IP Library Granted Patent US 7,922,859
Granted Patent B2
US 7,922,859 · App. 11/665,748 · Granted Apr 12, 2011

Laser-weldable polymers

Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
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Quick Facts
Patent No.
US 7,922,859
App. No.
11/665,748
Granted
Apr 12, 2011
Kind
B2
Abstract

The present invention relates to laser-weldable polymers which consist of a laser-transparent part and a laser-absorbent part and can be welded to one another by means of laser light and are distinguished by the fact that the laser-absorbent part comprises, as absorber, copper hydroxide phosphate and/or copper phosphate.

Claims (18)

1. A laser-weldable polymer consisting of a laser-transparent part and a laser-absorbent part, which can be welded to one another by laser light, wherein the laser-absorbent part comprises, as absorber, copper hydroxide phosphate and/or copper phosphate, wherein both the laser-absorbent part and the laser-transparent part comprise an absorber such that the laser-absorbent part comprises a 2 to 20 times larger amount of absorber than the laser-transparent part.

2. A laser-weldable polymer according to claim 1 , wherein the copper hydroxide phosphate or copper phosphate is Cu 3 (PO 4 ) 2 *2Cu(OH) 2 (CHP=libethenite), Cu 3 (PO 4 ) 2 *Cu(OH) 2 , Cu 2 P 2 O 7 *H 2 O, 4CuO*P 2 O 5 *H 2 O, 5CuO*P 2 O 5 *3H 2 O, 6CuO*P 2 O 5 *3H 2 O, 4CuO*P 2 O 5 *3H 2 O, 4CuO*P 2 O 5 * 1.2 H 2 O, 4 CuO*P 2 O 5 , or 4CuO*P 2 O 5 *1.5 H 2 O.

3. A laser-weldable polymer according to claim 1 , wherein the laser-absorbent part comprises copper hydroxide phosphate and/or copper phosphate in an amount of 0.5-10% by weight, based on the laser-absorbent part.

4. A laser-weldable polymer according to claim 1 , wherein the laser-transparent part comprises a laser-scattering absorber.

5. A laser-weldable polymer according to claim 4 , wherein the laser-scattering absorber is a conductive pigment, antimony, Sb 2 O 3 , (Sn,Sb)O 2 , (Sn,Sb)O 2 -coated mica, (Sn,Sb)O 2 - or SiO 2 -coated mica, TiO 2 -coated mica pigment, copper hydroxide phosphate or copper phosphate, or a combination thereof.

6. A laser-weldable polymer according to claim 4 , wherein the laser-scattering absorber is present in the laser-transparent part in an amount of 0.001-2% by weight, based on the laser-transparent part.

7. A laser-weldable polymer according to claim 1 , wherein the laser-transparent part comprises a laser-scattering additive.

8. A laser-weldable polymer according to claim 7 , wherein the laser-scattering additive is TiO 2 , CaCO 3 , MgCO 3 , glass beads or a mixture thereof.

9. A laser-weldable polymer according to claim 7 , wherein the laser-scattering additive is present in the laser-transparent part in amounts of ≦1% by weight, based on the laser-transparent part.

10. A laser-weldable polymer according to claim 1 , wherein the laser-weldable polymer parts are welded using a diode laser or Nd:YAG laser.

11. A laser-weldable polymer according to claim 1 , wherein the laser-weldable polymer is a thermoplastic.

12. A laser-weldable polymer according to claim 1 , wherein the polymer is a polyolefin, polyamide (PA), polyester, polyether, polyphenylene ether, polyacrylate, polyurethane (PU), polyoxymethylene (POM), polymethacrylate, polymethyl methacrylate (PMMA), polyvinyl acetate (PVAC), polyvinyl acetal (PVB), polystyrene (PS), acrylonitrile-butadiene-styrene (ABS), acrylonitrile-styrene-acrylate (ASA), ABS graft polymer, polyalkylene terephthalate, polyvinyl chloride (PVC), polyvinylidene chloride (PVDC), polyvinylidene fluoride (PVDF), polytetrafluoroethylene (PTFE), polycarbonate (PC), polyether sulfone, polyether ketone, thermoplastic polyurethane (TPU), thermoplastic elastomer (PTE) or a copolymer thereof and/or a mixture thereof.

13. A laser-weldable polymer according to claim 1 , wherein both the laser-absorbent part and the laser-transparent part comprise an absorber such that the laser-absorbent part comprises a 10 times larger amount of absorber than the laser-transparent part.

14. A laser-weldable polymer according to claim 1 , wherein both the laser-absorbent part and the laser-transparent part comprise an absorber such that the laser-absorbent part comprises a 5 to 10 times larger amount of absorber than the laser-transparent part.

15. A laser-weldable polymer according to claim 1 , which is transparent.

16. A laser-weldable polymer according to claim 1 , which is pale in color.

17. A process for preparing a laser-weldable polymer according to claim 1 , comprising adding the absorber and optionally further additives and auxiliaries to the laser-absorbent part and optionally to the laser-transparent part, and then shaping the polymer under the action of heat.

18. A method for laser-transmissive welding, comprising subjecting a laser-weldable polymer according to claim 1 to transmissive laser welding.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 28, 2025
From: MERCK PATENT GMBH
To: SUSONITY COMMERCIAL GMBH
Reel/Frame 072287/0400 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 19, 2007
From: ROSENBERER, SILVIA
To: MERCK PATENT GMBH
Reel/Frame 019219/0248 →
Priority Claims (1)
DE 10 2004 051 246 · Oct 20, 2004 · national
Continuity (1)
Related Publication 20080004363A1 · Jan 3, 2008