Acrylonitrile copolymer and method for producing the same, acrylonitrile copolymer solution and polyacrylonitrile precursor fiber for carbon fiber and method for producing the same
Disclosed are an acrylonitrile copolymer excellent in thermal stability as a solution (spinning dope) when dissolved in an amide solvent and capable of forming dense polyacrylonitrile fiber suitable for production of carbon fiber, an acrylonitrile copolymer solution in which the acrylonitrile copolymer is dissolved in an amide solvent, and a method for producing polyacrylonitrile precursor fiber for carbon fiber by use of the acrylonitrile copolymer solution. Specifically, an acrylonitrile copolymer contains a sulfonate group derived from a polymerization initiator in an amount of 1.0×10 −5 equivalent/g or more, and the value (equivalent ratio) of (the content of a sulfate group derived from the polymerization initiator/the total content of the sulfonate group and the sulfate group) is 0.4 or less; an acrylonitrile copolymer solution contains the aforementioned acrylonitrile copolymer and an amide solvent.
1. An acrylonitrile copolymer comprising a sulfonate group derived from a polymerization initiator in an amount of 1.0×10 −5 equivalent/g or more, an equivalent ratio of a content of a sulfate group derived from the polymerization initiator/a total content of the sulfonate group and the sulfate group being 0.4 or less,
wherein a total content of the sulfonate group and/or the sulfate group in the acrylonitrile copolymer is 1.0×10 −5 equivalent/g or more and less than 4.0×10 −5 equivalent/g.
2. A method for producing the acrylonitrile copolymer according to claim 1 , comprising
copolymerizing acrylonitrile with a vinyl monomer in the presence of at least one polymerization initiator selected from the group consisting of a persulfate and a sulfite.
3. A method for producing the acrylonitrile copolymer according to claim 1 ,
comprising copolymerizing acrylonitrile with a vinyl monomer in the presence of at least one polymerization initiator selected from the group consisting of a persulfate and a sulfite to form a copolymer, then hydrolyzing a sulfate group in the copolymer.
4. The method for producing the acrylonitrile copolymer according to claim 3 , wherein hydrolysis of the sulfate group in said copolymer is carried out in a solution comprising said copolymer and an amide solvent.
5. An acrylonitrile copolymer solution comprising the acrylonitrile copolymer according to claim 1 and an amide solvent.
6. The acrylonitrile copolymer solution according to claim 5 , wherein the amide solvent is at least one of dimethylacetamide and dimethylformamide.
7. A method for producing polyacrylonitrile precursor fiber for carbon fiber comprising the step of spinning the acrylonitrile copolymer solution according to claim 5 or 6 as spinning dope.
8. Acrylonitrile precursor fiber for carbon fiber to be obtained from coagulated fiber obtained by spinning of an acrylonitrile copolymer solution as spinning dope, an acrylonitrile copolymer in said precursor fiber being the acrylonitrile copolymer according to claim 1 .