Polymerizable oxetane derivative
View Patent ↗The invention provides a compound represented by formula (1). In the formula (1), R 1 is hydrogen, methyl or ethyl; X 1 is a single bond, —O— or —OCO—; X 2 is a single bond, —O—, —COO— or —OCO—; A 1 and A 2 are each independently a divalent aromatic ring or a divalent cyclohexane ring, and in these rings, arbitrary hydrogen may be replaced by halogen, alkyl having 1 to 3 carbons or halogenated alkyl having 1 to 3 carbons; Z 1 is independently a single bond, —O—, —S—, —COO—, —OCO—, —CH 2 O—, —OCH 2 —, —CH═CH—COO—, —OCO—CH═CH—, —CH 2 CH 2 —COO—, —OCO—CH 2 CH 2 —, —CON(R)— or —N(R)CO—; R is hydrogen or methyl; Y is a terpenoid residue or a steroid residue; m is an integer from 0 to 20; and n is an integer from 0 to 3.
1. A compound represented by the following formula (1):
wherein R 1 is hydrogen, methyl or ethyl; X 1 is a single bond, —O— or —OCO—; X 2 is a single bond, —O—, —COO— or —OCO—; A 1 and A 2 are each independently a divalent aromatic ring or a divalent cyclohexane ring, and in these rings, arbitrary hydrogen may be replaced by halogen, alkyl having 1 to 3 carbons or halogenated alkyl having 1 to 3 carbons; Z 1 is independently a single bond, —O—, —S—, —COO—, —OCO—, —CH 2 O—, —OCH 2 —, —CH═CH—COO—, —OCO—CH═CH—, —CH 2 CH 2 —COO—, —OCO—CH 2 CH 2 —, —CON(R)— or —N(R)CO—; R is hydrogen or methyl; Y is a terpenoid residue or a steroid residue; m is an integer from 0 to 20; and n is an integer from 0 to 3.
2. The compound according to claim 1 , wherein the terpenoid residue is a residue of menthol, neomenthol, isomenthol, carveol, dihydrocarveol, terpinen-4-ol, verbenol, nopol, perillyl alcohol, cedrol, citronellol, dihydrocitronellol or isopinocampheol; and the steroid residue is a residue of sterol.
3. The compound according to claim 1 , wherein in the formula (1), Y is a menthol residue or a cholesterol residue.
4. The compound according to claim 1 , wherein in the formula (1), -(A 1 -Z 1 ) n -A 2 - is a divalent group represented by the following formula (2-1) or (2-2)
5. The compound according to claim 1 , wherein in the formula (1), -(A 1 -Z 1 ) n -A 2 - is a divalent group represented by any one of the following formulas (3-1) to (3-7)
6. The compound according to claim 1 , wherein in the formula (1), -(A 1 -Z 1 ) n -A 2 - is a divalent group represented by any one of the following formulas (4-1) to (4-8)
7. The compound according to claim 1 , wherein in the formula (1), -(A 1 -Z 1 ) n -A 2 - is the following formula (3-1) and X 1 is —O—
8. A liquid crystal composition, comprising the compound according to claim 1 and a liquid crystal compound.
9. The liquid crystal composition according to claim 8 , wherein the composition comprises at least one polymerizable liquid crystal compound as the liquid crystal compound.
10. A polymer formed by polymerization of the liquid crystal composition according to claim 9 .
11. The polymer according to claim 10 , wherein the polymer exhibits a cholesteric phase.