IP Library Granted Patent US 8,252,721
Granted Patent B2
US 8,252,721 · App. 12/518,499 · Granted Aug 28, 2012

Herbicidal compositions

Assignee: ISEM S.r.l.
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 8,252,721
App. No.
12/518,499
Granted
Aug 28, 2012
Kind
B2
Abstract

A description follows of compositions with a herbicidal activity containing the compound having formula (I), mixed with one or more known herbicidal products, possibly stabilized by the addition of at least one inorganic or organic base, and the relative use for the control of weeds in agricultural crops.

Claims (99)

1. A herbicidal composition comprising a component [A] and a component [B], where component [A] is the compound having formula (I)

and component [B] comprises at least one known herbicide selected from the group consisting of:

propanil: N-(3,4-dichlorophenyl)propanamide;

pretilachlor: 2-chloro-N-(2,6-diethylphenyl)-N-(2-propoxyethyl)acetamide;

acetochlor: 2-choro-N-(ethoxymethyl)-N-(2-ethyl-6-methylphenyl)acetamide;

benzobicyclon: 3-[2-chloro-4-(methylsulfonyl)-benzoyl]-4-(phenylthio)bicyclo[3.2.1]oct-3-en-2-one;

bromobutide: 2-bromo-3,3-dimethyl-N-(1-methyl-1-phenylethyl)butaneamide;

carfentrazone-ethyl: ethyl α,2-dichloro-5-[4-(difluoromethyl)-4,5-dihydro-3-methyl-5-oxo-1H, 1,2,4-triazol-1-yl]-4-fluorobenzenepropanoate;

clomazone: 2-[(chlorophenyl)methyl]-4,4-dimethyl-3-isoxazolidinone;

2,4-D: (2,4-dichlorophenoxy)acetic acid, its esters and salts;

fentrazamide: N-cyclohexyl-N-ethyl-4-(2-chlorophenyl)-4,5-dihydro-5-oxo-1H-tetrazole-1-carboxamide;

imazethapyr: (±)-2-[4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl]-5-ethyl-3-pyridinecarboxylic acid;

pendimethalin: N-(1-ethylpropyl)-3,4-dimethyl-2,6-dinitrobenzeneamine;

quinclorac: 3,7-dichloro-8-quinolinecarboxylic acid;

atrazine: 6-chloro-N-ethyl-N′-(1-methylethyl)-1,3,5-triazine-2,4-diamine;

dicamba: 3,6-dichloro-2-methoxybenzoic acid and its salts;

glufosinate-ammonium: ammonium (±)-2-amino-4-(hydroxymethylphosphinyl)butanoate;

glyphosate: N-(phosphonomethyl)glycine and its salts;

halosulfuron: 3-chloro-5-[[[[(4,6-dimethoxy-2-pyrimidinyl)amino]carboyl]amino]sulfonyl]-1-methyl-1H-pyrazole-4-carboxylic acid and its methyl ester;

imazamox: 2-[4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl]-5-(methoxymethyl)-3-pyridine-carboxylic acid;

imazapic: 2-[4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl]-5-methyl-3-pyridinecarboxylic acid, its salts and esters;

metolachlor: 2-chloro-N-(2-ethyl-6-methyl-phenyl)-N-(2-methoxy-1-methylethyl)acetamide;

metsulfuron: 2-[[[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]benzoic acid and its methyl ester;

oxadiazon: 3-[2,4-dichloro-5-(1-methylethoxy)-phenyl]-5-(1,1-dimethylethyl-1,3,4-oxadiazol-2(3H)-one;

picloram: 4-amino-3,5,6-trichloro-2-pyridine-carboxylic acid and its potassium salt;

sulfentrazone: N-[2,4-dichloro-5-[4-(difluoromethyl)-4,5-dihydro-3-methyl-5-oxo-1H-1,2,4-triazol-1-yl]phenyl]methanesulfonamide;

triclopyr: [(3,5,6-trichloro-2-pyridinyl)oxy]-acetic acid, its esters and salts;

trifloxysulfuron: N-[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]-3-(2,2,2-trifluoroethoxy)-2-pyridinesulfonamide;

simazine: 6-chloro-N,N′-diethyl-1,3,5-triazine-2,4-diamine;

optionally in the presence of at least one inorganic or organic base.

2. The herbicidal composition according to claim 1 , wherein the ratio between the quantity by weight of component [A] and the quantity by weight of component(s) [B] ranges from 1:0.01 to 1:10,000.

3. The herbicidal composition according to claim 1 , wherein the applicative quantities of compound (I) are within the range of 5-200 g/ha.

4. The herbicidal composition according to claim 1 , wherein the applicative doses of component(s) [B] are within the range of 1-10,000 g/ha.

