Shampoo containing a gel network
Shampoo compositions comprise (a) from about 5% to about 50% of one or more detersive surfactants, by weight of the shampoo composition; (b) a dispersed gel network phase comprising, by weight of the shampoo composition, (i) at least about 0.05% of one or more fatty amphiphiles; (ii) at least about 0.01% of one or more secondary surfactants; and (iii) water; and (c) at least about 20% of an aqueous carrier, by weight of the shampoo composition. A process for preparing a shampoo composition comprises the steps of: (a) combining a fatty amphiphile, a secondary surfactant, and water at a temperature sufficient to allow partitioning of the secondary surfactant and the water into the fatty amphiphile to form a pre-mix; (b) cooling the pre-mix below the chain melt temperature of the fatty amphiphile to form a gel network; (c) adding the gel network to one or more detersive surfactants and an aqueous carrier to form a shampoo composition.
1. A shampoo composition comprising:
a) from about 5% to about 50% of one or more anionic detersive surfactants, by weight of said shampoo composition;
b) from about 5% to about 40% by weight of the shampoo composition of a pre-formed solid crystalline gel network phase consisting of:
i) from about 0.05% to about 14% of one or more fatty alcohols by weight of said shampoo composition;
ii) from about 0.3% to about 5% by weight of said shampoo composition of one or more surfactants selected from the group consisting of anionic, cationic, and mixtures thereof; and
iii) water;
wherein the fatty alcohol and the surfactants are combined in a ratio of from 1:1 to 40:1; and
c) from about 20% to about 95% of an aqueous carrier, by weight of said shampoo composition; and
d) from about 0.01% to about 5% by weight of said shampoo composition of an anti-dandruff active.
2. A shampoo composition according to claim 1 , further comprising a deposition aid.
3. A shampoo composition according to claim 2 , wherein said deposition aid is a cationic polymer.
4. A shampoo composition according to claim 3 , wherein said cationic polymer has a molecular weight from about 10,000 to about 10,000,000 and a charge density from about 0.9 meq/g to about 7.0 meq/g.
5. A shampoo composition according to claim 4 , wherein said charge density is from about 0.9 meq/g to about 5 meq/g.
6. A shampoo composition according to claim 1 , further comprising a suspending agent.
7. A shampoo composition according to claim 6 , wherein said suspending agent is a crystalline suspending agent.
8. A shampoo composition according to claim 1 , wherein the anti-dandruff active is selected from the group consisting of pyridinethione salts, azoles, selenium sulfide, particulate sulfur, keratolytic agents, octopirox, ciclopirox olamine, melaleuca, charcoal, and mixtures thereof.
9. A shampoo composition according to claim 8 , wherein the anti-dandruff active is a pyridinethione salt.
10. A shampoo composition according to claim 9 , wherein the pyridinethione salt is selected from the group consisting of zinc pyrithione, copper pyrithione, or mixtures thereof.
11. A shampoo composition according to claim 10 , wherein the anti-dandruff active is zinc pyrithione.
12. A shampoo composition according to claim 8 , wherein the anti-dandruff active is an azole.
13. A shampoo composition according to claim 12 , wherein the anti-dandruff dandruff active is an imidazole selected from the group consisting of climbazole, ketoconazole, and mixtures thereof.
14. A method of treating hair and skin, said method comprising the step of applying to the hair and skin a shampoo composition according to claim 1 .