Process for preparing conductive material
It is to provide a process for preparing a conductive material in which transparency and conductivity are both high, and storage stability is high, and further, in a process for preparing a conductive material utilizing ultra fine silver particles, to provide a process for preparing a conductive material having high conductivity without requiring a calcination step which has conventionally been required. A process for preparing a conductive material having a conductive pattern containing silver on a support, which process for preparing a conductive material comprises acting at least one of the following mentioned (I) to (IV) on the pattern portion containing silver provided on the support: (I) a reducing substance, (II) a water-soluble phosphorus oxo acid compound, (III) a water-soluble halogen compound, (IV) warm water of 55° C. or higher.
1. A process for preparing a conductive material having a conductive pattern containing silver on a support, which process for preparing a conductive material comprises acting at least one of the following mentioned (I) to (IV) on the pattern portion containing silver provided on the support:
(I) a reducing substance
(II) a water-soluble phosphorus oxo acid compound
(III) a water-soluble halogen compound
(IV) warm water of 55° C. or higher.
2. The process for preparing a conductive material according to claim 1 , wherein the pattern portion containing silver provided on the support is a pattern portion containing silver formed by pattern-wisely exposing a silver salt light-sensitive material having at least one silver halide emulsion layer on the support, and subjecting to development.
3. The process for preparing a conductive material according to claim 2 , wherein a half-value width of a peak at 2θ=38.2° of an obtained conductive pattern by an X-ray diffraction method is 0.41 or less.
4. The process for preparing a conductive material according to claim 1 , wherein the pattern portion containing silver provided on the support is a pattern portion containing silver formed by providing ultra fine silver particles which have been dispersed in water and/or an organic solvent as a metal colloid to the support.
5. The process for preparing a conductive material according to claim 4 , wherein the support has a porous layer comprising inorganic fine particles and a binder in an amount of 80% by weight or less based on the amount of the inorganic fine particles on the substrate.
6. The process for preparing a conductive material according to claim 4 , wherein at least one of the above-mentioned (I) to (IV) is acted on the pattern portion containing silver provided on the support, and then water is further supplied to.
7. The process for preparing a conductive material according to claim 1 , wherein (I) the reducing substance is a substance which can reduce a silver ion selected from the group consisting of polyhydroxybenzenes, ascorbic acid and its derivative(s), 3-pyrazolidones, aminophenols, polyaminobenzenes and hydroxylamines.
8. The process for preparing a conductive material according to claim 7 , wherein (I) the reducing substance is ascorbic acid.
9. The process for preparing a conductive material according to claim 7 , wherein (I) the reducing substance is used as an aqueous solution having a temperature which is 40° C. or higher but no greater than the Tg of the support.
10. The process for preparing a conductive material according to claim 1 , wherein (II) the water-soluble phosphorus oxo acid compound is selected from the group consisting of phosphorus oxo acids, a salt thereof, and an ester compound thereof.
11. The process for preparing a conductive material according to claim 10 , wherein (II) the water-soluble phosphorus oxo acid compound is used as an aqueous solution having a temperature which is 40° C. or higher but no greater than the Tg of the support.
12. The process for preparing a conductive material according to claim 1 , wherein (III) the water-soluble halogen compound is selected from the group consisting of hydrogen halides, inorganic or organic salts thereof, and inorganic or organic polymerized halides.
13. The process for preparing a conductive material according to claim 12 , wherein (III) the water-soluble halogen compound is an inorganic salt of hydrogen halides.
14. The process for preparing a conductive material according to claim 12 , wherein (III) the water-soluble halogen compound is used as an aqueous solution having a temperature which is 30° C. or higher but no greater than the Tg of the support.
15. The process for preparing a conductive material according to claim 1 , wherein (IV) the warm water has a temperature which is 65° C. or higher but no greater than the Tg of the support.
16. The process for preparing a conductive material according to claim 2 , wherein the process is a development by a silver salt diffusion transfer method comprising the steps where an image is precipitated by the silver salt diffusion transfer development, then unnecessary silver halide emulsion layer is removed by a removal step by washing with water, and the conductive material is dried by a drying step, and the step of acting at least one of (I) to (IV) is carried out after completion of the removal step by washing with water and before the drying step.
17. The process for preparing a conductive material according to claim 16 , wherein washing is carried out after the step of acting at least one of (I) to (IV) so as to not precipitate the components of the solution of the step of acting at least one of (I) to (IV) on the surface of the conductive material, and then subjecting the conductive material to a drying treatment.
18. The process for preparing a conductive material according to claim 4 , wherein the step of acting at least one of (I) to (III) on the pattern portion containing silver is a method in which at least one of the substances (I) to (III) themselves or a layer containing at least one of the substances (I) to (III) is previously formed on a whole surface or a necessary portion of a support, and a desired pattern shape is formed thereon by using a metal colloid solution.
19. The process for preparing a conductive material according to claim 4 , wherein the step of acting at least one of (I) to (III) on the pattern portion containing silver is a method in which a desired pattern shape is formed on a support by using a metal colloid solution, then a solution containing at least one of the substances (I) to (III) is coated thereon, optionally by dipping.
20. The process for preparing a conductive material according to claim 4 , wherein the step of acting at least one of (I) to (III) on the pattern portion containing silver is a method in which a metal colloid solution and a solution containing at least one of the substances (I) to (III) are mixed immediately before providing them on a support, and a desired pattern is formed on the support by using the same.