Compound, solid polymer electrolyte membrane, electrolyte membrane-electrode assembly, and solid polymer fuel cell
An unsaturated compound including a urethane bond in a main chain and a sulfonic acid group, a phosphoric acid group, an alkylsulfonic acid group, or an alkylphosphoric acid group on a benzene ring in a side chain is provided. In addition, a solid polymer electrolyte membrane containing a compound prepared by polymerizing the above-mentioned compound and an electrolyte membrane-electrode assembly including diffusion layers adhered on both surfaces of the electrolyte membrane are provided. Furthermore, a solid polymer fuel cell using the electrolyte membrane-electrode assembly is provided.
1. A solid polymer electrolyte membrane comprising a compound having one or more side chains and a main chain, wherein the side chain comprises a structure represented by Formula II and the main chain comprises a structure represented by Formula III:
wherein R 5 represents a substituted or unsubstituted alkyl group having 1 to 6 carbon atoms or a hydrogen atom; X represents —SO 3 H, —PO 3 H 2 , —PO 4 H 2 , —R 8 SO 3 H, —R 8 PO 3 H 2 , or —R 8 PO 4 H 2 , where R 8 represents a substituted or unsubstituted alkylene group having 1 to 6 carbon atoms; R 1 represents a methyl group or a hydrogen atom; R 9 represents a substituted or unsubstituted alkanetriyl group having 2 to 10 carbon atoms; and n is an integer of 1 to 5 and m is an integer of 0 to 4, where n+m is 5.
2. The solid polymer electrolyte membrane according to claim 1 , wherein the compound having one more side chains and a main chain is a polymer of a compound represented by Formula I:
wherein, R 1 and R 2 may be the same or different, each representing a methyl group or a hydrogen atom; R 3 and R 4 may be the same or different, each representing a substituted or unsubstituted alkanetriyl group having 2 to 10 carbon atoms; R 5 and R 6 may be the same or different, each representing a substituted or unsubstituted alkyl group having 1 to 6 carbon atoms or a hydrogen atom; R 7 represents a substituted or unsubstituted alkylene group having 1 to 6 carbon atoms or a substituted or unsubstituted phenylene group; X represents —SO 3 H, —PO 3 H 2 , —PO 4 H 2 , —R 8 SO 3 H, —R 8 PO 3 H 2 , or —R 8 PO 4 H 2 , where R 8 represents a substituted or unsubstituted alkylene group having 1 to 6 carbon atoms; and n and n′ are each independently an integer of 1 to 5, and m and m′ are each independently an integer of 0 to 4, where n+m is 5 and n′+m′ is 5.
3. The solid polymer electrolyte membrane according to claim 1 , comprising an electrolyte component and a porous polymer membrane for holding the electrolyte component, wherein the electrolyte component comprises the compound having one or more side chains and the main chain.
4. The solid polymer electrolyte membrane according to claim 3 , wherein the porous polymer membrane is a polyimide.
5. An electrolyte membrane-electrode assembly comprising a solid polymer electrolyte membrane according to claim 1 and an electrode.
6. A solid polymer fuel cell comprising a solid polymer electrolyte membrane according to claim 1 .