Thermoplastic resin composition and molded article obtained from the same
A thermoplastic resin composition contains (i) a polylactic acid, (ii) a polyolefin, and (iii) a compatibilizer (functional group-containing polymer that includes a functional group selected from functional groups X including a carboxyl group, an acid anhydride group, an epoxy group, a (meth)acryloyl group, an amino group, an alkoxysilyl group, a hydroxyl group, an isocyanate group, and an oxazoline group). The thermoplastic resin composition contains (iii-1) a functional group-containing hydrogenated diene polymer and (iii-2) a functional group-containing olefin polymer as the component (iii).
1. A thermoplastic resin composition comprising 1 to 30 parts by mass of (i) a polylactic acid, 70 to 99 parts by mass of (ii) a polyolefin consisting of olefin-derived units, and 0.1 to 30 parts by mass of (iii) a compatibilizer based on 100 parts by mass of the components (i) and (ii) in total, wherein the compatibilizer comprises
(iii-1) a functional group-containing hydrogenated diene polymer that comprises at least one amino functional group, and
(iii-2) a functional group-containing olefin polymer that comprises at least one functional group selected from an acid anhydride group and an epoxy group.
2. The thermoplastic resin composition according to claim 1 , wherein the component (ii) being (ii-1) polypropylene, and the component (iii-1) being a functional group-containing hydrogenated diene polymer that comprises a conjugated diene copolymer as a base polymer, the conjugated diene copolymer comprising a polymer block A and a polymer block B, the polymer block A and the polymer block B being bonded so as to form an (A)-(B)-(A) structure or an [(A)-(B)] x -Y structure, wherein x represents an integer equal to or larger than two, and Y represents a coupling agent residue, and wherein
the functional group being introduced into the base polymer, and at least 80% of double bonds of conjugated diene compound units that form the base polymer being hydrogenated, the polymer block A being a polymer block that comprises aromatic vinyl compound units in an amount of 50 mass % or more, the polymer block B being a polymer block that comprises conjugated diene compound units in an amount of 50 mass % or more and has a total content of 1,2-bonds and 3,4-bonds of 30 to 90%.
3. The thermoplastic resin composition according to claim 1 , wherein the component (ii) being (ii-2) polyethylene, and the component (iii-1) being a functional group-containing hydrogenated diene polymer that comprises a conjugated diene copolymer as a base polymer, the conjugated diene copolymer comprising a polymer block A, a polymer block B, and a polymer block C, the polymer block A, the polymer block B, and the polymer block C being bonded so as to form an (A)-(B)-(C) structure or an [(A)-(B)-(C)] x -Y structure, wherein x represents an integer equal to or larger than two, and Y represents a coupling agent residue, and wherein
the functional group being introduced into the base polymer, and at least 80% of double bonds of conjugated diene compound units that form the base polymer being hydrogenated, the polymer block A being a polymer block that comprises aromatic vinyl compound units in an amount of 50 mass % or more, the polymer block B being a polymer block that comprises conjugated diene compound units in an amount of 50 mass % or more and has a total content of 1,2-bonds and 3,4-bonds of 30 to 90%, and the polymer block C being a polymer block that comprises conjugated diene compound units in an amount of 50 mass % or more and has a total content of 1,2-bonds and 3,4-bonds of less than 30%.
4. A molded article comprising the thermoplastic resin composition according to claim 1 .
5. A molded article comprising the thermoplastic resin composition according to claim 2 .
6. A molded article comprising the thermoplastic resin composition according to claim 3 .
7. The thermoplastic resin composition according to claim 1 , wherein the component (iii-2) is (iii-2-1) an epoxy group-containing olefin polymer.
8. The thermoplastic resin composition according to claim 1 , wherein the component (iii-2) is (iii-2-2) an acid anhydride group-containing olefin polymer.
9. The thermoplastic resin composition according to claim 1 , wherein the compatibilizer comprises (iii-2-1) an epoxy group-containing olefin polymer and (iii-2-2) an acid anhydride group-containing olefin polymer as the component (iii-2).
10. The thermoplastic resin composition according to claim 1 , wherein the amino functional group is a primary amino group.
11. The thermoplastic resin composition according to claim 1 , wherein component (iii) is present in an amount of 0.5 to 20 parts by mass based on 100 parts by mass of the components (i) and (ii) in total.
