GI type optical fiber and method for manufacturing same
A GI type optical fiber of the present invention is a GI type optical fiber having a core component and a cladding component disposed around the outer periphery of the core component, the core component includes a polymer containing at least 55 wt % chlorostyrene monomer and a dopant, and the cladding component includes a polymer of a monomer containing at least 35 wt % methyl methacrylate. It is an object of the present invention to provide a GI type optical fiber in which chlorostyrene is used as the predominant component of the monomer that constitutes the core component, and therefore has excellent transparency and good flexibility, and allows high-speed communication.
1. A GI type optical fiber comprising a core component and a cladding component disposed around the outer periphery of the core component,
wherein the core component includes a dopant and a polymer of monomers containing methyl methacrylate and at least 55 wt% of chlorostyrene monomer, and
wherein the cladding component includes a polymer of a monomer containing at least 35 wt% of methyl methacrylate.
2. The GI type optical fiber according to claim 1 ,
wherein the polymer included in the core component is a polymer as a predominant constituent component whose structural units are monomers including 55 to 100 wt% chlorostyrene and 0 to 45 wt% methyl methacrylate, and
the polymer included in the cladding component is a polymer as a predominant constituent component whose structural units are monomers including methyl methacrylate and at least one compound selected from the group consisting of styrene, α-methyl styrene and N-cyclohexylmaleimide.
3. The GI type optical fiber according to claim 1 , wherein the polymer included in the cladding component is a polymer as the predominant constituent component whose structural units are 35 to 70 wt% methyl methacrylate, 30 to 65 wt% styrene and 0 to 15 wt% N-cyclohexylmaleimide.
4. The GI type optical fiber according to claim 1 , wherein the numerical aperture at one or more wavelengths from 630 to 690 nm, expressed as NA=(n 1 2 −n 2 2 ) 1/2 (wherein n 1 is the refractive index of a center part of the core component, and n 2 is the refractive index of the cladding component), is at least 0.25.
5. The GI type optical fiber according to claim 1 , wherein a center part of the core component includes 100 weight parts of the polymer and 2 to 8 weight parts dopant.
6. The GI type optical fiber according to claim 1 , wherein the chlorostyrene monomer is a monomer whose aniline content is no more than 100 ppm.
7. The GI type optical fiber according to claim 1 , which is used in a video-related optical link system.
8. A method for manufacturing a GI type optical fiber comprising:
subjecting a monomer including chlorostyrene to an aniline removal step so that the aniline concentration is no more than 100 ppm with respect to the total monomer weight, and
using a resulting chlorostyrene polymer by polymerizing the monomer thus obtained as a core component to manufacture a plastic optical fiber composed of the core component and a cladding component disposed around the outer periphery of the core component.
9. The method for manufacturing a GI type optical fiber according to claim 8 , wherein the aniline removal step is a method involving adsorptive separation.
10. A method for manufacturing a GI type optical fiber, a plastic optical fiber composed of a core component and a cladding component disposed around the outer periphery of the core component is manufactured by using for the core component a chlorostyrene polymer obtained in a step of removing aniline from a monomer including chlorostyrene and/or a step of removing dissolved oxygen.
11. The method for manufacturing a GI type optical fiber according to claim 10 , wherein the dissolved oxygen removal step is a method involving reduced pressure deaeration under ultrasonic waves.
12. The method for manufacturing a GI type optical fiber according to claim 10 , wherein the dissolved oxygen removal step is a method involving bubbling with an inert gas.
13. The method for manufacturing a GI type optical fiber according to claim 10 , wherein the aniline removal step is a method involving adsorptive separation.
14. A method for manufacturing a GI type optical fiber, a plastic optical fiber composed of a core component and a cladding component disposed around the outer periphery of the core component is manufactured by using for the core component a chlorostyrene polymer obtained by polymerizing a monomer in which the aniline content is no more than 100 ppm with respect to the total monomer weight.