Direct purification of a nickel laterite leaching effluent
The present invention refers to a direct purification process of a nickel laterite leaching effluent including adjusting a pH of a leaching solution, employing an ion exchange resin to adsorb nickel and copper selectively over ferric or ferrous iron, and recovering nickel.
1. A direct purification process of a nickel laterite leaching effluent, comprising:
providing a nickel laterite leaching solution;
adjusting the pH of the nickel laterite leaching solution to be between 1.0 and 3.0;
contacting the pH-adjusted nickel laterite leaching solution with a bis-picolylamine ion exchange resin to adsorb nickel and copper selectively over iron and cobalt; and
recovering nickel, wherein the pH-adjusted leaching solution is fed at a temperature between 0° C. and 100° C., and at a flow rate of 5 to 50 BV/h.
2. The process according to claim 1 , wherein the pH of the leaching solution is adjusted to be between 1.5 and 2.0.
3. The process according to claims 1 , wherein the leaching solution is fed at a temperature between 20 and 70° C.
4. The process according to claim 1 , wherein the leaching solution is fed at a flow rate of 15 to 25 BV/h.
5. The process according to claim 1 , wherein the ion exchange resin is used in a counter-current continuous system.
6. The process according to claim 1 , further comprising removing solids prior to adjusting of the pH.
7. The process of claim 1 , wherein nickel and copper are selectively adsorbed over ferric or ferrous iron from the leaching solution as it passes through the ion exchange resin.
8. The process of claim 1 , further comprising precipitating cobalt from the effluent of the resin raffinate.
9. The process of claim 8 , further comprising crystallizing magnesium sulfate from the raffinate effluent from the precipitation of cobalt.
10. The process of claim 1 , wherein the recovering of the nickel comprises contacting the ion exchange resin eluate with an acid retardation resin followed by nickel precipitation.
11. The process of claim 1 , wherein the nickel laterite leaching solution contains copper that is recovered from the ion exchange resin.