IP Library Granted Patent US 8,628,739
Granted Patent B2
US 8,628,739 · App. 13/364,107 · Granted Jan 14, 2014

Direct purification of a nickel laterite leaching effluent

Inventors: Tiago Valentim Berni (Belo Horizonte, BR); Antonio Clareti Pereira (Belo Horizone, BR)
Assignee: Vale
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Quick Facts
Patent No.
US 8,628,739
App. No.
13/364,107
Granted
Jan 14, 2014
Kind
B2
Abstract

The present invention refers to a direct purification process of a nickel laterite leaching effluent including adjusting a pH of a leaching solution, employing an ion exchange resin to adsorb nickel and copper selectively over ferric or ferrous iron, and recovering nickel.

Claims (15)

1. A direct purification process of a nickel laterite leaching effluent, comprising:

providing a nickel laterite leaching solution;

adjusting the pH of the nickel laterite leaching solution to be between 1.0 and 3.0;

contacting the pH-adjusted nickel laterite leaching solution with a bis-picolylamine ion exchange resin to adsorb nickel and copper selectively over iron and cobalt; and

recovering nickel, wherein the pH-adjusted leaching solution is fed at a temperature between 0° C. and 100° C., and at a flow rate of 5 to 50 BV/h.

2. The process according to claim 1 , wherein the pH of the leaching solution is adjusted to be between 1.5 and 2.0.

3. The process according to claims 1 , wherein the leaching solution is fed at a temperature between 20 and 70° C.

4. The process according to claim 1 , wherein the leaching solution is fed at a flow rate of 15 to 25 BV/h.

5. The process according to claim 1 , wherein the ion exchange resin is used in a counter-current continuous system.

6. The process according to claim 1 , further comprising removing solids prior to adjusting of the pH.

7. The process of claim 1 , wherein nickel and copper are selectively adsorbed over ferric or ferrous iron from the leaching solution as it passes through the ion exchange resin.

8. The process of claim 1 , further comprising precipitating cobalt from the effluent of the resin raffinate.

9. The process of claim 8 , further comprising crystallizing magnesium sulfate from the raffinate effluent from the precipitation of cobalt.

10. The process of claim 1 , wherein the recovering of the nickel comprises contacting the ion exchange resin eluate with an acid retardation resin followed by nickel precipitation.

11. The process of claim 1 , wherein the nickel laterite leaching solution contains copper that is recovered from the ion exchange resin.

Assignments (2)
CHANGE OF ADDRESS Recorded Sep 13, 2017
From: VALE S.A.
To: VALE S.A.
Reel/Frame 043849/0613 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 4, 2012
From: BERNI, TIAGO VALENTIM; PEREIRA, ANTONIO CLARETI
To: VALE S.A.
Reel/Frame 028160/0218 →
Continuity (2)
Provisional Application 61438513 · Feb 1, 2011
Related Publication 20120213681A1 · Aug 23, 2012