Methods of sequestering CO2
Methods of sequestering carbon dioxide (CO 2 ) are provided. Aspects of the methods include precipitating a storage stable carbon dioxide sequestering product from an alkaline-earth-metal-containing water and then disposing of the product, e.g., by placing the product in a disposal location or using the product as a component of a manufactured composition. Also provided are systems for practicing methods of the invention.
1. A method, comprising:
treating at least a portion of flue gas emitted from a cement plant, wherein said flue gas comprises carbon dioxide, with a proton removing agent to produce a solution comprising carbonate ions;
treating said solution with alkaline-earth-metal-ions to produce a carbonate precipitate comprising metastable compound selected from the group consisting of vaterite, amorphous calcium carbonate, and combination thereof, under one or more of precipitation conditions comprising precipitation facilitator, pH, temperature, additive, ion ratio, rate of precipitation, mixing rate, presence of seed crystals, catalysts, membranes or substrates, batch or continuous protocol, or combination thereof; and
producing a building material directly from at least a portion of said precipitate, wherein said building material is a cement composition comprising metastable compound selected from the group consisting of vaterite, amorphous calcium carbonate, and combination thereof.
2. The method of claim 1 , further comprising dewatering said precipitate to produce a slurry comprising said precipitate.
3. The method of claim 1 , wherein said precipitate comprises calcium carbonate, magnesium carbonate, calcium magnesium carbonate, or combination thereof.
4. The method of claim 1 , wherein said precipitate further comprises strontium in an amount ranging from 3 to 10,000 ppm.
5. The method of claim 1 , wherein said alkaline-earth-metal-ions are obtained from a mineral selected from the group consisting of serpentine, olivine, and combination thereof.
6. The method of claim 1 , wherein said solution further comprises bicarbonate ions.
7. The method of claim 1 , wherein said proton removing agent raises a pH of said solution to 9.5 or higher.
8. The method of claim 1 , wherein said building material is selected from the group consisting of hydraulic cement, aggregate, supplemental cementitious material, and combination thereof.
9. The method of claim 1 , wherein said proton removing agent is selected from the group consisting of oxide, hydroxide, carbonate, mineral, cement kiln dust, ash, natural body of alkaline water, slag, and combination thereof.
10. The method of claim 9 , wherein said hydroxide is made using an electrochemical process.
11. The method of claim 1 , wherein said alkaline-earth-metal-ions are obtained from saltwater or fresh water.
12. The method of claim 11 , wherein said saltwater is brackish water, sea water, or brine.