IP Library Granted Patent US 8,419,998
Granted Patent B2
US 8,419,998 · App. 13/080,738 · Granted Apr 16, 2013

Process for making hollow carbon spheres

Inventors: Claudia C. Luhrs (Rio Rancho, NM); Jonathan Phillips (Rio Rancho, NM); Monique N. Richard (Ann Arbor, MI); Angela Michelle Knapp (Ann Arbor, MI)
Assignees: Toyota Motor Engineering & Manufacturing North America, Inc.; The Regents of the University of New Mexico; Los Alamos National Lab
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Quick Facts
Patent No.
US 8,419,998
App. No.
13/080,738
Granted
Apr 16, 2013
Kind
B2
Abstract

A hollow carbon sphere having a carbon shell and an inner core is disclosed. The hollow carbon sphere has a total volume that is equal to a volume of the carbon shell plus an inner free volume within the carbon shell. The inner free volume is at least 25% of the total volume. In some instances, a nominal diameter of the hollow carbon sphere is between 10 and 180 nanometers.

Claims (16)

1. A process for making a hollow carbon sphere comprising:

providing a sacrificial material for the inner core of material;

vaporizing carbon with a plasma to form carbon vapor;

depositing carbon onto the inner core of material by condensation of the carbon vapor onto the sacrificial material in order to form a carbon shell; and

removing the inner core of material in order to produce a hollow carbon sphere, the hollow carbon sphere having:

a carbon shell having a volume;

an inner core having an inner free volume;

a total volume equal to said volume of said carbon shell plus said inner free volume;

said inner free volume being at least 25% of said total volume;

said hollow carbon sphere having a nominal diameter between 10 and 180 nanometers and having a wall thickness between 5 and 20 nanometers.

2. The process of claim 1 , wherein the depositing carbon onto the sacrificial material is selected from the group consisting of depositing by chemical vapor deposition, depositing by laser ablation, depositing by electric arc discharge and depositing by low temperature solvation.

3. The process of claim 1 , wherein removing the inner core of material is by acidic dissolution of the inner core material.

4. The process of claim 1 , wherein removing the inner core of material is by alkaline dissolution of the inner core material.

5. The process of claim 1 , further including encapsulating a biologically active material within the hollow carbon sphere.

6. The process of claim 1 , further including depositing a catalytic material onto a surface of the hollow carbon sphere.

7. The process of claim 6 , wherein the surface of the hollow carbon sphere is an outer surface of the hollow carbon sphere.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 6, 2011
From: RICHARD, MONIQUE N.; KNAPP, ANGELA MICHELLE
To: TOYOTA MOTOR ENGINEERING & MANUFACTURING NORTH AMERICA, INC.
Reel/Frame 026080/0821 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 6, 2011
From: PHILLIPS, JONATHAN
To: LOS ALAMOS NATIONAL LAB
Reel/Frame 026080/0943 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 6, 2011
From: LUHRS, CLAUDIA C.
To: REGENTS OF THE UNIVERSITY OF NEW MEXICO
Reel/Frame 026081/0870 →
Continuity (2)
Division 12391794 · Feb 24, 2009
Related Publication 20110180513A1 · Jul 28, 2011