Metal complex and organic electroluminescent device

1. A polymeric light-emitting substance wherein said light-emitting substance has an iridium complex structure showing light emission from triplet excited state in the main chain or side chain, and has a monovalent group represented by the following general formula (1) or (2):

wherein A is a single bond or a divalent group derived from conjugate system,

R 1 and R 2 each independently represent a halogen atom, alkyl group, alkoxy group, alkylthio group, alkylamino group, alkylsilyl group, aryl group, aryloxy group, arylthio group, arylamino group, arylsilyl group, arylalkyl group, arylalkoxy group, arylalkylthio group, arylalkylamino group, arylalkyl silyl group, acyl group, acyloxy group, imino group, amide group, arylalkenyl group, arylalkynyl group, cyano group, or a monovalent heterocyclic group,

R 3 represents alkyl group, aryl group, arylalkyl group, arylalkenyl group, arylalkynyl group, or a monovalent heterocyclic group,

a represents an integer of 0 to 3,

b represents an integer of 0 to 4, and

when a is two or more, a plurality of R 1 s may be the same or different and when b is two or more, a plurality of R 2 s may be the same or different;

wherein D is a single bond or a divalent group derived from conjugate system,

R 4 and R 5 each independently represent a halogen atom, alkyl group, alkoxy group, alkylthio group, alkylamino group, alkylsilyl group, aryl group, aryloxy group, arylthio group, arylamino group, arylsilyl group, arylalkyl group, arylalkoxy group, arylalkylthio group, arylalkylamino group, arylalkylsilyl group, acyl group, acyloxy group, imino group, amide group, arylalkenyl group, arylalkynyl group, cyano group, or a monovalent heterocyclic group,

c and d each independently represent an integer of 0 to 4, and

when c is two or more, a plurality of R 4 s may be the same or different; when d is two or more, a plurality of R 5 s may be the same or different;

wherein the main chain of said light-emitting substance is a conjugated type polymeric light-emitting substance, and contains a repeating unit represented by the following general formula (14),

—Ar 6 CR 20 ═CR 21 n   (14)

wherein Ar 6 represents an arylene group or a divalent heterocyclic group,

n is 0 or 1,

R 20 and R 21 each independently represent a hydrogen atom, alkyl group, aryl group, arylalkyl group, arylalkenyl group, arylalkynyl group, monovalent heterocyclic group, or cyano group, and

at least one of R 20 , R 21 , or a substituent on Ar 6 , represents a group represented by the above formula (1) or (2).

2. A polymeric light-emitting substance according to claim 1 , wherein at least one ligand of the iridium complex portion showing light emission from triplet excited state bonds to a metal through a nitrogen atom and/or a carbon atom.

3. A polymeric light-emitting substance according to claim 1 wherein at least one ligand of the iridium complex portion showing light emission from triplet excited state is a multi-dentate ligand.

4. A polymeric light-emitting substance according to claim 1 wherein at least one ligand of the iridium complex portion showing light emission from triplet excited state is a monovalent bi-dentate ligand represented by the below formula (15) or (16),

wherein R 22 to R 29 each independently represent a hydrogen atom, halogen atom, alkyl group, alkoxy group, alkylthio group, alkylamino group, alkylsilyl group, aryl group, aryloxy group, arylthio group, arylamino group, aryl silyl group, arylalkyl group, arylalkoxy group, arylalkylthio group, arylalkylamino group, arylalkylsilyl group, acyl group, acyloxy group, imino group, amide group, arylalkenyl group, arylalkynyl group, cyano group, or monovalent heterocyclic group, and at least one of R 22 to R 29 is a bond with a main chain or a side chain;

wherein E 2 represents an oxygen atom or a sulfur atom,

R 30 to R 35 each independently represent a hydrogen atom, halogen atom, alkyl group, alkoxy group, alkylthio group, alkylamino group, alkylsilyl group, aryl group, aryloxy group, arylthio group, arylamino group, arylsilyl group, arylalkyl group, aryl alkoxy group, arylalkylthio group, arylalkylamino group, arylalkylsilyl group, acyl group, acyloxy group, imino group, amide group, arylalkenyl group, arylalkynyl group, cyano group, or monovalent heterocyclic group, and

at least one of R 30 to R 35 is a bond with a main chain or a side chain.

5. An organic electroluminescent device comprising a layer which contains the polymeric light-emitting substance according to claim 1 between electrodes consisting of an anode and a cathode.