosslinked silicone rubber particles.
11. The composition of claim 3 , wherein the organopolysiloxane which is the hydrofluoric acid scavenger (B) is at least one kind selected from the group consisting of diorganopolysiloxane, silicone resin, crosslinkable silicone rubber composition and crosslinked silicone rubber particles.
12. The composition of claim 4 , wherein the organopolysiloxane which is the hydrofluoric acid scavenger (B) is at least one kind selected from the group consisting of diorganopolysiloxane, silicone resin, crosslinkable silicone rubber composition and crosslinked silicone rubber particles.
13. The composition of claim 6 , wherein the organopolysiloxane which is the hydrofluoric acid scavenger (B) is at least one kind selected from the group consisting of diorganopolysiloxane, silicone resin, crosslinkable silicone rubber composition and crosslinked silicone rubber particles.