Sidewall functionalization of carbon nanotubes with organosilanes for polymer composites
The present invention is directed to methods of functionalizing carbon nanotubes (CNTs), particularly single-wall carbon nanotubes (SWNTs), with organosilane species, wherein such functionalization enables fabrication of advanced polymer composites. The present invention is also directed toward the functionalized CNTs, advanced CNT-polymer composites made with such functionalized CNTs, and methods of making such advanced CNT-polymer composites.
1. A composite material, comprising:
a) carbon nanotubes, wherein the carbon nanotubes are silane-functionalized with an organosilane species;
b) a fiber reinforcement material, wherein the fiber reinforcement material comprises glass fibers and wherein the organosilane species further silane-functionalizes the glass fibers;
c) a polymer;
wherein the carbon nanotubes are covalently bound to both the fiber reinforcement material and the polymer;
wherein the carbon nanotubes continuously coat the fiber reinforcement material so as to exclude the polymer between the carbon nanotubes and the fiber reinforcement material; and
wherein the carbon nanotubes comprise a bridge between the fiber reinforcement material and the polymer.
2. The composite material of claim 1 , wherein the carbon nanotubes are single-wall carbon nanotubes.
3. The composite material of claim 1 , wherein the polymer is an epoxy.
4. The composite material of claim 1 , wherein the glass fibers are in a form of woven sheets.
5. The composite material of claim 4 , wherein the woven sheets are stacked together with the carbon nanotubes and the polymer between them.
6. The composite material of claim 1 , wherein the carbon nanotubes are hydroxyl-functionalized carbon nanotubes that have been further silane functionalized;
wherein the hydroxyl-functionalized carbon nanotubes comprise undestroyed rolled up graphene sheets; and
wherein the hydroxyl-functionalized carbon nanotubes are prepared by reacting fluorinated carbon nanotubes with a reagent selected from the group consisting of a mono-metal salt of a dialcohol, a mono-metal salt of a multi-alcohol, and an amino alcohol.
7. The composite material of claim 6 , wherein the hydroxyl-functionalized carbon nanotubes are further silane functionalized with a silation reagent selected from the group consisting of a silanol and a chlorosilane.
8. The composite material of claim 1 , wherein the organosilane species is derived from a silane agent, the adding further comprises providing the silane agent, and the silane agent is selected from the group consisting of methacryl silanes, amino silanes, epoxy silanes, and styrene silanes.
9. The composite material of claim 8 , wherein the silane agent comprise an amino silane.
10. The composite material of claim 9 , wherein the amino silane comprises 3-aminopropryltrimethoxy silane.
11. The composite material of claim 10 , wherein the organosilane species is bonded to the carbon nanotubes with C—O bonds.
12. The composite material of claim 10 , wherein the organosilane species is bonded to the carbon nanotubes with C—N bonds.
13. The composite material of claim 8 , wherein the silane agent comprise an epoxy silane.
14. The composite material of claim 8 , wherein the epoxy silane comprises trimethoxyepoxy silane.