Thermoplastic elastomer composition and production process
A thermoplastic elastomer composition which has excellent cleanability and is suitable for use as a medical rubber supply. It is characterized by comprising a rubber ingredient dynamically crosslinked with a crosslinking agent and a matrix which comprises a thermoplastic resin and in which the crosslinked rubber ingredient has been dispersed, the crosslinking agent comprising a triazine derivative.
1. A thermoplastic elastomer composition comprising a rubber component consisting of ethylene-propylene-diene rubber or/and butyl rubber; a crosslinking agent comprising a triazine derivative; 30 to 70 parts by mass of polypropylene or polyethylene for 100 parts by mass of the rubber component; at least 15 parts by mass of a softener for 100 parts by mass of the rubber component; and 30 to 40 parts by mass of hydrogenated styrene thermoplastic elastomer for 100 parts by mass of the rubber component,
wherein said rubber component is dynamically crosslinked with said triazine derivative and dispersed in said polypropylene or said polyethylene,
and wherein the triazine derivative is a compound of the following formula:
wherein R denotes —SH, —OR 1 , —SR 2 , —NHR 3 or NR 4 R 5 , with R 1 , R 2 , R 3 , R 4 , and R 5 each denoting a C 1 -C 12 alkyl group, a C 1 -C 12 alkenyl group, a C 6 -C 14 aryl group, a C 7 -C 19 aralkyl group, a C 7 -C 19 alkylaryl group or a C 3 -C 9 cycloalkyl group, and with R 4 and R 5 being identical to each other or different from each other; and M 1 and M 2 are identical to each other or different from each other and denote H, Na, Li, K, ½Mg, ½Ba, ½Ca, an aliphatic primary amine, an aliphatic secondary amine, an aliphatic tertiary amine, a quaternary ammonium salt or a phosphonium salt.
2. A thermoplastic elastomer composition according to claim 1 , which does not contain a zinc compound.
3. A thermoplastic elastomer composition according to claim 1 or 2 , wherein said crosslinking agent consisting of said triazine derivative is added to said rubber component at not less than 0.1 parts by mass nor more than 10 parts by mass for 100 parts by mass of said rubber component.
4. A method for producing a thermoplastic elastomer composition which comprises: mixing a rubber component consisting of ethylene-propylene-diene rubber or/and butyl rubber, a triazine derivative, 30 to 70 parts by mass of a polypropylene or polyethylene for 100 parts by mass of the rubber component, at least 15 parts by mass of a softener for 100 parts by mass of the rubber component, and 30 to 40 parts by mass of hydrogenated styrene thermoplastic elastomer for 100 parts by mass of the rubber component to form a mixture; and supplying the mixture to an extruder or a kneader for extrusion or kneading; wherein said rubber component is dispersed by applying a shearing force to said mixture, dynamically crosslinked with said triazine derivative, and dispersed in said polypropylene or said polyethylene,
and wherein the triazine derivative is a compound of the following formula:
wherein R denotes —SH, —OR 1 , —SR 2 , —NHR 3 or NR 4 R 5 , with R 1 , R 2 , R 3 , R 4 , and R 5 each denoting a C 1 -C 12 alkyl group, a C 1 -C 12 alkenyl group, a C 6 -C 14 aryl group, a C 7 -C 19 aralkyl group, a C 7 -C 19 alkylaryl group or a C 3 -C 9 cycloalkyl group, and with R 4 and R 5 being identical to each other or different from each other; and M 1 and M 2 are identical to each other or different from each other and denote H, Na, Li, K, ½Mg, ½Ba, ½Ca, an aliphatic primary amine, an aliphatic secondary amine, an aliphatic tertiary amine, a quaternary ammonium salt or a phosphonium salt.
5. A medical rubber supply component consisting of a thermoplastic elastomer composition as defined in claim 1 .
6. A medical rubber supply component consisting of a thermoplastic elastomer composition produced by using a method as defined in claim 4 .
7. A thermoplastic elastomer composition according to claim 3 , wherein the softener is an oil or a plasticizer that is present in an amount of not more than 400 parts by mass and not less than 15 parts by mass for 100 parts by mass of the rubber component; and
the triazine is a compound of the following formula:
wherein R denotes —SH, —OR 1 , —SR 2 , —NHR 3 or NR 4 R 5 , with R 1 , R 2 , R 3 , R 4 , and R 5 each denoting a C 1 -C 12 alkyl group, a C 1 -C 12 alkenyl group, a C 6 -C 14 aryl group, a C 7 -C 19 aralkyl group, a C 7 -C 19 alkylaryl group or a C 3 -C 9 cycloalkyl group, and with R 4 and R 5 being identical to each other or different from each other; and M 1 and M 2 are identical to each other or different from each other and denote H, Na, Li, K, ½Mg, ½Ba, ½Ca, an aliphatic primary amine, an aliphatic secondary amine, an aliphatic tertiary amine, a quaternary ammonium salt or a phosphonium salt.
8. A thermoplastic elastomer composition according to claim 7 , wherein the triazine is selected from the group consisting of 2,4,6-trimercapto-s-triazine, 2-methylamino-4,6-dimercapto-s-triazine, 2-(n-butylamino)-4,6-dimercapto-s-triazine, 2-octylamino-4,6-dimercapto-s-triazine, 2-propylamino-4,6-dimercapto-s-triazine, 2-diarylamino-4,6-dimercapto-s-triazine, 2-dimethylamino-4,6-dimercapto-s-triazine, 2-dibutylamino-4,6-dimercapto-s-triazine, 2-di(iso-butylamino)-4,6-dimercapto-s-triazine, 2-dipropylamino-4,6-dimercapto-s-triazine, 2-di(2-ethylhexyl)amino-4,6-dimercapto-s-triazine, 2-dioleylamino-4,6-dimercapto-s-triazine, 2-laurylamino-4,6-dimercapto-s-triazine, and 2-anilino-4,6-dimercapto-s-triazine, as well as sodium and disodium salts thereof.