5. The herbicidal composition according to claim 1 , which is in the form of a dry powder, a wettable powder, an emulsifying concentrate, a micro-emulsion, a paste, a granule, a granule dispersible in water, a solution and a suspension.

6. The herbicidal composition according to claim 1 , which is in the form of a wettable powder, a granule, and a granule dispersible in water.

7. The herbicidal composition according to claim 1 , which is in the form of a already prepared formulation comprising component [A] and component(s) [B] and optionally the at least one inorganic or organic base; or which is prepared for use by mixing component [A] and component(s) [B], formulated separately and optionally with the at least one inorganic or organic base; or, mixing component [A], component(s) [B] or both [A] and [B] in which are in a partially or totally salified form.

8. The herbicidal composition according to claim 1 , further comprising at least one additional ingredient selected from the group consisting of a herbicide, an antidote, a fungicide, an insecticide, an acaricide, and a fertilizer.

9. The herbicidal composition according to claim 8 , wherein the concentration of active substances, also comprising [A]+[B], is from 1 to 90%.

10. The herbicidal composition according to claim 9 , wherein the concentration is from 5 to 75%.

11. A method for the control of weeds in agricultural crops comprising applying to said crops a herbicidal composition comprising a component [A] and a component [B], wherein component [A] is the compound having formula (I)

and component [B] comprises at least one herbicide selected from the group consisting of:

propanil: N-(3,4-dichlorophenyl)propanamide;

pretilachlor: 2-chloro-N-(2,6-diethylphenyl)-N-(2-propoxyethyl)acetamide;

acetochlor: 2-choro-N-(ethoxymethyl)-N-(2-ethyl-6-methylphenyl)acetamide;

benzobicyclon: 3-[2-chloro-4-(methyl-sulfonyl)-benzoyl]-4-(phenylthio)bicyclo[3.2.1]oct-3-en-2-one;

bromobutide: 2-bromo-3,3-dimethyl-N-(1-methyl-1-phenylethyl)butaneamide;

carfentrazone-ethyl: ethyl α,2-dichloro-5-[4-(difluoromethyl)-4,5-dihydro-3-methyl-5-oxo-1H, 1,2,4-triazol-1-yl]-4-fluorobenzenepropanoate;

clomazone: 2-[(chlorophenyl)methyl]-4,4-dimethyl-3-isoxazolidinone;

2,4-D: (2,4-dichlorophenoxy)acetic acid, its esters and salts;

fentrazamide: N-cyclohexyl-N-ethyl-4-(2-chlorophenyl)-4,5-dihydro-5-oxo-1H-tetrazole-1-carboxamide;

imazethapyr: (±)-2-[4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl]-5-ethyl-3-pyridinecarboxylic acid;

pendimethalin: N-(1-ethylpropyl)-3,4-dimethyl-2,6-dinitrobenzeneamine;

quinclorac: 3,7-dichloro-8-quinolinecarboxylic acid;

atrazine: 6-chloro-N-ethyl-N′-(1-methylethyl)-1,3,5-triazine-2,4-diamine;

dicamba: 3,6-dichloro-2-methoxybenzoic acid and its salts;

glufosinate-ammonium: ammonium (±)-2-amino-4-(hydroxymethylphosphinyl)butanoate;

glyphosate: N-(phosphonomethyl)glycine and its salts;

halosulfuron: 3-chloro-5-[[[[(4,6-dimethoxy-2-pyrimidinyl)amino]carboyl]amino]sulfonyl]-1-methyl-1H-pyrazole-4-carboxylic acid and its methyl ester;

imazamox: 2-[4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl]-5-(methoxymethyl)-3-pyridinecarboxylic acid;

imazapic: 2-[4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl]-5-methyl-3-pyridinecarboxylic acid, its salts and esters;

metolachlor: 2-chloro-N-(2-ethyl-6-methyl-phenyl)-N-(2-methoxy-1-methylethyl)acetamide;

metsulfuron: 2-[[[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]benzoic acid and its methyl ester;

oxadiazon: 3-[2,4-dichloro-5-(1-methylethoxy)-phenyl]-5-(1,1-dimethylethyl-1,3,4-oxadiazol-2(3H)-one;

picloram: 4-amino-3,5,6-trichloro-2-pyridine-carboxylic acid and its potassium salt;

sulfentrazone: N-[2,4-dichloro-5-[4-(difluoromethyl)-4,5-dihydro-3-methyl-5-oxo-1H-1,2,4-triazol-1-yl]phenyl]methanesulfonamide;

triclopyr: [(3,5,6-trichloro-2-pyridinyl)oxy]-acetic acid, its esters and salts;

trifloxysulfuron: N-[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]-3-(2,2,2-trifluoroethoxy)-2-pyridinesulfonamide;

simazine: 6-chloro-N,N′-diethyl-1,3,5-triazine-2,4-diamine;

optionally in the presence of at least one inorganic or organic base.

