Method of making diamond-bonded constructions with improved thermal and mechanical properties
Diamond-bonded constructions include a diamond-bonded body having a thermally stable region extending a distance below a diamond-bonded body surface. The thermally stable region comprises a matrix phase of bonded-together diamond crystals, and interstitial regions comprising a reaction product. The reaction product is formed by reaction between the diamond crystals and a reactive material. The reactant is a carbide former and the reaction product is a carbide. The diamond-bonded body includes a further diamond region extending from the thermally stable region that comprises the matrix phase and a Group VIII metal disposed within interstitial regions of the matrix phase. The thermally stable region is substantially free of a catalyst material used to initially form the diamond-bonded body. The diamond-bonded body may include a material layer formed from the reaction product that is disposed on a surface of the diamond-bonded body thermally stable region.
1. A method for making a diamond-bonded construction comprising the steps of:
treating a diamond-bonded body having a material microstructure comprising a matrix phase of bonded-together diamond grains and interstitial regions disposed between the diamond grains, wherein a catalyst material used to form the diamond-bonded body during a first high pressure/high temperature condition is disposed within the interstitial regions, wherein during the step of treating the catalyst material is removed from interstitial regions of the entire diamond-bonded body; and
introducing an infiltrant material into the interstitial regions of a first region of the diamond-bonded body removed of the catalyst material and subjecting the diamond-bonded body to second high pressure/high temperature condition to form a reaction product between a reactive material in the infiltrant material and the diamond grains, wherein the reaction product is disposed within the interstitial regions removed of the catalyst material.
2. The method as recited in claim 1 further comprising the step of forming a material layer on a surface of the first region of the diamond-bonded body, wherein the material layer comprises the reaction product.
3. The method as recited in claim 1 further comprising introducing another infiltrant into the interstitial regions removed of the catalyst material and not occupied by the reaction product, wherein the another infiltrant is a Group VIII metal selected from the CAS version of the Periodic Table, and wherein the diamond-bonded body is substantially free of the catalyst material.
4. The method as recited in claim 1 wherein during the step of treating, the catalyst material is allowed to remain in a population of the interstitial regions.
5. The method as recited in claim 1 wherein the reaction product is titanium carbide and the reactive material is titanium.
6. The method as recited in claim 1 wherein the diamond-bonded construction comprises a metallic substrate attached to the diamond-bonded body.
7. The method as recited in claim 1 wherein during the step of introducing, the second high pressure/high temperature condition is at a temperature that is less than that of the first high pressure/high temperature condition.
8. The method as recited in claim 1 , wherein the material comprising the reactive material has a melting temperature that is below the melting temperature of the catalyst material.
9. The method as recited in claim 2 , wherein the material layer is substantially free of diamond crystals.
10. The method as recited in claim 2 , wherein the material layer extends along at least a portion of a top and sidewall surface of the diamond-bonded body.
11. The method as recited in claim 2 , wherein the material layer has a thickness in the range of from about 0.5 micrometers to 50 micrometers.
12. The method as recited in claim 2 , wherein the material layer covers an entire top surface of the first region.