Method for producing of ultra-clean and high-purity electronic grade reagents
A method for producing of ultra-clean and High-purity electronic grade reagents is disclosed. The industrial grade reagents are chemically pretreated and filtered, and the colature is rectified. Heating the steam during the rectification to overheated steam, and filtering the overheated steam used the microporous membrane to remove the solid particulates. Condensing the overheated steam and the secondarily filter to remove the dust in the product. Due to the adoption of the technical scheme, the ultra-clean and High-purity isopropanol produced is in conformity with standard SEMI-C12 and the hydrochloric acid to standard SEMI-C8. And the method is applicable for the large-scale continuous production.
1. A method for producing ultra-clean and high-purity hydrochloric acid comprising the following steps:
step 1: adding a dearsenical agent to industrial grade hydrochloric acid at room temperature and reacting for 0.5-1.5 hours to remove arsenic; filtering the hydrochloric acid and collecting a filtrate;
step 2: atmospherically rectifying the filtrate at a temperature of 115-116° C. in a top part of a rectifying column with 0.5-1.5 meter/second gas flow rate in the column, and heating steam to 118-120° C. to produce overheated steam during the rectification; then filtering the overheated steam through a microporous membrane having 0.1 μm apertures; and
step 3: condensing the overheated steam filtered in step 2 and collecting a fraction, and filtering the fraction through a microporous membrane.
2. The method according to claim 1 , wherein the dearsenical agent is hydrazine hydrate of 40% mass concentration.
3. The method according to claim 2 , wherein the weight ratio between the hydrazine hydrate and the industrial grade hydrochloric acid is 5-8:100.
4. A method of producing ultra-clean and high-purity isopropanol comprising the following steps:
step 1: adding a dehydrant to industrial grade isopropanol at room temperature and reacting for 0.5-1.5 hours; filtering the isopropanol and collecting a filtrate;
step 2: atmospherically rectifying the filtrate at a temperature of 82-83° C. in a top part of a rectifying column with 0.5-1.5 m/s gas flow rate in the column, and heating steam to 84-86° C. to produce overheated steam during the rectification; then filtering the overheated steam through a microporous membrane having 0.1 μm apertures; and
step 3: condensing the overheated steam filtered in step 2 and collecting a fraction, and filtering the fraction through a microporous membrane.
5. The method according to claim 4 , wherein the dehydrant is CaCl 2 .
6. The method according to claim 5 , wherein the weight ratio between the CaCl 2 and the industrial grade isopropanol is 3-5:100.