Lactic acid polymer composition, molded article comprising the composition and process for producing the molded article
To provide a lactic acid polymer composition excellent in transparency, heat resistance and productivity, a molded article, a sheet and a multilayer sheet each of which comprises the composition, a thermoformed article obtained by secondary-forming the sheet or the multilayer sheet, and a process for producing the thermoformed article with excellent productivity. The lactic acid polymer composition of the invention comprises 100 parts by weight of a lactic acid polymer (A), 0.1 to 3 parts by weight of an organic crystal nucleating agent (B) comprising an aliphatic carboxylic acid amide having an amide bond, and 0.1 to 7 parts by weight of a crystallization accelerator (C). The thermoformed article of the invention is obtained with excellent production efficiency by thermoforming the sheet comprising the composition of the invention at a temperature of 60 to 130° C.
1. A sheet comprising a lactic acid polymer composition, wherein the lactic acid polymer composition comprises 100 parts by weight of a lactic acid polymer (A), 0.1 to 3 parts by weight of an organic crystal nucleating agent (B) comprising an aliphatic carboxylic acid amide having an amide bond, and 0.1 to 7 parts by weight of a crystallization accelerator (C), and wherein the sheet has a crystallinity of 20% to 50% and a haze of not more than 15% based on the sheet thickness of 450 μm after the sheet is heated at a temperature of 60 to 130° C. for 1 to 15 seconds.
2. The sheet as claimed in claim 1 , wherein the mean dispersed particle diameter of the organic crystal nucleating agent (B) in the sheet after the sheet is heated at a temperature of 60 to 130° C. for 1 to 15 seconds is in the range of 0.01 to 1.0 μm.
3. A multilayer sheet comprising at least one layer of the sheet of claim 1 .
4. A process for producing a thermoformed article, comprising secondary-forming the multilayer sheet of claim 3 .
5. The process for producing a thermoformed article as claimed in claim 4 , wherein the secondary-forming is conducted by bringing the sheet into contact with a mold preset at a temperature of 90 to 130° C. for 1 to 15 seconds.
6. The process for producing a thermoformed article as claimed in claim 4 , wherein the thermoformed article has heat shrinkage resistance of not lower than 65° C.
7. A thermoformed article obtained by secondary-forming the multilayer sheet of claim 3 .
8. The thermoformed article as claimed in claim 7 , wherein the retention of volume of the thermoformed article is not less than 90% when the thermoformed article is kept at 90° C.
9. A thermoformed article obtained by secondary-forming the sheet of claim 1 .
10. The thermoformed article as claimed in claim 9 , wherein the retention of volume of the thermoformed article is not less than 90% when the thermoformed article is kept at 90° C.
11. A process for producing a thermoformed article, comprising secondary-forming the sheet of claim 1 .
12. The process for producing a thermoformed article as claimed in claim 11 , wherein-the secondary-forming is conducted by bringing the sheet into contact with a mold preset at a temperature of 90 to 130° C. for 1 to 15 seconds.
13. The process for producing a thermoformed article as claimed in claim 11 , wherein the thermoformed article has heat shrinkage resistance of not lower than 65° C.
14. The sheet as claimed in claim 1 , wherein the organic crystal nucleating agent (B) comprises an ethylenebiscarboxylic acid amide.
15. The sheet as claimed in claim 1 , wherein the content of the crystallization accelerator (C) is in the range of 0.5 to 7 parts by weight.
16. The sheet as claimed in claim 1 , wherein the lactic acid polymer (A) is polylactic acid.
17. The sheet as claimed in claim 1 , wherein the organic crystal nucleating agent (B) comprises a mixture of two or more kinds of ethylenebiscarboxylic acid amides.
18. The sheet as claimed in claim 1 , wherein the crystallization accelerator (C) is at least one compound selected from the group consisting of phthalic acid derivatives, isophthalic acid derivatives, adipic acid derivatives, maleic acid derivatives, citric acid derivatives, itaconic acid derivatives, oleic acid derivatives, ricinolic acid derivatives, phosphoric acid esters, hydroxypolycarboxylic acid esters and polyhydric alcohol esters.
19. A sheet comprising a lactic acid polymer composition, wherein the lactic acid polymer composition comprises 100 parts by weight of a lactic acid polymer (A), 0.1 to 3 parts by weight of an organic crystal nucleating agent (B) comprising a mixture of two or more kinds of aliphatic carboxylic acid amides having two or more amide bonds, and 0.1 to 7 parts by weight of a crystallization accelerator (C), and wherein the sheet has a crystallinity of 20% to 50% and a haze of not more than 15% based on the sheet thickness of 450 μm after the sheet is heated at a temperature of 60 to 130° C. for 1 to 15 seconds.
20. The sheet as claimed in claim 19 , wherein the mean dispersed particle diameter of the organic crystal nucleating agent (B) in the sheet after the sheet is heated at a temperature of 60 to 130° C. for 1 to 15 seconds is in the range of 0.01 to 1.0 μm.
21. A multilayer sheet comprising at least one layer of the sheet of claim 19 .
22. A thermoformed article obtained by secondary-forming the multilayer sheet of claim 21 .
23. The thermoformed article as claimed in claim 22 , wherein the retention of volume of the thermoformed article is not less than 90% when the thermoformed article is kept at 90° C.
24. A process for producing a thermoformed article, comprising secondary-forming the multilayer sheet of claim 21 .
25. The process for producing a thermoformed article as claimed in claim 24 , wherein the secondary-forming is conducted by bringing the sheet into contact with a mold preset at a temperature of 90 to 130° C. for 1 to 15 seconds.
26. The process for producing a thermoformed article as claimed in claim 24 , wherein the thermoformed article has heat shrinkage resistance of not lower than 65° C.
27. A thermoformed article obtained by secondary-forming the sheet of claim 19 .
28. The thermoformed article as claimed in claim 27 , wherein the retention of volume of the thermoformed article is not less than 90% when the thermoformed article is kept at 90° C.
29. A process for producing a thermoformed article, comprising secondary-forming the sheet of claim 19 .
30. The process for producing a thermoformed article as claimed in claim 29 , wherein the secondary-forming is conducted by bringing the sheet into contact with a mold preset at a temperature of 90 to 130° C. for 1 to 15 seconds.
31. The process for producing a thermoformed article as claimed in claim 29 , wherein the thermoformed article has heat shrinkage resistance of not lower than 65° C.
32. The sheet as claimed in claim 19 , wherein the lactic acid polymer (A) is polylactic acid.
33. The sheet as claimed in claim 19 , wherein the organic crystal nucleating agent (B) comprises a mixture of two or more kinds of ethylenebiscarboxylic acid amides.
34. The sheet as claimed in claim 19 , wherein the crystallization accelerator (C) is at least one compound selected from the group consisting of phthalic acid derivatives, isophthalic acid derivatives, adipic acid derivatives, maleic acid derivatives, citric acid derivatives, itaconic acid derivatives, oleic acid derivatives, ricinolic acid derivatives, phosphoric acid esters, hydroxypolycarboxylic acid esters and polyhydric alcohol esters.