12. A method for post-emergence and pre-emergence control of a monocotyledon and dicotyledon weed, for the treatment of an agricultural crop, a meadow, a lawn, and/or as a herbicide in pre-sowing applications, or weeding of an industrial area, a railway, and a monument, wherein the method comprises applying to said weed, agricultural crop, meadow, lawn, industrial area, railway or monument, a herbicidal composition comprising a component [A] and a component [B], wherein component [A] is the compound having formula (I)

and component [B] comprises at least one herbicide selected from the group consisting of:

propanil: N-(3,4-dichlorophenyl)propanamide;

pretilachlor: 2-chloro-N-(2,6-diethylphenyl)-N-(2-propoxyethyl)acetamide;

acetochlor: 2-choro-N-(ethoxymethyl)-N-(2-ethyl-6-methylphenyl)acetamide;

benzobicyclon: 3-[2-chloro-4-(methyl-sulfonyl)-benzoyl]-4-(phenylthio)bicyclo[3.2.1]oct-3-en-2-one;

bromobutide: 2-bromo-3,3-dimethyl-N-(1-methyl-1-phenylethyl)butaneamide;

carfentrazone-ethyl: ethyl α,2-dichloro-5-[4-(difluoromethyl)-4,5-dihydro-3-methyl-5-oxo-1H,1,2,4-triazol-1-yl]-4-fluorobenzenepropanoate;

clomazone: 2-[(chlorophenyl)methyl]-4,4-dimethyl-3-isoxazolidinone;

2,4-D: (2,4-dichlorophenoxy)acetic acid, its esters and salts;

fentrazamide: N-cyclohexyl-N-ethyl-4-(2-chlorophenyl)-4,5-dihydro-5-oxo-1H-tetrazole-1-carboxamide;

imazethapyr: (±)-2-[4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl]-5-ethyl-3-pyridinecarboxylic acid;

pendimethalin: N-(1-ethylpropyl)-3,4-dimethyl-2,6-dinitrobenzeneamine;

quinclorac: 3,7-dichloro-8-quinolinecarboxylic acid;

atrazine: 6-chloro-N-ethyl-N′-(1-methylethyl)-1,3,5-triazine-2,4-diamine;

dicamba: 3,6-dichloro-2-methoxybenzoic acid and its salts;

glufosinate-ammonium: ammonium (±)-2-amino-4-(hydroxymethylphosphinyl)butanoate;

glyphosate: N-(phosphonomethyl)glycine and its salts;

halosulfuron: 3-chloro-5-[[[[(4,6-dimethoxy-2-pyrimidinyl)amino]carboyl]amino]sulfonyl]-1-methyl-1H-pyrazole-4-carboxylic acid and its methyl ester;

imazamox: 2-[4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl]-5-(methoxymethyl)-3-pyridinecarboxylic acid;

imazapic: 2-[4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl]-5-methyl-3-pyridinecarboxylic acid, its salts and esters;

metolachlor: 2-chloro-N-(2-ethyl-6-methyl-phenyl)-N-(2-methoxy-1-methylethyl)acetamide;

metsulfuron: 2-[[[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]benzoic acid and its methyl ester;

oxadiazon: 3-[2,4-dichloro-5-(1-methylethoxy)-phenyl]-5-(1,1-dimethylethyl-1,3,4-oxadiazol-2(3H)-one;

picloram: 4-amino-3,5,6-trichloro-2-pyridine-carboxylic acid and its potassium salt;

sulfentrazone: N-[2,4-dichloro-5-[4-(difluoromethyl)-4,5-dihydro-3-methyl-5-oxo-1H-1,2,4-triazol-1-yl]phenyl]methanesulfonamide;

triclopyr: [(3,5,6-trichloro-2-pyridinyl)oxy]-acetic acid, its esters and salts;

trifloxysulfuron: N-[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]-3-(2,2,2-trifluoroethoxy)-2-pyridinesulfonamide; and

simazine: 6-chloro-N,N′-diethyl-1,3,5-triazine-2,4-diamine;

optionally in the presence of at least one inorganic or organic base.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 9, 2014
From: ISEM S.R.L.
To: NIHON NOHYAKU CO., LTD.
Reel/Frame 032635/0468 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 3, 2012
From: ISAGRO S.P.A.
To: ISEM S.R.L.
Reel/Frame 027469/0385 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 10, 2009
From: BETTARINI, FRANCO; FORNARA, LUCA; VANZULLI, MAURO
To: ISAGRO S.P.A.
Reel/Frame 022940/0970 →
Priority Claims (1)
IT MI2006A2368 · Dec 11, 2006 · national
Continuity (1)
Related Publication 20100016160A1 · Jan 21, 2010