Methods for producing flameproofed thermoplastic moulding compounds
The invention relates to a process for the preparation of thermoplastic molding materials comprising A) from 39 to 99% by weight of at least one thermoplastic polymer, B) from 1 to 60% by weight of a flameproofing component comprising B1) an expandable graphite, and C) from 0 to 60% by weight of further additives, the percentages by weight being based in each case on the total weight of the components A) to C) and together giving 100% by weight, by mixing melts of the components A), B) and, if present, C) in a screw extruder, the screw extruder comprising at least one metering zone, one plasticating zone, one homogenization zone and one discharge zone in this sequence along the conveying direction, wherein the metering of the expandable graphite B1) into the screw extruder is effected at a point behind which—viewed in the conveying direction—the extruder screw comprises substantially no shearing elements, and thermoplastic molding materials which can be prepared by these processes, the use of said thermoplastic molding materials for the production of fibers, films, moldings and foams, and these fibers, films, moldings and foams themselves.
1. A process for the preparation of thermoplastic molding materials comprising
A) from 39 to 99% by weight of at least one thermoplastic polymer,
B) from 1 to 60% by weight of a flameproofing component comprising
B1) an expandable graphite, and
C) from 0 to 60% by weight of further additives,
the percentages by weight being based in each case on the total weight of the components A) to C) and together giving 100% by weight,
by mixing melts of the components A), B) and, if present, C) in a screw extruder, the screw extruder comprising at least one metering zone, one plasticating zone, one homogenization zone and one discharge zone in this sequence along the conveying direction,
wherein the metering of the expandable graphite B1) into the screw extruder is effected at a point behind which—viewed in the conveying direction—the extruder screw comprises no shearing elements.
2. The process according to claim 1 , wherein the metering of the expandable graphite B1) into the screw extruder is effected at a point behind which—viewed in the conveying direction—the extruder screw comprises only conveying screw elements.
3. The process according to claim 1 , wherein the metering of the expandable graphite B1) into the screw extruder is effected between homogenization zone and discharge zone.
4. The process according to claim 1 , wherein the flameproofing component B) comprises
B1) an expandable graphite,
B2) a flameproofing compound comprising phosphorus and
B3) a fluorine-containing polymer.
5. The process according to claim 4 , wherein the flameproofing component B) comprises
from 20 to 79.99% by weight of the component B1),
from 20 to 79.99% by weight of the component B2) and
from 0.01 to 4% by weight of the component B3),
the percentages by weight being based in each case on the total weight of the components B1) to B3) and together giving 100% by weight.
6. The process according to claim 1 , wherein component B2) is at least one compound selected from the group consisting of inorganic or organic phosphates, phosphites, phosphonates, phosphate esters, red phosphorus and triphenylphosphine oxide, and combination thereof.
7. The process according to claim 1 , wherein component B3) is a fluorinated ethylene polymer.
8. A process for the preparation of thermoplastic molding materials comprising
A) from 39 to 99% by weight of at least one thermoplastic polymer;
B) from 1 to 60% by weight of a flameproofing component comprising
B1) from 20 to 79.99% by weight of an expandable graphite,
B2) from 20 to 79.99% by weight of a flameproofing compound comprising phosphorus which comprises at least one compound selected from the group consisting of inorganic or organic phosphates, phosphites, phosphonates, phosphate esters, red phosphorus and triphenylphosphine oxide, and
B3) 0.01 to 4% by weight of a fluorinated ethylene polymer; and
C) from 0 to 60% by weight of further additives,
the percentages by weight being based in each case on the total weight of the components A) to C) and together giving 100% by weight,
by mixing melts of the components A), B) and, if present, C) in a screw extruder, the screw extruder comprising at least one metering zone, one plasticating zone, one homogenization zone and one discharge zone in this sequence along the conveying direction,
wherein the metering of the expandable graphite B1) into the screw extruder is effected at a point behind which—viewed in the conveying direction—the extruder screw comprises no shearing elements.