Adhesive composition and optical member using the same
An adhesive composition includes a (meth)acrylic copolymer, the (meth)acrylic copolymer containing about 92 to about 99.7 parts by weight of a moiety derived from a (meth)acrylic acid ester monomer, and about 0.3 to about 8 parts by weight of at least one of a moiety derived from a carboxyl group-containing monomer and a moiety derived from a hydroxyl group-containing (meth)acrylic acid monomer, the (meth)acrylic copolymer having a weight average molecular weight of about 500,000 g/mol to about 2,000,000 g/mol, a carbodiimide curing agent, and an oligomeric silane coupling agent.
1. An adhesive composition, comprising:
a (meth)acrylic copolymer, said (meth)acrylic copolymer containing about 92 to about 99.7 parts by weight of a moiety derived from a (meth)acrylic acid ester monomer, and about 0.3 to about 8 parts by weight of at least one of a moiety derived from a carboxyl group-containing monomer and a moiety derived from a hydroxyl group-containing (meth)acrylic acid monomer, said (meth)acrylic copolymer having a weight average molecular weight of about 500,000 g/mol to about 2,000,000 g/mol;
a carbodiimide curing agent; and
an oligomeric silane coupling agent.
2. The adhesive composition as claimed in claim 1 , wherein said adhesive composition comprises:
about 100 parts by weight of said (meth)acrylic copolymer,
about 0.01 to about 1.0 part by weight of said carbodiimide curing agent, and
about 0.02 to about 1.0 part by weight of said oligomeric silane coupling agent.
3. The adhesive composition as claimed in claim 1 , further comprising an isocyanate curing agent.
4. The adhesive composition as claimed in claim 3 , wherein said isocyanate curing agent is present in an amount of about 0.05 to about 5 parts by weight, based on 100 parts by weight of the (meth)acrylic copolymer.
5. The adhesive composition as claimed in claim 1 , wherein said (meth)acrylic copolymer has a weight average molecular weight of about 600,000 g/mol to about 1,800,000 g/mol.
6. The adhesive composition as claimed in claim 1 , wherein said oligomeric silane coupling agent has an organic functional group.
7. The adhesive composition as claimed in claim 6 , wherein said adhesive composition has an adhesive strength of about 0.5 to about 5.0 N/25 mm at a peeling angle of 90 degrees and at a peeling rate of 0.3 m/min.
8. The adhesive composition as claimed in claim 6 , wherein said organic functional group is at least one of a vinyl group, an epoxy group, a styryl group, a (meth)acryloyl, a methacryloxy group, an acryloxy group, an amino group, a ureido group, a chloropropyl group, a mercapto group, and a polysulfide group.
9. The adhesive composition as claimed in claim 8 , wherein said (meth)acrylic acid ester monomer is selected from methyl (meth)acrylate, ethyl (meth)acrylate, n-butyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, and combinations thereof.
10. The adhesive composition as claimed in claim 9 , wherein said (meth)acrylic copolymer includes said moiety derived from a carboxyl group-containing monomer, and said carboxyl group-containing monomer is selected from (meth)acrylic acid, maleic acid, maleic anhydride, fumaric acid, fumaric anhydride, crotonic acid, itaconic acid, itaconic anhydride, and combinations thereof.
11. The adhesive composition as claimed in claim 10 , wherein said (meth)acrylic copolymer includes said moiety derived from a hydroxyl group-containing (meth)acrylic acid monomer, and said hydroxyl group-containing (meth)acrylic acid monomer is selected from 2-hydroxyethyl (meth)acrylate, 4-hydroxybutyl (meth)acrylate, 2-hydroxyethyl (meth)acrylamide, cyclohexane dimethanol monoacrylate, and combinations thereof.
12. An optical member comprising an adhesive layer formed of the adhesive composition as claimed in claim 1 .