IP Library Granted Patent US 8,603,240
Granted Patent B2
US 8,603,240 · App. 13/704,041 · Granted Dec 10, 2013

Converting coal ash and electric arc furnace dust into glass-ceramic materials

Inventors: James Morano (Hallandale, FL); John Buddemeyer (Salisbury, NC)
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Quick Facts
Patent No.
US 8,603,240
App. No.
13/704,041
Granted
Dec 10, 2013
Kind
B2
Abstract

A process for control melting a mixture of coal ash, electric arc furnace dust, recycled glass and additives to create a feedstock. The feedstock is quenched or air dried in a mold to create useful products, such as fracking compounds, abrasives, construction products, building materials, landscaping materials, and the like.

Claims (30)

1. A process for converting Coal Ash and EAFD into a feedstock comprising:

a. preparing a mixture of Coal Ash and EAFD;

b. adding cullet and an additive to form a blend;

c. melting the blend at a controlled temperature and time in an oxidizing atmosphere to create the feedstock, the feedstock comprising at least one spinel or metasilicate;

d. processing the feedstock by grinding or crushing.

2. The process of claim 1 wherein the blend comprises about 90% to about 30% Coal Ash, up to about 50% EAFD, about 30% to about 10% of cullet and a trace of additive.

3. The process of claim 1 wherein the blend comprises about 95% to about 30% Coal Ash, up to about 50% EAFD, about 40% to about 5% of cullet and up to about 15% of additive.

4. The process of claim 1 wherein the additive is a crystallization catalyst that improves at least one of fracture, friability and toughness of the feedstock.

5. The process of claim 4 wherein the crystallization catalyst is a recycled abrasive.

6. The process of claim 1 wherein the additive is at least one of titanium dioxide, silicon dioxide, zirconium dioxide, potassium oxide and chromite sand.

7. The process of claim 1 wherein the additive is at least one of a silica, a metal and sodium.

8. The process of claim 7 wherein the at least one of a silica, metal and sodium is sourced from a waste stream.

9. The process of claim 8 wherein the waste stream is one of a contaminated soil, a sludge, a surface water, and a ground water.

10. The process of claim 1 wherein up to about 40% of the additive is a recycled abrasive.

11. The process of claim 1 wherein the blend is melted at a controlled temperature of from about 1500° F. to about 3000° F. for about 4 hours to about 8 hours.

12. The process of claim 1 wherein the melting takes place in a kiln with an atmosphere of about at least 5% excess oxygen.

13. The process of claim 1 wherein the processing comprises quenching the feedstock to create a fractured product prior to grinding the feedstock to produce an abrasive.

14. The process of claim 1 wherein the processing comprises air drying the feedstock in a mold prior to grinding or crushing.

15. The process of claim 1 wherein the feedstock is processed into an aggregate.

16. The process of claim 15 wherein the aggregate is used for one of a rip rap, a road bed, a rail bed, and a ballast.

17. The process of claim 1 wherein the ground or crushed feedstock is used to produce a product selected from the group consisting of a fracking compound, a proppant, a packing material, a sandpaper product, a grinding wheel, an abrasive, a lubricant, a construction product, an insulation material, a building material, a household good, a filler, a fiber, a bead, a non-woven product, a water jet cutting system, a non-skid surface material, an aggregate and a landscaping material.

18. The process of claim 16 wherein the building material is selected from the group consisting of: a wallboard, roofing material, countertops, and ceramic fixtures.

19. A product produced by the process of claim 1 .

20. The product of claim 19 wherein the product is selected from the group consisting of a fracking compound, a proppant, a packing material, a sandpaper product, a grinding wheel, an abrasive, a construction product, an insulation material, a building material, a household good, a filler, a fiber, a bead, a non-woven product, a water jet cutting system, a non-skid surface material, an aggregate and a landscaping material.

21. The product of claim 19 wherein the product is ground into a rounded particle.

22. A process for converting Coal Ash and EAFD into a product comprising:

a. preparing a mixture of about 30% by weight of EAFD, the EAFD containing at least iron with about 48% Coal Ash, the Coal Ash containing at least silica and alumina;

b. adding about 18% cullet and about 4% titanium dioxide to the mixture to form a blend;

c. melting the blend at a temperature from about 2400 degrees Fahrenheit to about 2600 degrees Fahrenheit in a continuous float glass type kiln for about 4 hours to about 8 hours in an oxidizing atmosphere to chemically bind at least one hazardous material contained in the EAFD in a silicate matrix in the feedstock, the feedstock comprising at least one spinel or metasilicate; and

d. processing the feedstock by grinding or crushing.

Continuity (2)
Provisional Application 61357393 · Jun 22, 2010
Related Publication 20130097942A1 · Apr 25, 2013