Method for improving acoustic impedance of epoxy resins
View Patent ↗An epoxy and rubber microcomposite is formed by adding a carboxy-terminated or amine-terminated rubber component having a glass transition temperature less than zero degrees centigrade to a bisphenol A based epoxy resin component; heating the mixture to 150 degrees centigrade; cooling and curing with a suitable curing agent. A phase segregation occurs between the epoxy resin component and the rubber component to form discrete, spherical rubbery domains with the epoxy compound. Because the glass transition temperature of the rubbery domains is below zero degrees centigrade; the rubbery domains act as acoustic windows within the high-modulus epoxy compound.
1. A method for improving the acoustic impedance of an epoxy resin, said method comprising the steps of:
providing an epoxy resin component wherein the resin component comprises a bisphenol A epoxy resin;
providing a rubber component wherein the rubber component has a glass transition from −39° C. to −80° C. degrees centigrade, has a molecular weight of 3000 Daltons to 4200 Daltons and comprises up to thirty percent by weight of acrylonitrile;
mixing the epoxy resin component with the rubber component wherein the rubber component is added to the epoxy resin component in a concentration of approximately 15 to 30 parts by weight per 100 parts by weight of the epoxy resin component;
heating the mixture to a temperature from 72° centigrade to 200° centigrade to react the epoxy resin component with the rubber component;
cooling the reacted mixture to an ambient temperature;
adding a curing agent to the cooled reacted mixture; and
cross-linking the bisphenol A epoxy resin with the curing agent to form a rubber microcomposite having a plurality of spherical rubbery domains within an epoxy resin matrix.
2. The method of claim 1 , wherein the rubber component is a carboxy-terminated rubber.
3. The method of claim 2 , wherein the rubber component further comprises an amine-terminated rubber.
4. The method of claim 1 , wherein the rubber component comprises an amine-terminated rubber.
5. The method of claim 1 , wherein the rubber component consists of carboxy-terminated butadiene, carboxy-terminated butadiene nitrile, carboxy-terminated butadiene-nitrile with pendant nitrile groups, amine-terminated butadiene and amine-terminated butadiene nitrile and mixtures thereof.
6. The method of claim 1 , wherein the curing agent comprises 2-Ethyl-4-methyl-imidazole.
7. The method of claim 1 , wherein the curing agent comprises N-aminoethylpiperazine.
8. The method of claim 1 , wherein each spherical rubbery domain has a diameter of 1 μm to 10 μm.