Coating formulation for an offset paper and paper coated therewith
The document describes a coated paper for offset printing e.g. with a TAPPI 75° gloss value of below 35% or with high gloss properties, comprising at least on one side a top coating layer, said top coating layer comprising a pigment part, the 100 parts in dry weight thereof comprising in the range of 5-40 parts in dry weight of a fine particulate ground calcium carbonate with surface and internal structure modification as a result of treatment with one or more medium to strong H 3 O+ providers and eventually additional treatment with gaseous carbon dioxide, a binder part of 2-20 parts in dry weight of binder and (regular) additives in the range of 0-8 parts in dry weight.
1. A coated paper for offset printing comprising at least on one side a top coating layer, said top coating layer comprising
a pigment part, the 100 parts in dry weight thereof comprising 5-40 parts in dry weight of a fine particulate ground calcium carbonate with surface and internal structure modification as a result of treatment with one or more medium to strong H 3 O + ion providers and optionally with additional treatment of gaseous carbon dioxide,
30-80 parts in dry weight of a further fine particulate pigment selected from the group consisting of: fine particulate carbonate, kaoline, talcum, gypsum, titanium dioxide, barium sulphate, alumina tri-hydroxide, satin white, plastic pigment, or a mixture thereof,
a binder part of 2-20 parts in dry weight of binder, and
additives in the range of 0-8 parts in dry weight.
2. The coated paper according to claim 1 , wherein the fine particulate ground calcium carbonate with surface and internal structure modification and optionally with additional treatment of gaseous carbon dioxide has a nano-sized surface and internal pore structure with internal or surface pores with average pore sizes in the range of 5-100 nm.
3. The coated paper according to claim 1 , wherein the fine particulate ground calcium carbonate with surface and internal structure modification and optionally with additional treatment of gaseous carbon dioxide is comprised in the pigment part in the range of 10-30 parts in dry weight.
4. The coated paper according to claim 1 , wherein the fine particulate ground calcium carbonate with surface and internal structure modification and optionally with additional treatment of gaseous carbon dioxide has a median particle size in the range of 1.5-2.5 μm.
5. The coated paper according to claim 1 , wherein the fine particulate ground calcium carbonate with surface and internal structure modification and optionally with additional treatment of gaseous carbon dioxide has a particle size distribution such that 73-83% of the particles are smaller than 2 μm, and that 35-44% are smaller than 1 μm.
6. The coated paper according to claim 1 , wherein the fine particulate ground calcium carbonate with surface and internal structure modification is of the roses type.
7. The coated paper according to claim 1 , wherein the pigment part comprises less than 15 parts of an amorphous silica gel or precipitated silica.
8. The coated paper according to claim 1 , wherein the further fine particulate pigment is without surface and internal structure modifications.
9. The coated paper according to claim 1 , wherein the pigment part comprises one or a mixture of further fine particulate precipitated calcium carbonate pigments in a proportion of 10-40 parts in dry weight, wherein this further fine particulate precipitated calcium carbonate pigment has a particle size distribution such that 70-95% of the particles are smaller than 1.6 micrometer, that 60-80% of the particles are smaller than 1.0 micrometer, and that 10-25% of the particles are smaller than 0.4 micrometer.
10. The coated paper according to claim 9 , wherein its pigment part consists of
10-30 parts in dry weight of the one or a mixture of fine particulate ground calcium carbonates with surface and internal structure modification and optionally with additional treatment of gaseous carbon dioxide,
10-30 parts in dry weight of the one or the mixture of the fine particulate precipitated calcium carbonate,
30-50 parts in dry weight of one or a mixture of further fine particulate ground calcium carbonate pigment, as well as
0-15 parts in dry weight of one or a mixture of a talcum pigment.
11. The coated paper according to claim 1 , wherein the pigment part comprises a further fine particulate calcium carbonate pigment in a proportion of 30-80 parts in dry weight.
12. The coated paper according to claim 1 , wherein the further fine particulate pigment essentially has no internal pores within the pigment particles.
13. The coated paper according to claim 7 , wherein the further fine particulate pigment has median particle size in the range of 0.2-0.5 micrometer, and is a precipitated calcium carbonate, plastic and/or kaoline pigment.
14. The coated paper according to claim 1 , wherein its pigment part consists of 20-30 parts in dry weight of the fine particulate ground calcium carbonate with surface and internal structure modification and optionally with additional treatment of gaseous carbon dioxide, 40-60 parts in dry weight of the fine particulate precipitated calcium carbonate, 10-30 part in dry weight of a further different fine particulate calcium carbonate pigment, with a particle size distribution such that 90% of the particles are smaller than 2 micrometer, as well as 3-10 parts in dry weight of a talcum pigment.
