Dihalogen indolocarbazole monomers and poly(indolocarbazoles)
Monomers and polymers based on dihalogen indolocarbazole and poly(indolocarbazoles), and methods of making such and using the same are described, as well as organic electronic devices incorporating the same.
1. A compound made from a monomer of formula I or II comprising an oligamer or a polymer
wherein:
R 1 is 2′-ethylhexyl, or 2-[2-(2-methoxyethoxy)ethoxy]ethyl.
2. A polymer of claim 1 comprising a co-polymer, a homopolymer, a block co-polymer, or combinations thereof.
3. The polymer of claim 2 that is poly (N,N′-Di(2′-ethylhexyl)-5,11-dihydroindolo[3,2-b]carbazole); poly{N,N′-bis[2-[2-(2-methoxyethoxy)ethoxy]ethyl]-5,11-dihydroindolo[3,2-b]carbazole}; poly{N,N′-bis[2-[2- (2-methoxyethoxy)ethoxy]ethyl]-5,11-dihydroindolo[3,2-b]carbazole-co-[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]-phenylene}; poly{N,N′-bis[2-[2-(2-methoxyethoxy)ethoxy]ethyl]-5,11-dihydroindolo[3,2-b]carbazole-co-9,9-bis[2-[2-(2-methoxyethoxy)ethoxy]ethyl]-fluorene}; poly{9,9-bis[2-[2-(2-methoxyethoxy)ethoxy]ethyl]fluorene}; poly{2-[9 ,9-Bis-(2-ethyl-hexyl)-7-methyl-9H-fluoren-2-yl]-6-[9-(2-ethyl-butyl)-9-(2-ethyl-heptyl)-7-methyl-9H-fluoren-2-yl]-benzo[1,2-d;4,5-d′]bisoxazole}, wherein n is greater than 20; combinations thereof, conjugates thereof, or derivatives thereof.
4. A material comprising an oligomer or a polymer of claim 1 .
5. The material of claim 4 further comprising a solvent, a processing aid, or combinations thereof.
6. An organic electronic device having at least one layer comprising the material of claim 4 .
7. The device of claim 6 wherein the material forms a charge transport layer.
8. The device of claim 6 wherein the charge transport layer is a hole transport layer.
9. The device of claim 6 that is a light-emitting diode, a light-emitting diode display, a diode laser, a photodetector, a photoconductive cell, a photoresistor, a photo switch, a phototransistor, a phototube, an IR-detector, a photovoltaic device, a solar cell, a light sensor, a photoconductor, an electrophotographic device, or an organic transistor.