12. The thermoplastic resin composition according to claim 1 , wherein component (iii-1) is present in an amount of 0.1 to 19.9 parts by mass based on 100 parts by mass of the components (i) and (ii) in total.
13. The thermoplastic resin composition according to claim 1 , wherein component (iii-2) is present in an amount of 0.1 to 19.9 parts by mass based on 100 parts by mass of the components (i) and (ii) in total.
14. The thermoplastic resin composition according to claim 1 , wherein the functional group-containing hydrogenated diene polymer is obtained by subjecting a conjugated diene compound alone to homopolymerization or a conjugated diene compound and an aromatic vinyl compound to block copolymerization in the presence of an organic alkali metal compound that has an amino group and is shown by the following general formula (3) or (4), and hydrogenating the copolymer:
wherein R 3 and R 4 represent trialkylsilyl groups having 3 to 18 carbon atoms, or one of R 3 and R 4 represents a trialkylsilyl group having 3 to 18 carbon atoms and the other of R 3 and R 4 represents an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an aralkyl group having 7 to 20 carbon atoms, or an organosiloxy group having 1 to 100 carbon atoms, and R 5 represents an alkylene group or an alkylidene group having 1 to 20 carbon atoms,
wherein R 5 represents an alkylene group or an alkylidene group having 1 to 20 carbon atoms, and R 6 represents an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an aralkyl group having 7 to 20 carbon atoms, or an organosiloxy group having 1 to 100 carbon atoms.
15. The thermoplastic resin composition according to claim 1 , wherein the functional group-containing hydrogenated diene polymer is obtained by subjecting a conjugated diene compound alone to homopolymerization or a conjugated diene compound and an aromatic vinyl compound to block copolymerization in the presence of an unsaturated monomer that has an amino group and is shown by the following general formula (5) or (6) and an organic alkali metal compound, and hydrogenating the copolymer:
wherein R 7 and R 8 represent trialkylsilyl groups having 3 to 18 carbon atoms, or one of R 7 and R 8 represents a trialkylsilyl group having 3 to 18 carbon atoms and the other of R 7 and R 8 represents an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an aralkyl group having 7 to 20 carbon atoms, or an organosiloxy group having 1 to 100 carbon atoms, and n represents an integer from 1 to 3,
wherein R 7 and R 8 represent trialkylsilyl groups having 3 to 18 carbon atoms, or one of R 7 and R 8 represents a trialkylsilyl group having 3 to 18 carbon atoms and the other of R 7 and R 8 represents an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an aralkyl group having 7 to 20 carbon atoms, or an organosiloxy group having 1 to 100 carbon atoms, R 9 represents an alkylene group having 1 to 20 carbon atoms, and n represents an integer from 1 to 3.
16. The thermoplastic resin composition according to claim 1 , wherein the functional group-containing hydrogenated diene polymer is obtained by subjecting a conjugated diene compound alone to homopolymerization or a conjugated diene compound and an aromatic vinyl compound to block copolymerization in the presence of an organic alkali metal compound, allowing the active site of the copolymer to react with an alkoxysilane compound shown by the following general formula (7), and hydrogenating the resulting polymer:
R 10 (4-m-n) Si(OR 11 ) m X n (7)
wherein R 10 represents an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an aralkyl group having 7 to 20 carbon atoms, or an organosiloxy group having 1 to 100 carbon atoms, and when the alkoxysilane compound contains two or more R 10 s, the R 10 s may be identical or different functional groups; R 11 represents an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, or an aralkyl group having 7 to 20 carbon atoms, and when the alkoxysilane compound contains two or more OR 11 groups, the R 11 s may be identical or different functional groups; X represents a substituent having a polar group containing a nitrogen atom, and when the alkoxysilane compound contains two or more Xs, the Xs may be identical or different functional groups, and wherein the Xs may be independent substituents, or may form a cyclic structure; m and n represent integers from 1 to 3, and the sum of m and n is an integer from 1 to 4.
17. The thermoplastic resin composition according to claim 1 , wherein the component (iii-2) is an ethylene-glycidyl methacrylate copolymer.
18. The thermoplastic resin composition according to claim 13 , wherein the component (iii-2) is an ethylene-glycidyl methacrylate copolymer.