Additive for non-aqueous electrolyte and secondary battery using the same
Disclosed is an electrolyte comprising a compound having both a sulfonate group and a cyclic carbonate group. The electrolyte forms a more stable and dense SEI layer on the surface of an anode, and thus improves the capacity maintenance characteristics and lifespan characteristics of a battery. Also, disclosed is a compound represented by the following Formula 1, and a method for preparing the same by reacting 4-(hydroxyalkyl)-1,3-dioxolan-2-one with a sulfonyl halide compound: wherein each of R1 and R2 independently represents a C 1 ˜C 6 alkylene group optionally containing a C 1 ˜C 6 alkyl group or C 2 ˜C 6 alkenyl group introduced thereto; R3 is selected from the group consisting of a hydrogen atom, C 1 ˜C 20 alkyl group, C 3 ˜C 8 cyclic alkyl group, C 2 ˜C 6 alkenyl group, halo-substituted alkyl group, phenyl group and benzyl group.
1. A non-aqueous electrolyte for a secondary battery, the electrolyte comprising an electrolyte salt, an electrolyte solvent, and a compound having both a sulfonate group and a cyclic carbonate group;
wherein the sulfonate group is substituted with at least one selected from the group consisting of halogen atoms, cyano group (CN), trifluoromethane group (CF 3 ), pentafluoroethane group (C 2 F 5 ), trifluoromethane-sulfonyl group (SO 2 CF 3 ), pentafluoroethanesulfony group (SO 2 C 2 F 5 ), trifluoro-methanesulfonate group (SO 3 CF 3 ), pentafluoroethanesulfonate group (SO 3 C 2 F 5 ), pentafluorophenyl (C 6 F 5 ), acetyl group (COCH 3 ), ethyl ketone group (COC 2 H 5 ), propyl ketone group (COC 3 H 7 ), butyl ketone group (COC 4 H 9 ), pentyl ketone group (COC 5 H 11 ), hexyl ketone group (COC 6 H 13 ), ethanoate group (CO 2 CH 3 ), propanoate group (CO 2 C 2 H 5 ), butanoate group (CO 2 C 3 H 7 ), pentanoate group (CO 2 C 4 H 9 ), hexanoate group (CO 2 C 5 H 11 ), a hydrogen atom C1˜C20 alkyl group, C3˜C8 cyclic alkyl group, C2˜C6 alkenyl group, halo-substituted alkyl group, and benzyl group,
wherein the secondary battery is a lithium secondary battery, and
wherein the electrolyte solvent is an organic solvent.
2. The non-aqueous electrolyte as claimed in claim 1 , wherein the compound is represented by the following Formula 1:
wherein each of R1 and R2 independently represents a C 1 ˜C 6 alkylene group optionally containing a C 1 ˜C 6 alkyl group or C 2 ˜C 6 alkenyl group introduced thereto; R3 is selected from the group consisting of a hydrogen atom, C 1 ˜C 20 alkyl group, C 3 ˜C 8 cyclic alkyl group, C 2 ˜C 6 alkenyl group, halo-substituted alkyl group, and benzyl group.
3. The non-aqueous electrolyte as claimed in claim 1 , wherein the compound is selected from the group consisting of 1,3-dioxolan-2-onylmethyl allyl sulfonate, 1,3-dioxolan-2-onylmethyl methyl sulfonate, 1,3-dioxolan-2-onylmethyl ethyl sulfonate, 1,3-dioxolan-2-onylmethyl propyl sulfonate, 1,3-dioxolan-2-onylmethyl butyl sulfonate, 1,3-dioxolan-2-onylmethyl pentyl sulfonate, 1,3-dioxolan-2-onylmethyl hexyl sulfonate, 1,3-dioxolan-2-onylmethyl cyclopentyl sulfonate, 1,3-dioxolan-2-onylmethyl cyclohexyl sulfonate, 1,3-dioxolan-2-onylmethyl cycloheptyl sulfonate, 1,3-dioxolan-2-onylmethyl trifluoromethyl sulfonate, 1,3-dioxolan-2-onylmethyl trifluoroethyl sulfonate, 1,3-dioxolan-2-onylmethyl benzyl sulfonate, 1,3-dioxolan-2-onylethyl allyl sulfonate, 1,3-dioxolan-2-onylethyl methyl sulfonate, 1,3-dioxolan-2-onylethyl cyclopentyl sulfonate, 1,3-dioxolan-2-onylethyl cyclohexyl sulfonate, 1,3-dioxolan-2-onylethyl trifluoromethyl sulfonate, 1,3-dioxolan-2-onylethyl trifluoroethyl sulfonate, 1,3-dioxolan-2-onylethyl benzyl sulfonate, 1,3-dioxan-2-onyl-4-methyl allyl sulfonate, 1,3-dioxan-2-onyl-4-methyl methyl sulfonate, 1,3-dioxan-2-onyl-4-methyl cyclopentyl sulfonate, 1,3-dioxan-2-onyl-4-methyl cyclohexyl sulfonate, 1,3-dioxan-2-onyl-4-methyl trifluoromethyl sulfonate, 1,3-dioxan-2-onyl-4-methyl trifluoroethyl sulfonate, 1,3-dioxan-2-onyl-4-methyl benzyl sulfonate.
4. The non-aqueous electrolyte as claimed in claim 1 , wherein the compound is used in an amount of 0.1˜30 parts by weight per 100 parts by weight of the electrolyte.
5. A secondary battery comprising a cathode, an anode and a non-aqueous electrolyte as claimed in claim 1 .
6. The secondary battery as claimed in claim 5 , wherein the compound having both a sulfonate group and a cyclic carbonate group is represented by the following Formula 1:
wherein each of R1 and R2 independently represents a C 1 ˜C 6 alkylene group optionally containing a C 1 ˜C 6 alkyl group or C 2 ˜C 6 alkenyl group introduced thereto; R3 is selected from the group consisting of a hydrogen atom, C 1 ˜C 20 alkyl group, C 3 ˜C 8 cyclic alkyl group, C 2 ˜C 6 alkenyl group, halo-substituted alkyl group, and benzyl group.