Internal connector for organic electronic devices

1. An electronic device comprising an anode and a cathode, between which there are at least two organic phototransducing units where the units are separated by an intermediate connecting region which comprises:

a) an organic p-type layer;

b) an intermediate layer in direct contact with the organic p-type layer consisting essentially of a single compound that has a LUMO more negative than −3.0 eV and is different from an organic compound in the organic p-type layer; and

c) an organic n-type doped layer in direct contact with the intermediate layer and including an electron transport material as a host and an organic n-dopant with an effective HOMO less negative than −4.5 eV.

2. The device of claim 1 wherein the organic n-dopant has an effective HOMO less negative than −3.5 eV.

3. The device of claim 1 wherein the n-dopant is selected from 2,2′-Diisopropyl -1,1′,3,3′-tetramethyl-2,2′,3,3′,4,4′,5,5′,6,6′,7,7′-dodecahydro-2,2′-bibenzo [d]imidazole (NDR-1); 4,4′,5,5′-Tetracyclohexyl-1,1′,2,2′,3,3′-hexamethyl-2,2′,3,3′-tetrahydro -2,2′-biimidazole (NDR-2); 2,2′-diisopropyl-4,4′,5,5′-tetrakis(2-methoxyphenyl)-1,1′,3,3′-tetramethyl-2,2′,3,3′-tetrahydro-1H,1′H-2,2′-biimidazole (NDR-3); 2,2′-diisopropyl-1,1′,3,3′-tetramethyl-2,2′,3,3′-tetrahydro-1H,1′H-2,2′-bibenzo[d]imidazole (NDR-4);

2,2′-diisopropyl-4,4′,5,5′-tetrakis(3-methoxyphenyl)-1,1′,3,3′-tetramethyl-2,2′,3,3′-tetrahydro-1H,1′H-2,2′-biimidazole (NDR-5); 2-Isopropyl-1,3-dimethyl-2,3,6,7-tetrahydro-5,8-dioxa-1,3-diaza -cyclopenta[b]naphthene; Bis-[1,3-dimethyl-2-isopropyl-1,2-dihydro-benzimidazolyl-(2)];

and 2,2′-Diisopropyl-4,5-bis (2-methoxyphenyl)-4′,5′bis(4-methoxyphenyl)-1,1′,3,3′-tetramethyl -2,2′,3,3′tetrahydro-2,2′-biimidazole.

4. The device of claim 1 wherein the organic p-type layer is a p-type doped layer including an aromatic tertiary amine as a host and a p-type dopant with a LUMO more negative than -4.5 eV.

5. The device of claim 4 wherein the p-type dopant is chosen from hexaazatriphenylene compounds, fluorinated derivatives of tetracyanobenzoquinonedimethane or radialenes.

6. The device of claim 1 wherein the intermediate layer includes a metal phthalocyanine.

7. A tandem OLED comprising an anode and a cathode, between which there are at least two electroluminescent units where the units are separated by an intermediate connecting region which comprises:

a) an organic p-type layer;

b) an intermediate layer in direct contact with the organic p-type layer, consisting essentially of a single compound that has a LUMO more negative than −3.0 eV and is different from an organic compound in the organic p-type layer; and

c) an organic n-type doped layer in direct contact with the intermediate layer and including an electron transport material as a host and an organic n-dopant with an effective HOMO less negative than −4.5 eV.

8. The tandem OLED of claim 7 wherein white light is emitted.

9. The tandem OLED of claim 7 wherein the organic p-type layer includes one or more compounds selected from the group consisting of 2,2′-(perfluorocyclohexa-2,5-diene-1,4-diylidene) dimalononitrile (TCNQ-1); N′-Dicyan-2,3,5,6-tetrafluoro-1,4-chinondiimine; N,N′-Dicyan-2,5-dichloro-1,4-chinondiimine; N,N′-Dicyan-2,5-dichloro -3,6-difluoro-1,4-chinondiimine; N,N′-Dicyan-2,3,5,6,7,8-hexafluoro-1,4-naphthochinondiimine; 1,4,5,8-Tetrahydro-1,4,5,8-tetrathia-2,3,6,7-tetracyanoanthrachinone;

1,3,4,5,7,8-Hexafluoronaphtho-2,6-chinontetracyanomethane (TCNQ-7); 2,2′-(2,5-Dibrom-3,6-difluorcyclohexa -2,5-dien-1,4-diyliden)dimalononitrile; 4,4′-(1E,1′E)-(2-cyano-3,6-difluoro-5-isocyanocyclohexa -2,5-diene-1,4-diylidene)bis(cyanomethan-1-yl-1-ylidene)bis(2,3,5,6-tetrafluorobenzonitrile); 2,2′,2″-(Cyclopropan-1,2,3- triyliden)tris(2-(2,6-dichlor-3,5-difluor-4-(trifluormethyl)phenyl)acetonitrile); (2E,2′E,2″E)-2,2′,2″-(cyclopropane-1,2,3-triylidene)tris(2-(perfluorophenyl) acetonitrile); 2,2′,2″-(cyclopropane-1,2,3-triylidene)tris(2-(perfluorobiphenyl-4-yl)acetonitrile); 2,2′,2″-(cyclopropane-1,2,3-triylidene)tris(2-(2,6-dichloro-3,5-difluoro-4-(trifluoromethyl) phenyl)-acetonitrile);and Benzeneacetonitrile, α,α′ ,α″-1,2,3-cyclopropanetriylidenetris[4-cyano-2,3,5,6-tetrafluorol].

10. The tandem OLED of claim 7 wherein the electron transporting material as a host in the organic n-type doped layer is chosen from metal oxinoids, anthracenes, rubrenes, fluoranthenes or phenanthrolines.

11. The tandem OLED of claim 7 wherein the organic p-type layer consists essentially of a hexaaztriphenylene compound.

12. The tandem OLED of claim 7 wherein the organic p-type layer is an organic p-type doped layer including an aromatic tertiary amine as a host and a p-dopant with a LUMO more negative than −4.5 eV.

13. The tandem OLED of claim 12 wherein the p-dopant is chosen from hexaazatriphenylene compounds, fluorinated derivatives of cyanobenzoquinonedimethanes or radialenes.

14. The tandem OLED of claim 12 wherein p-dopant in the p-type doped layer is chosen from fluorinated derivatives of tetracyanobenzoquinonedimethane or radialenes and the intermediate layer consists essentially of a hexaazatriphenylene compound.

15. The tandem OLED of claim 14 wherein the hexaazatriphenylene compound in the intermediate layer is:

16. The tandem OLED of claim 7 wherein the intermediate layer includes a metal phthalocyanine.

17. The tandem OLED of claim 16 wherein the metal phthalocyanine is copper phthalocyanine.

18. A solar cell comprising an anode and a cathode, between which there are at least two organic photoactive units where the units are separated by an intermediate connecting region which comprises:

a) an organic p-type layer;

b) an intermediate layer in direct contact with the organic p-type layer consisting essentially of a single compound that has a LUMO more negative than −3.0 eV and is different from an organic compound in the organic p-type layer; and

c) an organic n-type doped layer in direct contact with the intermediate layer and including an electron transport material as a host and an organic n-dopant with an effective HOMO less negative than −4.5 eV.