15. The coated paper according to claim 1 , wherein beneath said top coating layer there is a middle coating layer, wherein this middle coating layer comprises a pigment part, the 100 parts in dry weight thereof comprising in the range of 5-40 parts in dry weight of a fine particulate ground calcium carbonate with surface and internal structure modification and optionally with additional treatment of gaseous carbon dioxide as defined in any of the preceding claims, a binder part and optionally additives.
16. Use of a paper according to claim 1 in an offset printing process, with reduced use or without the use of offset powder and/or without irradiative drying after printing and/or with reduced use or without use of overprint varnish.
17. The coated paper according to claim 1 , wherein the fine particulate ground calcium carbonate with surface and internal structure modification and optionally with additional treatment of gaseous carbon dioxide has a nano-sized surface and internal pore structure with internal or surface pores with average pore sizes in the range of 30-70 nm, most with a narrow pore size distribution.
18. The coated paper according to claim 1 , wherein the fine particulate ground calcium carbonate with surface and internal structure modification has a median pore size in the range of 0.04-0.06 μm and with narrow pore size distribution.
19. The coated paper according to claim 1 , wherein the fine particulate ground calcium carbonate with surface and internal structure modification has a surface area in the range of 30-80 m 2 /g.
20. The coated paper according to claim 1 , wherein the pigment part comprises less than or equal to 5 parts in dry weight of an amorphous silica gel or precipitated silica.
21. The coated paper according to claim 1 , wherein the pigment part comprises a further fine particulate pigment selected from the group of carbonate, kaoline, talcum, plastic pigment or a mixture thereof, wherein the talcum pigment makes up 3-10 parts in dry weight of the pigment part.
22. The coated paper according to claim 1 , wherein the pigment part comprises one or a mixture of further fine particulate precipitated calcium carbonate pigments in a proportion of 15-30 parts in dry weight, wherein this further fine particulate precipitated calcium carbonate pigment has a particle size distribution such that 70-95% of the particles are smaller than 1.6 micrometer, that 60-80% of the particles are smaller than 1.0 micrometer, and that 10-25% of the particles are smaller than 0.4 micrometer, wherein this further fine particulate has a surface area in the range of 30-50 m 2 /g.
23. The coated paper according to claim 9 , wherein its pigment part consists of
15-25 parts in dry weight of the one or a mixture of fine particulate ground calcium carbonates with surface and internal structure modification and optionally with additional treatment of gaseous carbon dioxide,
15-25 parts in dry weight of the one or the mixture of the fine particulate precipitated calcium carbonate,
40-50 parts in dry weight of one or a mixture of further fine particulate ground calcium carbonate pigment, with a particle size distribution such that at least 90% of the particles are smaller than 2 micrometer, as well as
3-12 parts in dry weight of one or a mixture of a talcum pigment, of a talcum which is surface treated and/or impregnated with aminosilane coupling agents.
24. The coated paper according to claim 1 , wherein the pigment part comprises a further fine particulate, precipitated calcium carbonate, pigment in a proportion of 40-60 parts in dry weight, wherein this further fine particulate pigment has a particle size distribution such that 85-95% of the particles are smaller than 1 micrometer, that 65-75% of the particles are smaller than 0.5 micrometer, and that 35-45% of the particles are smaller than 0.2 micrometer, wherein the precipitated calcium carbonate is such that it provides interconnected intra-particulate pores or voids in the total pigment matrix with average pores or voids diameter of approximately 0.1-1 μm.
25. The coated paper according to claim 1 , wherein the pigment part comprises a further fine particulate carbonate and/or kaoline and/or talcum and/or gypsum and/or titanium dioxide and/or barium sulphate and/or alumina tri-hydroxide and or satin white and/or plastic pigment or a mixture thereof, and wherein the further fine particulate pigment essentially has no internal pores within the pigment particles, and wherein the further fine particulate pigment is of aragonite, of needle type morphology, and wherein the further fine particulate pigment has a surface area (BET) in the range of 8-20 m 2 /g.
26. The coated paper according to claim 1 , wherein beneath said top coating layer there is a middle coating layer, wherein this middle coating layer comprises a pigment part, the 100 parts in dry weight thereof comprising in the range of 10-20 parts in dry weight of a fine particulate ground calcium carbonate with surface and internal structure modification and optionally with additional treatment of gaseous carbon dioxide as defined in any of the preceding claims, a binder part and optionally additives, wherein the remainder of the pigment part of the middle coating layer comprises or consists of at least one further and different fine particulate pigment selected from the group of: calcium carbonate, kaoline, talcum, gypsum, alumina tri-hydroxide, barium sulphate, satin white, titanium dioxide, plastic pigment and mixtures thereof.