Monovinylaromatic polymer composition comprising a polymer made from renewable resources as a dispersed phase
The present invention concerns a monovinylaromatic polymer composition comprising a bio-sourced polymer dispersed phase and optionally a rubber dispersed phase wherein said bio-sourced polymer dispersed phase is predominantly made of particles having a size of less than 10 μm. The present invention also relates to a process (hereunder referred as the first process) to make said monovinylaromatic polymer composition, said process comprising admixing: a monovinylaromatic monomer, at least one bio-sourced polymer, optionally a rubber, at conditions effective to polymerize at least a part of the monovinylaromatic monomer and generate a compatibilizer of the bio-sourced polymer and monovinylaromatic polymer. The present invention also relates to a process (hereunder referred as the second process) to make said monovinylaromatic polymer composition, said process comprising admixing: a monovinylaromatic monomer, functionalized bio-sourced polymer-s), or mixtures of bio-sourced polymer(s) and functionalized bio-sourced polymer(s), optionally a rubber, at conditions effective to polymerize at least a part of the monovinylaromatic monomer. The present invention also relates to a process (hereunder referred as the third process) to make said monovinylaromatic polymer composition, said process comprising blending in the molten state functionalized bio-sourced polymer(s) (or mixtures of bio-sourced polymer(s) and functionalized bio-sourced polymer(s)) with monovinylaromatic polymer, said monovinylaromatic polymer comprising optionally a rubber.
1. A polymer composition comprising:
a monovinylaromatic polymer continuous phase; and
a bio-sourced polymer dispersed phase dispersed in the monovinylaromatic polymer continuous phase;
wherein the bio-sourced polymer dispersed phase is predominantly made of particles having a size of less than 10 μm, wherein the bio-sourced polymer dispersed phase is characterized by the formula:
wherein x is ≧0, and wherein R 1 is an alkyl group.
2. The polymer composition of claim 1 , wherein the particles of the bio-sourced polymer dispersed phase have predominantly a size from 0.1 to 4 μm.
3. The polymer composition of claim 1 , wherein the particles of the bio-sourced polymer dispersed phase have predominantly a size from 0.1 to 2 μm.
4. The polymer composition of claim 1 , wherein the particles of the bio-sourced polymer dispersed phase have predominantly a size from 0.1 to 1 μm.
5. The polymer composition of claim 1 , wherein the particles of the bio-sourced polymer dispersed phase have predominantly a size from 0.1 to 0.7 μm.
6. The polymer composition of claim 1 , wherein the weight proportions of the polymer composition comprise 50% to 99% of monovinylaromatic polymer and 1% to 50% of bio-sourced polymer.
7. The polymer composition of claim 1 , further comprising a rubber dispersed phase.
8. The polymer composition of claim 7 , wherein the rubber dispersed phase ranges from 0 wt % to 35 wt % of the polymer composition.
9. The polymer composition of claim 8 , wherein the rubber dispersed phase and bio-sourced polymer together comprise from 1 wt % to 50 wt % of the polymer composition.
10. The polymer composition of claim 7 , wherein the weight proportions of the polymer composition are: 50 to 99% of monovinylaromatic polymer; 1 to 50% of bio-sourced polymer; and 0 to 35% of rubber; wherein the weight proportion of the bio-sourced polymer plus the rubber ranges from 1 to 50%, with the balance being monovinylaromatic polymer.
11. The polymer composition of claim 1 , wherein the bio-sourced polymer is selected from the group comprising polyhydroxyacids, polyhydroxyalkanoates, and combinations thereof.
12. The polymer composition of claim 1 , wherein the bio-sourced polymer is selected from the group comprising poly(lactic acid), polyhydroxybutyrate, polyhydroxyvalerate, polyhydroxyhexanoate, polyhydroxyoctanoate, and combinations thereof.
13. The polymer composition of claim 1 , wherein the bio-sourced polymer dispersed phase comprises functionalized bio-sourced polymers or mixtures of bio-sourced polymers and functionalized bio-sourced polymers.
14. The polymer composition of claim 1 , wherein the bio-sourced polymer dispersed phase comprises monovinylaromatic polymer inclusions.
15. The polymer composition of claim 1 , wherein the monovinylaromatic polymer comprises monovinylaromatic monomers selected from the group consisting of: styrene, vinyl toluene, alphamethylstyrene, alphaethylstyrene, methyl-4-styrene, methyl-3-styrene, methoxy-4-styrene, hydroxymethyl-2-styrene, ethyl-4-styrene, ethoxy-4-styrene, dimethyl-3,4-styrene, chloro-2-styrene, chloro-3-styrene, chloro-4-methyl-3-styrene, tert.-butyl-3-styrene, dichloro-2,4-styrene, dichloro-2,6-styrene, vinyl-1-naphtalene, vinylanthracene, and combinations thereof.
16. The polymer composition of claim 15 , wherein the monovinylaromatic polymer further comprises unsaturated monomers copolymerizable with styrene selected from the group consisting of: alkyl esters of acrylic or methacrylic acid, acrylonitrile, and methacrylonitrile.
17. The polymer composition of claim 7 , wherein the rubber dispersed phase and the bio-sourced polymer dispersed phase each contain at least one sub-particle of occluded monovinylaromatic polymer.
18. The polymer composition of claim 17 , wherein the rubber dispersed phase and the bio-sourced polymer dispersed phase each have a dispersed phase morphology selected from the group consisting of: core-shell particles, salami morphology type, labyrinths, onions, rods, or droplets.
19. The polymer composition of claim 7 , wherein the rubber dispersed phase and the bio-sourced polymer dispersed phase are independent particles.
20. The polymer composition of claim 7 , wherein the rubber dispersed phase comprises: ethylene-propylene rubber, ethylene-propylene elastomer, ethylene-propylene-diene rubber, ethylene-propylene-diene elastomer, polybutadiene, acrylonitrile-butadiene copolymer, polyisoprene, isoprene-acrylonitrile copolymer, styrene butadiene rubber, styrenic block copolymers with a hydrogenated midblock of styrene-ethylene/butylene-styrene or styrene-ethylene/propylene-styrene, a copolymer having styrene blocks, copolymers and homopolymers of C 4 -C 6 conjugated diolefins, copolymers comprising from 60 weight % to 85 weight % of one or more C 4 -C 6 conjugated diolefins and from 15 weight % to 40 weight % of acrylonitrile monomers or methacrylonitrile monomers, copolymers comprising from 20 weight % to 60 weight % of one or more C 8 -C 12 vinyl aromatic monomers that are unsubstituted or are substituted by a C 1 -C 4 alkyl radical and from 60 weight % to 40 weight % of one or more C 4 -C 6 conjugated diolefins monomers.