Process for the production of moldings with reduced formation of deposit
The invention relates to processes for the production of moldings via shaping of thermoplastic molding compositions F with reduced formation of deposit on the shaping mold, and it is essential to the invention that the thermoplastic molding compositions F comprise an amount of from 0 mg/kg to 100 mg/kg (calculated as the total of the mg of Mg and the mg of Ca per kg of thermoplastic molding composition F and determined by means of atomic emission spectrometry using inductively coupled plasma (ICPAES)) of magnesium compounds and/or calcium compounds; the invention further relates to the use of molding compositions F in the inventive processes, and also to moldings which can be produced by the inventive processes.
1. A process for the production of moldings via shaping of thermoplastic molding compositions F with reduced formation of deposit on the shaping mold, wherein the thermoplastic molding compositions F comprise an amount of from 3 mg/kg to 75 mg/kg (calculated as the total of the mg of Mg and the mg of Ca per kg of thermoplastic molding composition F and determined by means of atomic emission spectrometry using inductively coupled plasma (ICPAES)) of at least one magnesium compound and/or calcium compound, wherein the molding compositions F comprise, alongside the at least one magnesium compound and/or calcium compound,
A) from 20 to 100% by weight of at least one impact-modified vinylaromatic copolymer selected from the group consisting of acrylonitrile-butadiene-styrene copolymers (ABS), acrylonitrile-styrene-acrylate copolymers (ASA), and methacrylate-acrylonitrile-butadiene-styrene copolymers (MABS),
B) from 0 to 80% by weight of at least one polycarbonate (PC), and
C) from 0 to 60% by weight of further additives conventional in plastics, where each of the percentages by weight is based on the total weight of components A) to C) and the total of the percentages by weight is 100% by weight.
2. The process according to claim 1 , wherein the shaping takes place via extrusion to give pellets, foils, sheets, strands, or profiles.
3. The process according to claim 1 , wherein the shaping takes place via injection-molding to give moldings.
4. A molding that can be produced by the process according to claim 1 .
5. A thermoplastic molding composition F for the production of moldings by the process according to claim 1 , comprising an amount of from 3 mg/kg to 75 mg/kg (calculated as the total of the mg of Mg and the mg of Ca per kg of thermoplastic molding composition F and determined by means of atomic emission spectrometry using inductively coupled plasma (ICPAES)) of at least one magnesium compound and/or calcium compound.
6. The process according to claim 2 , wherein the shaping takes place via injection-molding to give moldings.
7. A molding that can be produced by the process according to claim 1 .
8. A molding that can be produced by the process according to claim 2 .
9. A molding that can be produced by the process according to claim 3 .
10. A thermoplastic molding composition F for the production of moldings by the process according to claim 2 , comprising an amount of from 3 mg/kg to 75 mg/kg (calculated as the total of the mg of Mg and the mg of Ca per kg of thermoplastic molding composition F and determined by means of atomic emission spectrometry using inductively coupled plasma (ICPAES)) of at least one magnesium compound and/or calcium compound.
11. A thermoplastic molding composition F for the production of moldings by the process according to claim 3 , comprising an amount of from 3 mg/kg to 75 mg/kg (calculated as the total of the mg of Mg and the mg of Ca per kg of thermoplastic molding composition F and determined by means of atomic emission spectrometry using inductively coupled plasma (ICPAES)) of at least one magnesium compound and/or calcium compound.
12. The process according to claim 2 , wherein the shaping takes place via injection-molding to give moldings.
13. A molding that can be produced by the process according to claim 2 .
14. A molding that can be produced by the process according to claim 3 .