Electrochromic device having controlled infrared reflection
The present invention relates to an electrochromic device having controlled infrared reflection, in particular of the electrically controllable type, comprising, between a carrier substrate ( 1 a ) transparent in the infrared range and a counter-substrate ( 1 b ), a multilayer stack. The device is characterized in that this multilayer stack comprises, in succession: a) a metal grid ( 3 ) transparent in the infrared range, forming a first electrode; b) an electrochromic functional system ( 5 ) comprising a layer (EC 1 ) of an ion-storage first electrochromic material, at least one layer (EL 1 , EL 2 ) having an electrolytic function, and a layer (EC 2 ) of a second electrochromic material; c) a metal layer ( 7 ) capable of reflecting the infrared radiation, forming a second electrode; and d) a lamination interlayer ( 9 ) made of a thermoplastic polymer.
1. An electrochromic device comprising, between a carrier substrate transparent in the infrared range and a counter-substrate, a multilayer stack, wherein the multilayer stack comprises, in succession:
a) a metal grid transparent in the infrared range, forming a first electrode;
b) an electrochromic functional system comprising a layer of an ion-storage first electrochromic material, at least one layer having an electrolytic function, and a layer of a second electrochromic material;
c) a metal layer capable of reflecting the infrared radiation, forming a second electrode; and
d) a lamination interlayer comprising a thermoplastic polymer, wherein
e) the substrate and the counter-substrate comprise, sapphire or silicon or germanium or zinc sulfide or zinc selenide or cadmium telluride, or calcium fluoride, or barium fluoride or magnesium fluoride, or glass transparent to infrared, or polyethylene,
wherein the electrochromic device has controlled infrared reflection.
2. The electrochromic device as claimed in claim 1 , wherein the substrate comprises sapphire and the counter-substrate comprises glass.
3. The electrochromic device as claimed in claim 1 , wherein the metal grid may be a monolayer or multilayer and may comprise aluminum and/or platinum and/or palladium and/or copper and/or gold and/or based on an alloy of these metals, and/or based on titanium nitride.
4. The electrochromic device as claimed in claim 1 , wherein the ion-storage layer comprises iridium oxide.
5. The electrochromic device as claimed in claim 1 , wherein the layer having an electrolytic function is a bilayer.
6. The electrochromic device as claimed in claim 5 , wherein the electrolytic layer comprises tantalum oxide and tungsten oxide.
7. The electrochromic device as claimed in claim 1 , wherein the lamination interlayer comprises polyvinyl butyral or ethylene vinyl/acetate, or polyurethane.
8. The electrochromic device as claimed in claim 1 , wherein the lamination interlayer ensures that a connection element bringing the current to the electrodes is supported.
9. A panel having controlled energy dissipation, wherein it comprises a device as claimed in claim 1 .
10. A panel as claimed in claim 9 , further comprising glazing.
11. An architectural glazing, automotive glazing, glazing for industrial vehicles or for rail, sea and air public vehicles, agricultural vehicles, building site machines, rear-view and other mirrors, displays and shutters for image acquisition devices, comprising the panel of claim 9 .