CO2-sequestering formed building materials
CO 2 -sequestering formed building materials are provided. The building materials of the invention include a composition comprising a carbonate/bicarbonate component. Additional aspects of the invention include methods of making and using the CO 2 -sequestering formed building material.
1. A method for producing a formed building material comprising:
a) contacting a gaseous waste stream comprising CO 2 with water comprising proton removing agent to form a CO 2 charged water;
b) producing a CO 2 -sequestering component from a solution of divalent cations and the CO 2 charged water under one or more of precipitation conditions favoring precipitation of the CO 2 -sequestering component comprising a metastable carbonate comprising vaterite, aragonite, or combinations thereof; and
c) forming the formed building material from the CO 2 -sequestering component in a process comprising contacting the CO 2 -sequestering component with water, wherein the formed building material is a cement board.
2. The method of claim 1 , wherein the gaseous waste stream further comprises NOx, SOx, VOCs, particulates, mercury, or a combination thereof.
3. The method of claim 1 , wherein the formed building material comprises 50% (w/w) CO 2 -sequestering component or more.
4. The method of claim 1 , wherein the CO 2 -sequestering component further comprises bicarbonates.
5. The method of claim 4 , wherein the carbonates or the combination of the carbonates and bicarbonates has a δ 13 C less than −5‰.
6. The method of claim 1 , wherein the CO 2 -sequestering component further comprises calcite, ikaite, magnesite, barringtonite, nesquehonite, landfordite, amorphous magnesium carbonate, or a combination thereof.
7. The method of claim 1 , wherein the carbonates are metastable such that upon contact with freshwater, the carbonates reprecipitate into freshwater stable compounds.
8. The method of claim 1 , wherein the CO 2 -sequestering component further comprises magnesium.
9. The method of claim 8 , wherein the CO 2 -sequestering component further comprises strontium.
10. The method of claim 1 , wherein the CO 2 -sequestering component further comprises co-products of NOx, SOx, VOCs, particulates, mercury, or a combination thereof.
11. The method of claim 10 , wherein the CO 2 -sequestering component further comprises sulfates.
12. The method of claim 1 , wherein precipitating the CO 2 -sequestering component comprises utilizing a low-voltage electrochemical method for removing protons from the solution of divalent cations and the gaseous waste stream comprising CO 2 .
13. The method of claim 1 , wherein producing the CO 2 -sequestering component further comprises dewatering the CO 2 -sequestering component after precipitating the CO 2 -sequestering component to produce a dewatered CO 2 -sequestering component.
14. The method of claim 13 , wherein the dewatered CO 2 -sequestering component is directly used in forming the formed building material.
15. The method of claim 14 , wherein at least some water for forming the formed building material is provided by the CO 2 -sequestering component.
16. The method of claim 1 , wherein forming the formed building material comprises molding, casting, cutting, extruding, sculpting, rolling, compacting, or combinations thereof, the CO 2 -sequestering component.
17. The method of claim 1 , wherein the cement board has a carbon footprint that is neutral or negative.
18. The method of claim 1 , wherein the cement board has a compressive strength ranging from 5 to 50 MPa.
19. The method of claim 1 , further comprising adding plasticizer, foaming agent, accelerator, retarder, air entrainment additive, or combinations thereof, to the CO 2 -sequestering component to form the cement board.
20. The method of claim 1 , further comprising covering face of the cement board with a fiberglass mat.
21. The method of claim 1 , further comprising adding glass fiber to the CO 2 -sequestering component to form the cement board.
22. The method of claim 1 , wherein the cement board is a backer board.
23. The method of claim 1 , wherein the one or more of precipitation conditions are selected from the group consisting of temperature, pH, additive, ion ratio, rate of precipitation, mixing rate, forms of agitation, and presence of seed crystal, catalyst, membrane, or substrate.
24. The method of claim 1 , further comprising contacting the CO 2 -sequestering component with an additional component selected from the group consisting of clay, shale, soft slate, calcium silicate, quarried stone, Portland cement, fly ash, slag, aggregate, silica fume, pozzolans, and combinations thereof.