Selective catalytic reduction via electrolysis of urea

1. A method for supplying NH 3 to an exhaust gas treatment system comprising:

supplying urea to an electrolytic flow cell comprising

an inlet,

an outlet,

a cathode having a first conducting component,

an anode having a second conducting component, and

an alkaline electrolyte composition in electrical communication with the anode and the cathode, where the alkaline electrolyte composition has a hydroxide concentration of at least 0.01 M or a pH of at least 8;

producing ammonia by the electrolytic hydrolysis of urea by applying a voltage difference to the electrolytic flow cell, wherein the voltage difference is applied across the cathode and the anode, wherein the voltage difference is sufficient to effect the electrolytic hydrolysis of urea to produce at least NH 3 ;

recovering at least a portion of the NH 3 ;

transferring the at least a portion of the NH 3 to the exhaust gas treatment system; and

recirculating at least a portion of the alkaline electrolyte composition.

2. The method of claim 1 , wherein the first conducting component comprises carbon, cobalt, copper, iridium, iron, nickel, palladium, platinum, rhodium, ruthenium, or mixtures or alloys thereof.

3. The method of claim 1 , wherein the second conducting component comprises cobalt, copper, iridium, iron, platinum, nickel, rhodium, ruthenium, or mixtures or alloys thereof.

4. The method of claim 1 , wherein the second conducting component comprises an oxidized form of cobalt, copper, iridium, iron, platinum, nickel, rhodium, ruthenium, or mixtures or alloys thereof.

5. The method of claim 1 , further comprising:

varying at least one of

a temperature of the electrolytic flow cell,

a pressure of the electrolytic flow cell,

an electrical current applied to the electrolytic flow cell, or

a voltage applied to the electrolytic flow cell;

varying a voltage applied to a portion of the anode, wherein the anode comprises an anodic catalyst bed; or

varying an area percentage of a total area of the anodic catalyst bed contacting a urea solution.

6. The method of claim 1 , wherein the alkaline electrolyte composition comprises an alkali metal or alkaline earth metal salt of a hydroxide, a carbonate, a bicarbonate, or combinations thereof.

7. The method of claim 1 , further comprising heating the electrolytic flow cell.

8. The method of claim 1 , wherein the urea is provided as a solid in a cartridge.

9. The method of claim 1 , wherein supplying urea to the electrolytic flow cell comprises

diluting a concentrated stock solution of urea with at least a portion of the alkaline electrolyte composition, or

dissolving at least a portion of solid urea with water or at least a portion of the alkaline electrolyte composition.

10. The method of claim 1 , further comprising concentrating the alkaline electrolyte composition by evaporating water therefrom.

11. An exhaust gas treatment system for a combustion engine comprising:

at least one of a selective catalytic reduction system, a selective non-catalytic reduction system, or a flue gas conditioning system; and

an ammonia generator comprising an electrolytic flow cell having

an inlet,

at least one outlet,

a cathode having a first conducting component,

an anode having a second conducting component,

an alkaline electrolyte composition in electrical communication with the anode and the cathode, where the alkaline electrolyte composition has a hydroxide concentration of at least 0.01 M or a pH of at least 8, and

a recirculation system operatively coupled to the inlet and the at least one outlet of the electrolytic cell,

wherein the at least one outlet from the ammonia generator is further in communication with the at least one of the selective catalytic reduction system, the selective non-catalytic reduction system, or the flue gas conditioning system.

12. The exhaust gas treatment system of claim 11 , wherein the first conducting component comprises carbon, cobalt, copper, iridium, iron, nickel, palladium, platinum, rhodium, ruthenium, or mixtures or alloys thereof.

13. The exhaust gas treatment system of claim 11 , wherein the second conducting component comprises cobalt, copper, iridium, iron, platinum, nickel, rhodium, ruthenium, or mixtures or alloys thereof.

14. The exhaust gas treatment system of claim 11 , wherein the second conducting component comprises an oxidized form of cobalt, copper, iridium, iron, platinum, nickel, rhodium, ruthenium, or mixtures or alloys thereof.

15. The exhaust gas treatment system of claim 11 , wherein the alkaline electrolyte composition comprises an alkali metal or alkaline earth metal salt of a hydroxide, a carbonate, a bicarbonate, or combinations thereof.

16. The exhaust gas treatment system of claim 11 , wherein the electrolytic cell further comprises

a heater apparatus operatively coupled to the electrolytic cell.

17. The exhaust gas treatment system of claim 11 , wherein the electrolytic cell further comprises a cartridge containing solid urea.

18. The exhaust gas treatment system of claim 11 , wherein the recirculation system further comprises an evaporator.

19. An ammonia generator comprising an electrolytic flow cell having

an inlet,

at least one outlet,

a cathode having a first conducting component,

an anode having a second conducting component,

an alkaline electrolyte composition in electrical communication with the anode and the cathode, where the alkaline electrolyte composition has a hydroxide concentration of at least 0.01 M or a pH of at least 8, and

a recirculation system operatively coupled to the inlet and the at least one outlet of the electrolytic cell.

20. The ammonia generator of claim 19 , wherein the recirculation system further comprises an evaporator.