Effect pigments
Disclosed are yellowing-stable, silver-white effect pigments having high whiteness based on synthetic mica flakes and to the use thereof in paints, lacquers, printing inks, plastics, button pastes, ceramic materials, glasses, for coloring seed, as dopant in laser markings of plastics and papers, as additive for laser welding of plastics, as additive for coloring in the foods and pharmaceuticals sectors and in cosmetic formulations, and for the preparation of pigment compositions and dry preparations.
1. Effect pigments, comprising
synthetic mica flakes having an equivalence diameter distribution according to which 90% of the particles are in the range of 2 to 40 μm, and a thickness distribution according to which 90% of the particles are in the range of 100 to 3500 nm, and
have a coating with a refractive index ≧1.9, which comprises
titanium dioxide,
and one or more low-solubility alkaline-earth metal compounds
and optionally zinc oxide,
wherein the low-solubility alkaline-earth metal compound is
an alkaline-earth metal stannate, which is magnesium stannate, calcium stannate, strontium stannate or barium stannate, or
an alkaline-earth metal zirconate, which is magnesium zirconate, calcium zirconate, strontium zirconate or barium zirconate,
or
wherein the mica flakes have a first layer of titanium dioxide and a second layer of zinc oxide and one or more low-solubility alkaline-earth metal compounds.
2. Effect pigments according to claim 1 , wherein the aspect ratio (diameter/thickness ratio) of the mica flakes is 5-200.
3. Effect pigments according to claim 1 , wherein the synthetic mica is fluorophlogopite.
4. Effect pigments according to claim 1 , wherein the alkaline-earth metal stannate is magnesium stannate, calcium stannate, strontium stannate or barium stannate.
5. Effect pigments according to claim 1 , wherein the alkaline-earth metal zirconate is magnesium zirconate, calcium zirconate, strontium zirconate or barium zirconate.
6. Effect pigments according to claim 1 , wherein the mica flakes have a first layer of titanium dioxide and a second layer of zinc oxide and one or more low-solubility alkaline-earth metal compounds.
7. Effect pigments according to claim 1 , wherein the synthetic mica flakes have a coating of
TiO 2 (anatase)+calcium titanate;
TiO 2 (rutile)+calcium titanate;
TiO 2 (anatase)+calcium zirconate;
TiO 2 (rutile)+calcium zirconate;
TiO 2 (anatase)+calcium stannate;
TiO 2 (rutile)+calcium stannate;
TiO 2 (anatase)+zinc oxide+calcium titanate;
TiO 2 (rutile)+zinc oxide+calcium titanate;
TiO 2 (anatase)+calcium titanate+zinc oxide; or
TiO 2 (rutile)+calcium titanate+zinc oxide.
8. A process for preparing effect pigments according to claim 1 , comprising applying the coating to the synthetic mica flakes by a wet-chemical method or by hydrolytic decomposition of a metal salt in an aqueous medium.
9. A paint, button paste, lacquer, printing ink, security printing ink, plastic composition or article, ceramic material, glass composition or article, seed coating, dopant for a laser marking of plastics or paper, additive for laser welding of plastics, additive for coloring food or a pharmaceutical, cosmetic formulation, pigment composition or dry preparation, comprising effect pigments according to claim 1 .
10. A composition comprising effect pigments according to claim 1 and one or more of absorbents, astringents, antimicrobial substances, antioxidants, antiperspirants, antifoaming agents, antidandruff active ingredients, antistatics, binders, biological additives, bleaching agents, chelating agents, deodorants, emollients, emulsifiers, emulsion stabilisers, dyes, humectants, film formers, fillers, odor substances, flavor substances, insect repellents, preservatives, anticorrosion agents, cosmetic oils, solvents, oxidants, vegetable constituents, buffer substances, reducing agents, surfactants, propellant gases, opacifiers, UV filters, UV absorbers, denaturing agents, viscosity regulators, perfumes and/or vitamins.
11. A pigment composition comprising one or more binders and effect pigments according to claim 1 .
12. A dry preparation comprising effect pigments according to claim 1 .
13. Effect pigments according to claim 1 , wherein the equivalence diameter distribution according to which 90% of the particles are in the range of 5 to 30 μm, or the thickness distribution according to which 90% of the particles are in the range of 250 to 2200 nm, or the coating has a refractive index ≧2.1.
14. Effect pigments according to claim 1 , wherein the synthetic mica flakes have thereon a single coating which consists essentially of titanium dioxide and one or more alkaline-earth metal compounds and optionally zinc oxide, wherein the coating is a mixture of titanium dioxide and one or more low-solubility alkaline-earth metal compounds and optionally zinc oxide or contains two separate layers wherein the titanium dioxide is in a different layer than the one or more low-solubility alkaline-earth metal compounds and the optional zinc oxide.
15. Effect pigments according to claim 1 , wherein the synthetic mica flakes have thereon a single coating which consists of titanium dioxide and one or more low-solubility alkaline-earth metal compounds and optionally zinc oxide, wherein the coating is a mixture of titanium dioxide and one or more low-solubility alkaline-earth metal compounds and optionally zinc oxide or contains two separate layers wherein the titanium dioxide is in a different layer than the one or more low-solubility alkaline-earth metal compounds and the optional zinc oxide.
16. Effect pigments according to claim 1 ,
wherein the titanium dioxide is in a first layer on the synthetic mica flakes, and the one or more low-solubility alkaline-earth metal compounds and the optional zinc oxide are in a second layer on the first layer.
17. Effect pigments according to claim 16 , wherein the synthetic mica flakes have a coating of
TiO 2 (anatase)+calcium titanate;
TiO 2 (rutile)+calcium titanate;
TiO 2 (anatase)+calcium zirconate;
TiO 2 (rutile)+calcium zirconate;
TiO 2 (anatase)+calcium stannate;
TiO 2 (rutile)+calcium stannate
TiO 2 (anatase)+zinc oxide+calcium titanate;
TiO 2 (rutile)+zinc oxide+calcium titanate;
TiO 2 (anatase)+calcium titanate+zinc oxide; or
TiO 2 (rutile)+calcium titanate+zinc oxide.
18. Effect pigments according to claim 16 , wherein the first layer consists essentially of titanium dioxide and the second layer consists essentially of one or more low-solubility alkaline-earth metal compounds and optionally zinc oxide.