Char methanation catalyst and its use in gasification processes
The invention provides processes for generating a methane-enriched gas from a gas mixture comprising carbon monoxide and hydrogen such as gas streams generated by gasification of an alkali metal catalyst-loaded carbonaceous feedstock, and a char methanation catalyst useful in such processes.
1. A process for the production of a methane-enriched gaseous product, comprising the steps of:
(a) gasifying a carbonaceous material in a gasifying reactor, in the presence of steam and an alkali metal gasification catalyst, to produce a gaseous product stream and an alkali metal-containing solid char product, wherein the gaseous product stream comprises methane, carbon monoxide, carbon dioxide and hydrogen;
(b) withdrawing the alkali metal-containing solid char product from the gasifying reactor;
(c) introducing a gaseous mixture comprising hydrogen and carbon monoxide into a reaction zone containing at least a portion of the alkali metal-containing solid char product as a methanation catalyst,
(d) reacting at least a portion of the hydrogen with at least a portion of the carbon monoxide in the reaction zone, under suitable temperature and pressure, in the presence of the alkali metal-containing solid char product to produce a methane-enriched gaseous product, and
(e) recovering a methane-enriched gaseous product from the reaction zone.
2. The process of claim 1 , wherein the alkali metal-containing char product comprises a carbon content and an ash content, the carbon content being from about 25% to about 75% (by weight, dry basis), the alkali metal-containing char product further comprising:
(i) a total elemental oxide content of from about 65% to about 98% (based on the weight of the ash content, dry basis),
(ii) a molar ratio of alkali metal to carbon of from about 0.1 to about 0.6,
(iii) a BET surface area of from about 10 to about 400 m 2 /g,
(iv) an average particle size of from about 25 to about 2500 μm, and
(v) an average particle density of from about 0.2 to about 1.75 g/cc.
3. The process of claim 1 , wherein the gaseous mixture in step (c) is the gaseous product stream from step (a).
4. The process of claim 1 , wherein the gaseous product stream comprises at least about 20 mol % methane based on the moles of methane, carbon dioxide, carbon monoxide and hydrogen in the second gas stream.
5. The process of claim 4 , wherein the gaseous product stream comprises at least about 50 mol % methane plus carbon dioxide, based on the moles of methane, carbon dioxide, carbon monoxide and hydrogen in the second gas stream.
6. The process of claim 2 , wherein the gaseous mixture in step (c) is the gaseous product stream from step (a).
7. The process of claim 6 , wherein the gaseous product stream comprises methane, carbon monoxide, carbon dioxide and hydrogen.
8. The process of claim 7 , wherein the gaseous product stream comprises at least about 20 mol % methane based on the moles of methane, carbon dioxide, carbon monoxide and hydrogen in the second gas stream.
9. The process of claim 8 , wherein the gaseous product stream comprises at least about 50 mol % methane plus carbon dioxide, based on the moles of methane, carbon dioxide, carbon monoxide and hydrogen in the second gas stream.
10. The process of claim 1 , wherein in step (a) the carbonaceous material is gasified in a gasifying reactor, in the presence of steam, carbon monoxide, hydrogen and an alkali metal gasification catalyst, to produce the gaseous product stream and the alkali metal-containing solid char product.