Catalyst slurry, electrode prepared by using the catalyst slurry, and fuel cell including the electrode
A catalyst slurry, an electrode prepared by using the same, and a fuel cell including the electrode. The catalyst slurry includes: a catalyst material; a binder; and a solvent including a first liquid for dissolving the binder and a second liquid having a viscosity that is higher than that of the first liquid.
1. A catalyst slurry for a fuel cell, the catalyst slurry comprising:
a catalyst material;
a binder; and
a solvent comprising a first liquid for dissolving the binder and a second liquid having a viscosity that is higher than that of the first liquid,
wherein a weight ratio of the second liquid with respect to the first liquid is in a range of about 20/80 to about 1/99;
the second liquid is a material that is miscible with the first liquid and does not dissolve the binder;
the first liquid is N-methylpyrrolidone and the second liquid is dihydroterpineol.
2. The catalyst slurry of claim 1 , wherein the catalyst material comprises a carrier and a catalyst metal supported by the carrier.
3. The catalyst slurry of claim 2 , wherein the carrier comprises at least one selected from carbon powder, carbon black, acetylene black, ketjen black, active carbon, carbon nanotube, carbon nanofiber, carbon nanowire, carbon nanohorn, carbon aerogel, carbon xerogel, and carbon nanoring.
4. The catalyst slurry of claim 2 , wherein the catalyst metal comprises at least one selected from platinum (Pt), iron (Fe), cobalt (Co), nickel (Ni), ruthenium (Ru), rhodium (Rh), palladium (Pd), osmium (Os), iridium (Ir), copper (Cu), silver (Ag), gold (Au), tin (Sn), titanium (Ti), chromium (Cr), and an alloy of two or more of these.
5. The catalyst slurry of claim 1 , wherein the binder comprises at least one selected from polyvinylidene fluoride (PVdF), polytetrafluoroethylene (PTFE), a vinylidenefluoride-hexafluoropropylene copolymer, and fluorine terminated phenoxide based hyperbranched polymer (HPEF).
6. The catalyst slurry of claim 1 , wherein a viscosity of the first liquid is in a range of about 0.1 to about 10 cP, and a viscosity of the second liquid is in a range of about 10 to 100 cP.
7. The catalyst slurry of claim 1 , wherein a weight ratio of the second liquid with respect to the first liquid is in a range of about 20/80 to about 10/90.
8. An electrode for a fuel cell, the electrode comprising:
an electrode support; and
a catalyst layer disposed on the electrode support,
wherein the catalyst layer is formed using the catalyst slurry of claim 1 .
9. The electrode of claim 8 , wherein the electrode has pores and a volume of pores having a diameter of about 50 to about 100 μm is in a range of about 5 to about 6 mL/g.
10. A fuel cell comprising:
a cathode;
an anode; and
an electrolyte membrane interposed between the cathode and the anode,
wherein at least one of the cathode and the anode is the electrode of claim 8 .