Process and apparatus for converting organic matter into a product
View Patent ↗A process for treating organic matter to convert it into a product comprises the step of contacting the organic matter with supercritical liquid whereby it reacts to form the product. The liquid may be heated by an external heating medium, or may be heated internally of the process by co-feeding an oxidising agent with the liquid. This agent can be in an amount that is predetermined to control the extent to which the reaction mixture is heated. The heat can be supplied to provide sufficient activation energy for the process reaction to occur with sufficient speed and for the liquid to attain sufficient characteristics to cause the reaction.
1. A process for converting organic matter into a product, the process comprising
producing a reaction mixture comprising water and the organic matter, and
heating the reaction mixture to a temperature of between 350° C. and 420° C. and a pressure of greater than about 220 bar to produce supercritical or subcritical water and thereby convert the organic matter into the product, wherein
the supercritical or subcritical water is produced internally of the reaction mixture by heating in a fixed volume,
the organic matter comprises lignite (brown coal) or a combination of hemicellulose, cellulose and lignin, and
the product comprises a liquid phase of petroleum products and either or both of: (i) a solid char product; (ii) a gas product comprising one or more of methane, hydrogen, carbon monoxide.
2. The process according to claim 1 , wherein said heating comprises combustion of at least a portion of the organic matter with an oxidizing agent.
3. The process according to claim 2 , wherein the reaction mixture comprises a predetermined amount of said oxidizing agent to control the extent to which the reaction mixture is heated.
4. The process according to claim 2 , wherein the oxidizing agent is selected from one or more of oxygen, hydrogen peroxide and sodium nitrate.
5. The process according to claim 1 , wherein producing the supercritical or subcritical liquid comprises pressurizing the reaction mixture in a sub-terrestrial or sub-oceanic vessel using pressure external to said vessel.
6. The process according to claim 1 , wherein the reaction mixture further comprises supercritical or subcritical methanol and/or ethanol.
7. The process according to claim 1 , wherein the organic matter is in the form of a slurry having a ratio of liquid to solid of less than about 12:1.
8. The process according to claim 1 , wherein the organic matter is in the form of a slurry having a ratio of liquid to solid of more than about 2:1.