Alloyed semiconductor nanocrystals
The invention relates to methods for preparing 3-element semiconductor nanocrystals of the formula WY x Z (1-x) , wherein W is a Group II element, Y and Z are different Group VI elements, and 0<X<1, comprising dissolving a Group II element, a first Group VI element, and a second Group VI element in a one or more solvents. The Group II, VI and VI elements are combined to provide a II:VI:VI SCN precursor solution, which is heated to a temperature sufficient to produce semiconductor nanocrystals of the formula WY x Z (1-x) . The solvent used to dissolve the Group II element comprises octadecene and a fatty acid. The solvent used to dissolve the Group VI elements comprises octadecene. The invention also includes semiconductor nanocrystals prepared according to the disclosed methods, as well as methods of using the semiconductor nanocrystals.
1. A method for synthesizing 2-6-6 semiconductor nanocrystals (SCNs) of the formula WY x Z (1-x) , wherein W is a Group II element, Y and Z are different Group VI elements, and 0<X<1, comprising:
heating a 2-6-6 SCN precursor solution comprising a Group II element, a first Group VI element, and a second Group VI element in one or more solvents together comprising octadecene and a fatty acid to a temperature sufficient to produce said 2-6-6 SCNs.
2. The method of claim 1 , wherein said 2-6-6 SCN precursor is prepared by:
dissolving a Group II element, a first Group VI element, and a second Group VI element in a solvent comprising octadecene and a fatty acid to provide said 2-6-6 SCN precursor solution.
3. The method of claim 1 , wherein said 2-6-6 SCN precursor is prepared by
preparing a first solution by dissolving a Group II element and a first Group VI element in a first solvent comprising octadecene and a fatty acid;
preparing a second solution by dissolving a second Group VI element in a second solvent comprising octadecene;
mixing said first and second solutions to provide a 2-6-6 SCN precursor solution.
4. The method of claim 1 , wherein said 2-6-6 SCN precursor is prepared by:
preparing a first solution by dissolving a Group II element in a first solvent comprising octadecene and a fatty acid;
preparing a second solution by dissolving a first Group VI and a second Group VI element in a second solvent comprising octadecene;
mixing said first and second solutions to provide a 2-6-6 SCN precursor solution.
5. The method of claim 1 , wherein said 2-6-6 SCN precursor is prepared by:
preparing a first solution by dissolving a Group II element in a first solvent comprising octadecene and a fatty acid;
preparing a second solution by dissolving a first Group VI element in a second solvent comprising octadecene;
preparing a third solution by dissolving a second Group VI element in a third solvent comprising tributylphosphine;
mixing said first, second, and third solutions to provide a 2-6-6 SCN precursor solution.
6. The method of claim 2 wherein said fatty acid is oleic acid.
7. The method of claim 1 wherein said temperature is between about 270° C. and 330° C.
8. The method of claim 3 wherein said Group II element is dissolved in said first solvent at a temperature between about 270° C. and 330° C.
9. The method of claim 4 wherein said Group II element is dissolved in said first solvent at a temperature between about 270° C. and 330° C.
10. The method of claim 5 wherein said Group II element is dissolved in said first solvent at a temperature between about 270° C. and 330° C.
11. The method of claim 1 , wherein the synthesis of the 2-6-6 semiconductor proceeds to completion without a step to halt nanocrystal growth.